Mustafa Anik

Dissolution Behavior of Electrodeposited Ni–W Alloys

Nickel (Ni)–Tungsten (W) alloys were electrodeposited galvanostatically (at–10 mA cm–2) on copper substrate with 3 different W contents under the controlled hydrodynamic conditions and then the anodic dissolution behaviors of the alloys were observed by potentiodynamic polarization and electrochemical quartz crystal microbalance (EQCM) techniques. While the structure of the electrodeposited Ni–W alloy with low W content (15.90% W) was crystalline, that of the alloy with high W content (50.80% W) was nano-crystalline according to X-ray diffraction patterns. The increase in the W content of the electrodeposited Ni–W alloy resulted decrease at pH 3 and increase at pH 7 and 12.5 in the anodic currents of the alloy. The pH dependent dissolutions caused electrodeposited alloy surface to have W—enrichment at pH 3 and Ni—enrichment at pH 7 and 12.5. These observations indicated that the selective dissolution of Ni or W was the main mechanism in the anodic dissolution of the electrodeposited Ni–W alloys. The EQCM experiments conducted at pH 7 supported the presence of the selective dissolution mechanism that the anodic dissolution potential of W was 0.42 V lower than that of Ni in the electrodeposited Ni–W alloys.

Corrosion and Wear Characteristics of Electroless Ni–P, Ni–P–W and Composite Ni–P–W/Al 2 O 3 Coatings on AZ91 Sheet

Electroless Ni–P–W was coated on AZ91 sheets with various W contents and both the corrosion and wear resistance characteristics of these coatings were observed. The increase in W content resulted in a decrease in P content and an increase in the crystallinity of the electroless coatings. The corrosion resistance of the electroless coatings increased upon increase in W content of the electroless coatings up to approximately 5%. Above this content, however, the corrosion resistance tended to decrease due to the disturbed grain structure of the electroless coating. But both the surface hardness and wear resistance increased concurrently due to the positive contribution of W solid solution hardening. The applied heat treatment resulted in a decrease in the corrosion resistance due to the disappearance of the amorphous structure and increase in both the surface hardness and wear resistance due to the precipitation hardening. Al2O3 dispersion was better with the nonionic surfactant, as compared to the anionic and cationic surfactants. Composite coating reduced the corrosion resistance and increased the wear resistance of the electroless Ni–P–W coatings. The applied heat treatment was observed to have positive contribution to Ni–P–W coatings in getting the optimum corrosion and wear resistance combination.