Mojtaba Ahmadi

One-pot synthesis of aminated multi-walled carbon nanotube using thiol-ene click chemistry for improvement of epoxy nanocomposites properties

A non-oxidative method based on thiol-ene click chemistry for functionalization of multi-walled carbon nanotube (CNT) was performed in order to improve the interfacial interactions between epoxy matrix and CNT. In this way, the CNT was aminated using 2-aminoethanethiol hydrochloride radicals thermally produced by a peroxide radical initiator. The aminated CNT (CNT-NH2) was characterized by FTIR, TGA, and solubility evaluations, confirming that thiol radicals are successfully grafted onto the CNT surface with a proper yield. Various percentages of pure CNT (p-CNT) and CNT-NH2 were then incorporated into epoxy matrix to evaluate the effect of the functionalization of CNT on thermal, mechanical, and morphological properties. The nanocomposites were characterized by DMA, tensile testing, and TGA. Results showed that glass transition temperature, tensile properties and thermal stability of epoxy nanocomposites containing CNT-NH2 improves significantly compared to those containing unmodified CNT. These results prove the role of amino-functionalization in improving the interfacial adhesion between epoxy and CNT, which was further confirmed by morphological observations of fracture surfaces of the nanocomposites.

Fish DNA-modified clays: Towards highly flame retardant polymer nanocomposite with improved interfacial and mechanical performance.

Deoxyribonucleic Acid (DNA) has been recently found to be an efficient renewable and environmentally-friendly flame retardant. In this work, for the first time, we have used waste DNA from fishing industry to modify clay structure in order to increase the clay interactions with epoxy resin and take benefit of its additional thermal property effect on thermo-physical properties of epoxy-clay nanocomposites. Intercalation of DNA within the clay layers was accomplished in a one-step approach confirmed by FT-IR, XPS, TGA, and XRD analyses, indicating that d-space of clay layers was expanded from ~1.2 nm for pristine clay to ~1.9 nm for clay modified with DNA (d-clay). Compared to epoxy nanocomposite containing 2.5%wt of Nanomer I.28E organoclay (m-clay), it was found that at 2.5%wt d-clay loading, significant enhancements of ~14%, ~6% and ~26% in tensile strength, tensile modulus, and fracture toughness of epoxy nanocomposite can be achieved, respectively. Effect of DNA as clay modifier on thermal performance of epoxy nanocomposite containing 2.5%wt d-clay was evaluated using TGA and cone calorimetry analysis, revealing significant decreases of ~4000 kJ/m2 and ~78 kW/m2 in total heat release and peak of heat release rate, respectively, in comparison to that containing 2.5%wt of m-clay.

A renewable bio-based epoxy resin with improved mechanical performance that can compete with DGEBA

The aim of this study is to find a suitable substitution for diglycidyl ether bisphenol A (DGEBA) to avoid the devastating side effects of bisphenol A. Vanillin, an aromatic compound, was used as a renewable material to synthesize a bio-based epoxy resin. The structure of the vanillin-based epoxy resin was confirmed by Fourier transform infrared spectroscopy (FT-IR) analysis. The major drawback of bio-based epoxy resins is their poor mechanical properties preventing them from competing with petroleum based epoxy resins such as DGEBA. Herein, a prepared calcium nitrate solution as an inorganic accelerator was used to accelerate the curing reaction of bio-based epoxy resin which reduced curing times as well as improving significantly the mechanical properties e.g., tensile strength, pull-off strength, and Izod impact strength. Differential scanning calorimetry (DSC) analysis was used to investigate the curing process and thermal properties of the vanillin-based epoxy resin with and without inorganic accelerators and also DGEBA without accelerators. The results showed that in the presence of 2 wt% inorganic accelerator, the initial onset curing temperature of vanillin-based epoxy resin was reduced from 60.1 °C to 8.5 °C, while the initial onset curing temperature of DGEBA was 55.8 °C. In addition, tensile strength and Izod impact strength of the vanillin-based epoxy system in the presence of inorganic accelerators increased in comparison to the DGEBA system. Moreover, in order to study the effect of inorganic accelerators on the toughness of the synthesized vanillin-based epoxy resin, fracture surfaces from Izod impact strength tests were observed using scanning electron microscopy (SEM) which confirmed improving mechanical properties.

Interfacial shear strength characterization of GMA-grafted UHMWPE fiber/epoxy/nano clay hybrid nanocomposite materials

Interfacial properties of glycidyl methacrylate grafted ultra-high molecular weight polyethylene fibers and nano clay/epoxy resin were characterized by a microdroplet test. Nano clay (1, 3 and 5 wt%) was dispersed in both acetone and an acetone epoxy solution to form pastes. The X-ray diffraction (XRD) and transmission electron microscopy (TEM) images show that agglomerates of nano clay (1 and 3 wt%) were broken down to form small particles consisting of several clay platelets. The interfacial shear strength (IFSS) of the GMA-grafted fiber/epoxy system has been greatly enhanced with the addition of nano clay. With the addition of only 3 wt% of clay, the IFSS increased by 228.8% up to the original composite. Scanning electron microscopy (SEM) was used to examine the characteristics of the fracture surfaces after the microdroplet test.

