Mufeed I. Batarseh

Agricultural reuse of reclaimed water and uptake of organic compounds : Pilot study at Mutah University wastewater treatment plant, Jordan

The residues of polynuclear aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), chlorinated benzenes (CBs) and phenols were investigated for soil, wastewater, groundwater and plants. The uptake concentration of these compounds was comparatively determined using various plant types: Zea mays L., Helianthus annus L., Capsicum annum L., Abelmoschus esculentus L., Solanum melongena L. and Lycopersicon esculentum L. which were grown in a pilot site established at Mutah University wastewater treatment plant, Jordan. Soil, wastewater, groundwater and various plant parts (roots, leaves and fruits) samples were extracted in duplicate, cleaned up by open-column chromatography and analyzed by a multi-residue analytical methods using gas chromatography equipped with either mass selective detector (GC/MS), electron capture detector (GC/ECD), or flame ionization detector (FID). Environmentally relevant concentrations of targeted compounds were detected for wastewater much higher than for groundwater. The overall distribution profiles of PAHs and PCBs appeared similar for groundwater and wastewater indicating common potential pollution sources. The concentrations of PAHs, PCBs and phenols for different soils ranged from 169.34 to 673.20 microg kg(-1), 0.04 to 73.86 microg kg(-1) and 73.83 to 8724.42 microg kg(-1), respectively. However, much lower concentrations were detected for reference soil. CBs were detected in very low concentrations. Furthermore, it was found that different plants have different uptake and translocation behavior. As a consequence, there are some difficulties in evaluating the translocation of PAHs, CBs, PCBs and phenols from soil-roots-plant system. The uptake concentrations of various compounds from soil, in which plants grown, were dependent on plant variety and plant part, and they showed different uptake concentrations. Among the different plant parts, roots were found to be the most contaminated and fruits the least contaminated.

Chemical Composition of Urban Wet Deposition in Amman, Jordan

Precipitation events were collected during the period from October 1996 to April 1997 from two sites in the city of Amman, Jordan. The samples were analyzed for major cations (Na+, K+, Ca2+, Mg2+ and NH4+), major anions (F-, Cl-, NO3- and SO42-), in addition to heavy metals (Cu2+, Cd2+, Zn2+, and Pb2+). High levels of Ca2+ and SO42- were observed. The results were comparable with some regional values and they indicate that about 58% of Na+ and Cl- are of marine origin, while Ca2+, K+ and a large fraction of SO42- are of soil dust origin. Heavy metals were detectable in most of the samples, zinc showed the highest concentrations. Significant correlation was obtained between zinc and lead, which may indicate automobile emission source.

Pesticides and trace metals residue in grape and home made wine in Jordan.

Sixty home made wine and sixty-four grape samples were collectedfrom five territories in Jordan, where grapes and wine aremostly producted. The collected samples were analyzed for themost used organochlorine pesticides (OCP) and organophosphorouspesticides (OPP) in Jordan, as well as for four heavy metals(Ni, Cu, Zn and Pb). The results showed that OCPs residues weredetected in 73% of the wine samples but no OPPs residue weredetected which is due to generally shorter half life of thelater pesticide. Grapes showed higher incident of contaminationthan wine, however, OCPs and OPPs with both short and longhalf-lives were detected. The OPPs were detected in only8.3% of the analyzed grape samples. Heavy metals showed higher valuesin grapes than in the wine samples and it was attributed toremoval of solids during wine preparation processes or throughcontamination of wine during storage. Most of the samples werebelow toxic limit.

The distribution of heavy metals in urban street dusts of Karak City, Jordan

Street dust samples from urban and suburban areas were collected from the city of Karak, Jordan, during the summer season of 2004. Samples were analyzed for their heavy metal concentrations (Pb, Cu, Zn, Ni, Fe, Cr, Cd, and Mn). The results showed that all heavy metals are higher in city urban areas than the surrounding suburbs. The distribution and concentrations of heavy metals in all areas show automobile originated sources such as emissions and wear and tear of automobiles were the main source of pollution. Despite the fact that the city of Karak and the capital Amman are under the same climatic conditions and same type of fuel used in both cities, the heavy metal concentrations of street dust samples were lower in Karak than Amman due to the lower traffic density.

Toxic Element Levels in the Phosphate Deposits of Central Jordan

The phosphate deposits are used mainly as raw materials in the fertilizer industry. However, toxic elements content in both phosphate ores and final mining products has received little attention. The present study used inductively coupled plasma mass spectrometry (ICP-MS) to determine levels of toxic elements in phosphate deposits in Al-Hisa and Al-Abyad mines, Jordan. Concentrations of elements were converted into rock content based on the ICP-MS results and compared using an enrichment-factor (EF) method that normalized to the mean concentration of elements in crustal rock. The results showed that the U, V, and Hg were enriched in the Jordanian deposits compared to the average worldwide phosphate (AWP), whereas lower enrichments of Pb were found in the Jordanian deposits (JP). Other trace elements had similar levels in Jordanian deposits comparable to worldwide averages of phosphates. Concentrations of U, V, and Cd in Jordanian phosphate deposits were greater than the permissible limits for soils for growing crops established by the European Community (EC) and World Health Organization (WHO). Finally, Jordanian phosphate deposits show the highest enrichment of Hg and U, thus can be regarded as U-bearing.

