Mustafa M. Özer

Hard Superconductivity of a Soft Metal in the Quantum Regime

Superconductivity is inevitably suppressed in reduced dimensionality1,2,3,4,5,6,7,8,9. Questions of how thin superconducting wires or films can be before they lose their superconducting properties have important technological ramifications and go to the heart of understanding coherence and robustness of the superconducting state in quantum-confined geometries1,2,3,4,5,6,7,8,9. Here, we exploit quantum confinement of itinerant electrons in a soft metal, Pb, to stabilize superconductors with lateral dimensions of the order of a few millimetres and vertical dimensions of only a few atomic layers10. These extremely thin superconductors show no indication of defect- or fluctuation-driven suppression of superconductivity, and sustain supercurrents of up to 10% of the depairing current density. Their magnetic hardness implies a Bean-like critical state with strong vortex pinning that is attributed to quantum trapping of vortices. This study paints a conceptually appealing, elegant picture of a model nanoscale superconductor with calculable critical-state properties and surprisingly strong phase coherence. It indicates the intriguing possibility of exploiting robust superconductivity at the nanoscale.

Tuning the Quantum Stability and Superconductivity of Ultrathin Metal Alloys

Quantum confinement of itinerant electrons in atomically smooth ultrathin lead films produces strong oscillations in the thickness-dependent film energy. By adding extra electrons via bismuth alloying, we showed that both the structural stability and the superconducting properties of such films can be tuned. The phase boundary (upper critical field) between the superconducting vortex state and the normal state indicates an anomalous suppression of superconducting order just below the critical temperature, Tc. This suppression varies systematically with the film thickness and the bismuth content and can be parametrized in terms of a characteristic temperature, Tc* (less than Tc), that is inversely proportional to the scattering mean free path. The results indicate that the isotropic nature of the superconductive pairing in bulk lead-bismuth alloys is altered in the quantum regime.

Quantum Size Effects in the Growth and Properties of Ultrathin Metal Films, Alloys, and Related Low-Dimensional Structures

This chapter addresses the quantum mechanical nature of the formation, stability, and properties of ultrathin metal films, metallic alloys, and related low-dimensional structures, with Pb as a primary elemental example. The emphasis is on the contribution to the overall energetics from the electronic degrees of freedom of the low-dimensional systems. As a metal film reduces its thickness, the competition between quantum confinement, charge spilling, and Friedel oscillations, all of electronic origin, can dictate whether an atomically smooth film is marginally, critically, or magically stable or unstable against roughening during the growth of such metal films. The “electronic growth” mode as emphasized here serves as an intriguing addition to the three well-established classic modes of crystal growth. In exploring electronic growth, Pb(111) films represent a particularly compelling example, not only because their stability exhibits unusually strong quantum oscillations but also because their physical and chemical properties can be tuned with great precision by controlling the film thickness or the chemical composition. Recent advances and the perpectives in this active area of film growth will be reviewed, with results from both theoretical and experimental studies.

Plasmonic excitations in ultrathin metal films on dielectric substrates

The optical properties of metals are mainly determined by their plasmonic excitations, with various intriguing phenomena associated with systems in reduced dimensions. In this paper, we present a systematic study of the plasmonic excitations in ultrathin metal films on dielectric substrates using two different theoretical approaches, and with Mg thin films on Si as prototype systems. The bulk of the results are obtained using the first approach within first-principles time-dependent local density approximation. We show that the presence of the substrate substantially modifies the plasmon hybridization of the metal films; in turn, the plasmon excitation in the films strongly enhances the absorption of the substrate. The detailed absorption spectra contain several intriguing features. Above the Mg surface plasmon mode, we observe a broad resonance due to the hybridization between the antisymmetric surface plasmon and multipole surface plasmon. Furthermore, below the Mg surface plasmon mode, there also exists a broad absorption feature, caused by individual electron?hole pair excitations. In the second approach, we use a semi-classical local optics model to reveal an intrinsic connection between the broad absorption feature and the multipole surface plasmon modes, which result from the single-particle and collective excitations of the same surface electrons, respectively. Our theoretical predictions on the plasmon dispersions and absorption spectra are also shown to be qualitatively consistent with the latest experimental observations using electron energy loss spectroscopy for Mg thin films grown on Si substrates.