The Effects of UV Light on the Chemical and Mechanical Properties of a Transparent Epoxy-Diamine System in the Presence of an Organic UV Absorber

Despite several excellent properties including low shrinkage, good chemical resistance, curable at low temperatures and the absence of byproducts or volatiles, epoxy resins are susceptible to ultra violet (UV) damage and their durability is reduced substantially when exposed to outdoor environments. To overcome this drawback, UV absorbers have been usually used to decrease the rate of UV degradation. In this present study, the effects of UV light on the chemical, mechanical and physical properties of cured epoxy structure, as well as the effect of an organic UV absorber, Tinuvin 1130, on the epoxy properties were investigated. Chemical changes in a cured epoxy system as a result of the presence and absence of Tinuvin 1130 were determined using Fourier transform infrared spectroscopy (FT-IR) analyses. The effect of Tinuvin 1130 on the surface morphology of the epoxy systems was also investigated by scanning electron microscopy (SEM) imaging. Additionally, the glass transition temperatures (Tg) before and during UV radiation were measured. After an 800 h UV radiation, mechanical test results revealed that the lack of the UV absorber can lead to a ~30% reduction in tensile strength. However, in the presence of Tinuvin 1130, the tensile strength was reduced only by ~11%. It was hypothesized that the use of Tinuvin 1130, as an organic UV absorber in the epoxy-amine system, could decrease the undesirable effects, arising from exposure to UV light.

Collision-induced activation: towards industrially scalable approach to graphite nanoplatelets functionalization for superior polymer nanocomposites

Scale-up manufacturing of engineered graphene-like nanomaterials to deliver the industry needs for development of high-performance polymer nanocomposites still remains a challenge. Herein, we introduce a quick and cost-effective approach to scalable production of functionalized graphite nanoplatelets using “kitchen blender” approach and Diels-Alder chemistry. We have shown that, in a solvent-free process and through a cycloaddition mechanism, maleic anhydride can be grafted onto the edge-localized electron rich active sites of graphite nanoplatelets (GNP) resulting from high collision force, called “graphite collision-induced activation”. The mechanical impact was modelled by applying the point charge method using density functional theory (DFT). The functionalization of GNP with maleic anhydride (m-GNP) was characterized using various spectroscopy techniques. In the next step, we used a recyclable process to convert m-GNP to the highly-reactive GNP (f-GNP) which exhibits a strong affinity towards the epoxy polymer matrix. It was found that at a low content of f-GNP e.g., 0.5 wt%, significant enhancements of ~54% and ~65% in tensile and flexural strengths of epoxy nanocomposite can be achieved, respectively. It is believed that this new protocol for functionalization of graphene nanomaterials will pave the way for relatively simple industrial scale fabrication of high performance graphene based nanocomposites.

Catalyzed Synthesis and Characterization of a Novel Lignin-Based Curing Agent for the Curing of High-Performance Epoxy Resin

In this study, lignin, an aromatic compound from the forestry industry, was used as a renewable material to synthesize a new aromatic amine curing agent for epoxy resin. Firstly, lignin was separated from black liquor and hydroxyl groups were converted to tosyl groups as leaving groups. Then, primary amination was conducted using an ammonia solution at high pressure and temperature, in the presence of a nano-alumina-based catalyst. The structure of the nanocatalyst was confirmed by FT-IR, ICP, SEM, and XPS analyses. According to the FT-IR spectra, a demethylation reaction, the substitution of hydroxyl groups with tosyl groups, and then an amination reaction were successfully performed on lignin, which was further confirmed by the 13C NMR and CHNS analyses. The active hydrogen equivalent of aminated lignin was determined and three samples with 9.9 wt %, 12.9 wt %, and 15.9 wt % of aminated lignin, as curing agents, were prepared for curing the diglycidyl ether of bisphenol A (DGEBA). The thermal characteristics of the curing process of these epoxy samples were determined by DSC and TGA analyses. Moreover, the mechanical performance of the cured epoxy systems, e.g., the tensile strength and Izod impact strength, were measured, showing that in the presence of 12.9 wt % aminated lignin, the mechanical properties of the aminated lignin-epoxy system exhibited the best performance, which was competitive, compared to the epoxy systems cured by commercial aromatic curing agents.

Flexural and Charpy impact behaviour of epoxy/glass fabric treated by nano-SiO2 and silane blend

ABSTRACT A sizing formulation, containing compatible and incompatible silane coupling agents with epoxy resin in conjunction with nanoscale colloidal silica, was used to modify the surface of glass fabric. The modified glass fabric/epoxy resin composite panels were fabricated and characterised by flexural test, Charpy impact test and scanning electron microscope (SEM). By combining nano silica with silane blend in the fabric sizing, more energy was consumed under bending and impacting, which resulted in an improvement of the toughness in composites. The flexural strength, bending stain and Charpy impact strength of the epoxy composite/glass fabric treated with 1 wt-% nano silica and silane blend were ∼42, ∼22 and 35%, respectively, higher than those of silane blend coated glass fabric-reinforced composites (without nano silica). Furthermore, the change of the brittle fracture of the composite into ductile fracture was investigated by SEM micrographs. A possible toughening mechanism was also proposed.