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Montserrat Alfonso

University of Zurich

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Publication

Featured researches published by Montserrat Alfonso.

Chemical Communications | 2003

A facile and novel route to unprecedented manganese C4 cumulenic complexes.

Koushik Venkatesan; Francisco J. Fernández; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) [=C=C=C=C(SnPh3)2] was obtained by photolysis of the C(sp2)-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)-C[triple bond]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn-C4-SnPh3.

Chemical Communications | 2001

A facile and new type of route to the redox-active rigid-rod complex [{Mn(dmpe)2(CCH)}2(μ-C4)][PF6] via Mn–C2˙ radical coupling

Francisco J. Fernández; Olivier Blacque; Montserrat Alfonso; Heinz Berke

The binuclear rigid-rod complex [{Mn(dmpe)2(CCH)}2(μ-C4 )][PF6] was spontaneously obtained from the reaction of [Mn(dmpe)2(CCSiMe3)2][PF6 ] with one equivalent of TBAF.

Chemistry: A European Journal | 2003

Generation and Coupling of [Mn(dmpe)2(CCR)(CC)]. Radicals Producing Redox‐Active C4‐Bridged Rigid‐Rod Complexes

Francisco J. Fernández; Koushik Venkatesan; Olivier Blacque; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

Organometallics | 2005

μ-carbon - Carbon bonds of dinuclear manganese half-sandwich complexes as electron reservoirs

Koushik Venkatesan; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Sohrab Kheradmandan; Heinz Berke

Organometallics | 2004

Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions

Koushik Venkatesan; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

Organometallics | 2001

Utilization of Redox and Acid/Base Chemistry for the Deprotection of a Mn(dmpe)2(C⋮CSiMe3)2 Complex

Francisco J. Fernández; Montserrat Alfonso; and Helmut W. Schmalle; Heinz Berke

Journal of Organometallic Chemistry | 2004

Oxidative addition capability of triphosphine iron and ruthenium complexes with methyl iodide

Piotr Jaunky; Helmut W. Schmalle; Montserrat Alfonso; Thomas Fox; Heinz Berke

Organometallics | 2004

Synthetic Access to Half-Sandwich Manganese C4 Cumulenic Complexes

Koushik Venkatesan; Olivier Blacque; Thomas Fox; Montserrat Alfonso; and Helmut W. Schmalle; Heinz Berke

European Journal of Inorganic Chemistry | 2006

Hydride Transfer Reactivity of Mo(L)(H)(depe)2 (L = N, NBEt3)

Johan Cugny; Helmut W. Schmalle; Thomas Fox; Olivier Blacque; Montserrat Alfonso; Heinz Berke

Chemical Communications | 2003

A facile and novel route to unprecedented manganese C4 cumulenic complexesElectronic supplementary information (ESI) available: experimental and computational details. See http://www.rsc.org/suppdata/cc/b3/b304882a/

Koushik Venkatesan; Francisco J. Fernndez; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

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Heinz Berke

University of Zurich

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Helmut W. Schmalle

University of Zurich

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Olivier Blacque

University of Zurich

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Thomas Fox

University of Zurich

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Koushik Venkatesan

University of Zurich

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Francisco J. Fernández

University of Zurich

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Angela Llamazares

University of Zurich

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Christian M. Frech

University of Zurich

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Franck Furno

University of Zurich

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Johan Cugny

University of Zurich

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