Mrinmoy Mondal

Characterization and antifouling properties of polyethylene glycol doped PAN–CAP blend membrane

The effects of polyethylene glycol (PEG) as an additive to a cellulose acetate phthalate–polyacrylonitrile blend membrane in the ultrafiltration range were investigated. Influences of both the molecular weight and concentration of PEG were examined. Ternary phase diagrams were generated to identify the domain of composition where thermodynamic instability occurred. Kinetic hindrance due to the presence of the additive was also estimated. The relative importance of thermodynamic and kinetic factors was investigated quantitatively to interpret the nature of the membrane morphology. The prepared membranes were characterized in terms of surface morphology by scanning electron microscopy, water permeability, pore density, molecular weight cut off, contact angle and breaking stress. The antifouling characteristics of the prepared membranes were evaluated in terms of the filtration of bovine serum albumin protein. Membranes with PEG 200 at concentrations of 2 wt% and 6 wt% showed the best antifouling properties.

A socio-economic study along with impact assessment for laterite based technology demonstration for arsenic mitigation

Arsenic contamination mitigation technologies have been adsorption-based, but the most widely-used and traditionally available adsorbents suffered inherent limitations, including cost infeasibility and problems associated with regeneration and disposal of the spent adsorbent. The present technology is based on indigenously developed activated laterite prepared from the naturally and abundantly available material, and can hence easily be scaled up for community usage and large scale implementation. The total arsenic removal capacity is 32.5mg/g, which is the highest among all naturally occurring arsenic adsorbents. A major issue in earlier adsorbents was that during regeneration, the adsorbed arsenic would be released back into the environment (leaching), and would eventually contaminate the groundwater again. But the adsorbent in this filter does not require regeneration during its five-year lifespan and does not leach upon disposal. An attempt is made to test and demonstrate the practical implementation of the technology - its effectiveness and viability in three community (primary schools - one in Malda and two in north 24 Parganas, West Bengal, India) and 20 household filters, catering to over 5000 people in different areas of West Bengal exposed to high arsenic contamination of groundwater (ranging from 0.05 to 0.5mg/l). The work also focuses on the social impact of the real life technological solution on the lives on the affected people in the worst hit arsenic affected communities, perhaps the greatest public health risk emergency of the decade.

Effects of overlapping electric double layer on mass transport of a macro-solute across porous wall of a micro/nanochannel for power law fluid

Effects of overlapping electric double layer and high wall potential on transport of a macrosolute for flow of a power law fluid through a microchannel with porous walls are studied in this work. The electric potential distribution is obtained by coupling the Poissons equation without considering the Debye–Huckel approximation. The numerical solution shows that the center line potential can be 16% of wall potential at pH 8.5, at wall potential −73 mV and scaled Debye length 0.5. Transport phenomena involving mass transport of a neutral macrosolute is formulated by species advective equation. An analytical solution of Sherwood number is obtained for power law fluid. Effects of fluid rheology are studied in detail. Average Sherwood number is more for a pseudoplastic fluid compared to dilatant upto the ratio of Poiseuille to electroosmotic velocity of 5. Beyond that, the Sherwood number is independent of fluid rheology. Effects of fluid rheology and solute size on permeation flux and concentration of neutral solute are also quantified. More solute permeation occurs as the fluid changes from pseudoplastic to dilatant.