Mohammed Said Benzagouta

Ionic liquids as novel surfactants for potential use in enhanced oil recovery

The screening and use of benign chemicals for enhanced oil recovery (EOR) applications is important because of their properties and relationship to the embedded fluids. We investigated a special type of ionic liquids (ILs) called “Ammoeng” for potential use in surfactant EOR to replace the currently used surfactants that have many disadvantages. The interfacial tension (IFT) between a representative oil sample from Saudi reservoirs and solutions of Ammoeng™ ILs at different concentrations in 10 wt% NaCl aqueous solutions were measured as a function of temperature. It was found that the IFT values decreased with the increase of IL concentration. However, the effect of temperature on the IFT depended on the type of IL. Ammoeng™ 102 gave the lowest IFT values among the screened ILs. The comparison of the results to those resulting from TritonX100, a commercially used surfactant, showed that the IFT values using Ammoeng™ 102 were smaller than the corresponding values when TritonX100 was used at the same conditions. The possibility of having a synergetic effect when using a mixture of Ammoeng™ 102 and Triton X 100 was also investigated. The results showed that the IFT values depended on the total concentration, the surfactant to IL mass ratio, and the temperature.

Characterization of heterogeneity of the Shajara reservoirs of the Shajara formation of the Permo-Carboniferous Unayzah group

Representative sandstone samples were collected from the surface-type section of the Shajara Formation of the Permo-Carboniferous Unayzah Group for reservoir characterization through fractal dimension investigation. Two models based on mercury intrusion technique were employed to represent the pores characteristics of these sandstones. The results show that realistic dimensions and outstanding fractal features of porous structures in Shajara sandstones, when these materials are correlated by thermodynamic model and 3-D fractal model of mercury intrusion. On the basis of sub-Unayzah unconformity, sub-Middle Shajara local unconformity, mudstone of the Middle Shajara and sub-Khuff unconformity, the three porous and permeable sandstone units of Shajara Formation were treated separately and classified here into three fractal dimension units. The units from base to top are: Lower Shajara Fractal Dimension Unit, Middle Shajara Fractal Dimension Unit, and Upper Shajara Fractal Dimension Unit. The thermodynamic model and 3-D fractal model were effectively used to characterize the porous structures of Shajara sandstones in logical and quantitative way.

Investigation on crude oil penetration depth into soils

The main objectives of this paper are to study crude oil migration as a toxic fluid, its rate of penetration, and its consequences for eventual treatment. To achieve these objectives, an experimental model was designed comprising two separated columns, filled with soil and other rock types to simulate a real case scenario. Crude oil penetration depth versus time was recorded by taking soil samples whereas water samples were collected from the wet system to analyze the penetrating liquid. The results show that penetration depth was greater in the wet system during the early stages rather than in the dry system. However, with time, penetration becomes more developed in both systems. Overall penetration in the final stage was found to be significantly higher in the dry system. In addition, it was observed that during crude oil migration in dry system, chromatographic separation of crude oil components has occurred obviously. The obtained results reveal that immediate treatment must be performed in both systems but particularly in the wet system, due to its higher initial penetration rate.