Chemical and Mineralogical Characteristics of Dry Deposition in the Surrounding of a Cement Factory in Jordan

Dry deposition samples were collected from 28 residential rooftops in Fuhais, Jordan, during the dry seasons of the year 2004. The samples were analyzed for trace and heavy metal concentrations to investigate the impact of total suspended particles emitted from the cement industry in the city of Fuhais. The cement factory has been operational for the past 50 years, and the management was evaluating the use of petcoke blending to reduce fuel costs. No baseline data on heavy metals due to the current operations existed prior to this study. The present study showed that lead (Pb) and copper (Cu) concentrations were statistically significant in the northwest sector of the city compared with the other quadrants. This significance was attributed to the heavy traffic of trucks carrying raw materials and cement in and out of the cement factory as the main route of transportation to the factory runs through this quadrant of the city. Cadmium (Cd), aluminum (Al), iron (Fe), zinc (Zn), manganese (Mn), nickel (Ni), molybdenum (Mo), and chromium (Cr) concentrations were high in all sampled areas. The overall average concentrations of all elements except Mo were found to be higher on the rooftops of the residential areas in Fuhais City in comparison with a remote reference site near Amman where no anthropogenic activity exists. The trace and heavy metal concentrations and the mineralogical composition of dry deposition samples collected from residential rooftops are representative of the current cement industry operations, which dominate the air quality of Fuhais City.

Polycyclic aromatic hydrocarbons (PAH) in top soil, leachate and groundwater from Ruseifa solid waste landfill, Jordan

The distribution profiles and pathways of polynuclear aromatic hydrocarbons in the surroundings of Ruseifa landfill area in Jordan were investigated for surface sediments, leachate, and groundwater. The total concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in sediments ranged from 286 to 1704 ppm with an average value of 751 ppm. Meanwhile, concentrations of PAH in groundwater ranged between 7.1 and 12.6 ppm with an average value of 9.1 ppm. The PAH in leachate varied between 0.10 and 0.40 with an average value of 0.29 ppm. The overall PAH distribution profiles appeared to be similar for leachate and groundwater dominated by 2–3 rings system molecules. While, the sediments profile was dominated by 4–6 rings system molecules which indicated the loss of low molecular weight compounds of PAH and accumulation of higher molecular weight of PAH under prevailing semiarid and hot climatic conditions.

The use of cypress tree bark as an environmental indicator of heavy metals deposition in Fuheis City, Jordan

The present study focused on the use of cypress tree bark as an environmental indicator of heavy metal deposition in Fuheis City, Jordan, and the evaluation of the impact of emissions from the cement industry in the adjacent environment. Tree bark samples were collected from four directions (north, south, east and west) in the vicinity of the cement factory. The samples were analysed for heavy metal content: Mn, Cu, Ni, Co, Pb, Cd, Zn, Cr, and Fe. The results showed variations in heavy metal concentrations between sites. The levels of heavy metal were divided into three groups: mean concentrations of Co and Cd ranged from 1 to 4 mg/kg; Mn, Cu, Ni, Pb, Zn and Cr ranged from 9 to 109 mg/kg; and finally, Fe ranged from 2238 to 3393 mg/kg.

Lichens (Rhizocarpon geographicum (L.) DC) as a Biomonitor for Atmospheric Pollution in Amman City, Jordan

The lichen, Rizocarpon geographicum (L.) DC, grown on walls and roofs along the main streets in Amman city-Jordan, was used as a bioindicator for atmospheric pollution. The samples were collected from three areas representing high traffic, residential, and remote sites. The results of heavy metals concentration (Zn, Cu, Pb, Cd and Co) showed clear variations between the investigated sites comparedto that of the remote site. The highest concentrations occurred at the busy traffic sites and the lowest at the remote site. Peak concentrations of zinc (1206 μg g−1), copper (255 μg g−1), lead (400 μg g−1), cadmium (1.8 μg g−1) and cobalt (4.1 μg g−1) were observed at the city center of Amman that characterized busy road traffic. The heavy metal concentrations of lichens at Amman city were found to be at the upper limit values reported in the literature for temperate countries. Furthermore, lichens were found to be comparable to dust deposits and tree bark in terms of heavy metals content for the metropolitan area.

Polynuclear Aromatic Hydrocarbons (PAH) and Heavy Metals in Dry and Wet Sludge from As-Samra Wastewater Treatment Plant, Jordan

Dry and wet sludge samples were collected from the sewage sludge storage site and primary treatment ponds at As-Samra Wastewater Treatment Ponds in Al Hayshmia, Jordan. The concentrations of polynuclear aromatic hydrocarbons (PAH) and macro- and microelements were determined using gas chromatography-mass spectrometry (GC-MS) and inductively coupled plasma-mass spectrometry (ICP-MS), respectively. Environmentally relevant concentrations of PAH were detected ranging from 62 μg g−1 to 70 μg g−1 for dry sludge and from 35 μg g−1 to 47 μg g−1 for wet sludge. These results indicated a potential environmental risk if sewage sludge is reused in Jordan as organic fertilizer without first being treated. The results of the study showed that the sewage sludge samples were contaminated with low levels of heavy metals, as the dry sludge samples were characterized by higher concentrations of most analyzed elements than for wet sludge samples. Still, none of the trace metal concentrations exceeded the threshold concentration levels for agricultural-related sludge. Unlike many other nutrients found in sludge, the Total Organic Carbon (TOC%) found in dry and wet sludge revealed similar values, at 13.18 percent and 13.29 percent, respectively. The total phosphorus ranged from 0.25% for dry sludge to 0.47% for wet sludge. Total nitrogen varied from 0.80% for wet sludge to 1.01% for the dry sludge samples. The overall nutrients levels are close to those found in the literature. The findings of this study have improved the understanding of sewage sludge characteristics in a semiarid environment.