Mohammad Hayal Alotaibi

Thioxoquinazolines: synthesis, reactions and biological activities

The chemistry of thioxoquinazolines has considerable values and has gained an increased interest in both synthetic and biological fields. Therefore, the methods of syntheses and modification of such ring systems remain the focus of various researchers. Indeed, some of the reactions have been applied successfully for the production of various valuable compounds and has also led to a ring system modifications. The present review discusses the synthetic methods, reactions, and biological activities of such compounds which have been reported recently.

The Effect of Ultraviolet Irradiation on the Physicochemical Properties of Poly(vinyl Chloride) Films Containing Organotin(IV) Complexes as Photostabilizers

Three organotin(IV) complexes containing ciprofloxacin as a ligand (Ph3SnL, Me2SnL2 and Bu2SnL2; 0.5% by weight) were used as additives to inhibit the photodegradation of polyvinyl chloride films (40 µm thickness) upon irradiation with ultraviolet light (λmax = 313 at a light intensity = 7.75 × 10−7 ein dm−3 S−1) at room temperature. The efficiency of organotin(IV) complexes as photostabilizers was determined by monitoring the changes in the weight, growth of specific functional groups (hydroxyl, carbonyl and carbene), viscosity, average molecular weight, chain scission and degree of deterioration of the polymeric films upon irradiation. The results obtained indicated that organotin(IV) complexes stabilized poly(vinyl chloride) and the dimethyltin(IV) complex was the most efficient additive. The surface morphologies of poly(vinyl chloride) films containing organotin(IV) complexes were examined using an atomic force microscope and scanning electron microscopy. These showed that the surface of polymeric films containing organotin(IV) complexes were smoother and less rough, compared to the surface of the blank films. Some mechanisms that explained the role of organotin(IV) complexes in poly(vinyl chloride) photostabilization process were proposed.

Poly(vinyl Chloride) Photostabilization in the Presence of Schiff Bases Containing a Thiadiazole Moiety

Five Schiff bases containing a thiadiazole moiety have been used as poly(vinyl chloride) photostabilizers at low concentrations. The efficiency of Schiff bases as photostabilizers was investigated using various techniques, for example, the changes in poly(vinyl chloride) infrared spectra, molecular weight, chain scission quantum yield, and surface morphology were monitored upon irradiation with an ultraviolet light. Evidently, all the additives used inhibited poly(vinyl chloride) photodegradation at a significant level. The most efficient Schiff base exhibited a high level of aromaticity and contained a hydroxyl group. It seems possible that such photostabilization could be due to the direct absorption of ultraviolet radiation by the additives. In addition, Schiff bases could act as radical scavengers and proton transfer facilitators to stabilize the polymeric materials.

1-(2-Bromo-4-chloro-phen-yl)-3,3-di-methyl-thio-urea.

In the title compound, C9H10BrClN2S, the dimethylthiourea group is twisted from the benzene ring plane by 54.38 (6)°. In the crystal, the amino groups are involved in the formation of N—H⋯S hydrogen bonds, which link the molecules into chains along [010]. Weak C—H⋯Cl interactions further link these chains into layers parallel to the ab plane.

Insights about the Absence of Rb Cation from the 3D Perovskite Lattice: Effect on the Structural, Morphological, and Photophysical Properties and Photovoltaic Performance

Efficiencies >20% are obtained from the perovskite solar cells (PSCs) employing Cs+ and Rb+ based perovskite compositions; therefore, it is important to understand the effect of these inorganic cations specifically Rb+ on the properties of perovskite structures. Here the influence of Cs+ and Rb+ is elucidated on the structural, morphological, and photophysical properties of perovskite structures and the photovoltaic performances of resulting PSCs. Structural, photoluminescence (PL), and external quantum efficiency studies establish the incorporation of Cs+ (x < 10%) but amply rule out the possibility of Rb-incorporation into the MAPbI3 (MA = CH3 NH3+ ) lattice. Moreover, morphological studies and time-resolved PL show that both Cs+ and Rb+ detrimentally affect the surface coverage of MAPbI3 layers and charge-carrier dynamics, respectively, by influencing nucleation density and by inducing nonradiative recombination. In addition, differential scanning calorimetry shows that the transition from orthorhombic to tetragonal phase occurring around 160 K requires more thermal energy for the Cs-containing MAPbI3 systems compared to the pristine MAPbI3 . Investigation including mixed halide (I/Br) and mixed cation A-cation based compositions further confirms the absence of Rb+ from the 3D-perovskite lattice. The fundamental insights gained through this work will be of great significance to further understand highly promising perovskite compositions.

Fabrication of Novel Ball-Like Polystyrene Films Containing Schiff Base Microspheres as Photostabilizers

Polystyrene films containing a low concentration of three highly aromatic Schiff bases were prepared using the casting method. The polystyrene films were irradiated with ultraviolet light (300 h). The polystyrene infrared spectra, weight loss, molecular weight reduction and the surface morphology were examined upon irradiation. The Schiff bases acted as photostabilizers and reduced the photodegradation of polystyrene films to a significant level in comparison to the blank film. The images recorded of the surface of the miscible polystyrene/Schiff base blends showed novel ball-like microspheres with a diameter of 3.4–4.3 µm. The Schiff bases were able to endow excellent protection to polystyrene against ultraviolet irradiation.

Fabrication of ordered honeycomb porous poly(vinyl chloride) thin film doped with a Schiff base and nickel(II) chloride

A modified poly(vinyl chloride) honeycomb thin film containing a low concentration of a thiadiazole Schiff base and nickel(II) chloride was successfully fabricated using the casting process. The surface morphology of the synthesized thin film was investigated using the scanning electronic microscopy. The synthesized poly(vinyl chloride) thin film was found to have a homogeneous surface morphology with a high crystalline nature. The addition of nickel(II) chloride was discovered to be vital for the formation of the honeycomb like structure.

Crystal structure of 3-(2-bromophenyl)-1,1-dimethylthiourea, C9H11BrN2S

Abstract C9H11BrN2S, orthorhombic, P212121 (no. 19), a = 7.5187(3) Å, b = 8.0634(3) Å, c = 17.5320(6) Å, V = 1062.90(7) Å3, Z = 4, Rgt(F) = 0.0216, wRref(F2) = 0.0536, T = 296(2) K.