Myeonghun Song

Ultrasensitive Multi-Functional Flexible Sensors Based on Organic Field-Effect Transistors with Polymer-Dispersed Liquid Crystal Sensing Layers

Ultrasensitive flexible sensors with multi-sensing functions are required for various applications in flexible electronics era. Here we demonstrate flexible polymer-dispersed liquid crystal (PDLC)-integrated-organic field-effect transistors (OFETs) (PDLC-i-OFETs), which sensitively respond to various stimulations including weak gas (air) flow, direct physical touch, light, and heat. The flexible PDLC-i-OFETs were fabricated by spin-coating the poly(methyl methacrylate) (PMMA)-dispersed 4,4’-pentyl-cyanobiphenyl (5CB) layers on the poly(3-hexylthiophene) (P3HT) channel layers of OFETs with 200 μm-thick poly(ethylene naphthalate) (PEN) substrates. The flexible PDLC-i-OFET devices could sense very weak nitrogen gas flow (0.3 sccm), which cannot be felt by human skins, and stably responded to direct physical touches (0.6~4.8 g load). In addition, the present devices showed very sensitive photoresponses to a visible light and exhibited excellent heat-sensing characteristics at a temperature of 25~70 °C. In particular, the present flexible PDLC-i-OFET devices could sense two different stimulations at the same time, indicative of promising multi-sensing capabilities.

Acidity-Controlled Conducting Polymer Films for Organic Thermoelectric Devices with Horizontal and Vertical Architectures

Organic thermoelectric devices (OTEDs) are recognized one of the next generation energy conversion platforms because of their huge potentials for securing electricity continuously from even tiny heat sources in our daily life. The advantage of OTEDs can be attributable to the design freedom in device shapes and the low-cost fabrication by employing solution coating processes at low temperatures. As one of the major OTE materials to date, poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) has been used, but no study has been yet carried out on its acidity control even though the acidic components in OTEDs can seriously affect the device performance upon operation. Here we demonstrate that the addition of aniline (a weak base) can control the acidity of PEDOT:PSS and enhance the performance of OTEDs. In particular, the vertical OTEDs with aniline-doped PEDOT:PSS films (active area = 1.0 cm2) could continuously generate electricity (0.06 nW) even at low temperatures (<38 °C) when they were mounted on a desk lamp (power = 24 W).

Ultrasensitive tactile sensors based on planar liquid crystal-gated-organic field-effect transistors with polymeric dipole control layers

A polymeric dipole control layer (DCL) greatly reduced the leakage current in planar liquid crystal-gated-organic field-effect transistors and the resulting LC-DCL-g-OFET devices could detect extremely low intensity nitrogen gas flows which cannot be felt by human skin.

Strong addition effect of n-type polymer with mid-energy level in polymer:fullerene solar cells with power conversion efficiency exceeding 10%

Here we report a strong addition effect of n-type conjugated polymer, which has a middle energy level between electron-donating polymers and electron-accepting fullerenes, on the enhanced power conversion efficiency (PCE) of inverted-type organic solar cells with bulk heterojunction (BHJ) layers of poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene-co-3-fluorothieno[3,4-b]thiophene-2-carboxylate] (PTB7-Th) and [6,6]-phenyl C71 butyric acid methyl ester (PC71BM). As a mid-energy level additive, poly(3-hexylthiophene-co-benzothiadiazole) end-capped with hexylthiophene (THBT-ht) was employed by varying its content up to 3 wt%. Results showed that the PCE of inverted-type PTB7-Th:PC71BM solar cells was enhanced from 8.77% to 9.81% (max: 10.02%) by adding only 0.5 wt% (1.47 mol%) THBT-ht. The pronounced improvement at 0.5 wt% has been assigned to the balanced charge transport and the drastic change of nanoscale morphology toward finer phase segregation and less hydrophobic smoother surface. The present finding is expected to contribute to further efficiency improvement of BHJ-based organic solar cells with various types of material systems.

Strong Composition Effects in All-Polymer Phototransistors with Bulk Heterojunction Layers of p-type and n-type Conjugated Polymers

We report the composition effect of polymeric sensing channel layers on the performance of all-polymer phototransistors featuring bulk heterojunction (BHJ) structure of electron-donating (p-type) and electron-accepting (n-type) polymers. As an n-type component, poly(3-hexylthiopehe-co-benzothiadiazole) end-capped with 4-hexylthiophene (THBT-4ht) was synthesized via two-step reactions. A well-studied conjugated polymer, poly(3-hexylthiophene) (P3HT), was employed as a p-type polymer. The composition of BHJ (P3HT:THBT-4ht) films was studied in detail by varying the THBT-4ht contents (0, 1, 3, 5, 10, 20, 30, 40, and 100 wt %). The best charge separation in the P3HT:THBT-4ht films was measured at 30 wt % by the photoluminescence (PL) study, while the charge transport characteristics of devices were improved at the low THBT-4ht contents (<10 wt %). The photosensing experiments revealed that the photosensivity of all-polymer phototransistors was higher than that of the phototransistors with the pristine P3HT layers and strongly dependent on the BHJ composition. The highest (corrected) responsivity (RC) was achieved at 20 wt %, which can be attributable to the balance between the best charge separation and transport states, as investigated for crystal nanostructures and surface morphology by employing synchrotron-radiation grazing-incidence wide-angle X-ray scattering, high-resolution/scanning transmission electron microscopy, and atomic force microscopy.

Influence of Weak Base Addition to Hole-Collecting Buffer Layers in Polymer:Fullerene Solar Cells

We report the effect of weak base addition to acidic polymer hole-collecting layers in normal-type polymer:fullerene solar cells. Varying amounts of the weak base aniline (AN) were added to solutions of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The acidity of the aniline-added PEDOT:PSS solutions gradually decreased from pH = 1.74 (AN = 0 mol %) to pH = 4.24 (AN = 1.8 mol %). The electrical conductivity of the PEDOT:PSS-AN films did not change much with the pH value, while the ratio of conductivity between out-of-plane and in-plane directions was dependent on the pH of solutions. The highest power conversion efficiency (PCE) was obtained at pH = 2.52, even though all devices with the PEDOT:PSS-AN layers exhibited better PCE than those with the pristine PEDOT:PSS layers. Atomic force microscopy investigation revealed that the size of PEDOT:PSS domains became smaller as the pH increased. The stability test for 100 h illumination under one sun condition disclosed that the PCE decay was relatively slower for the devices with the PEDOT:PSS-AN layers than for those with pristine PEDOT:PSS layers.

Flexible Thermal Sensors Based on Organic Field-Effect Transistors with Polymeric Channel/Gate-Insulating and Light-Blocking Layers

Here, we report flexible thermal sensors based on organic field-effect transistors (OFETs) that are fabricated using polymeric channel and gate-insulating layers on flexible polymer film substrates. Poly(3-hexylthiophene) and poly(methyl methacrylate) were used as the channel and gate-insulating layers, respectively, whereas indium-tin oxide-coated poly(ethylene naphthalate) films (thickness = 130 μm) were employed as the flexible substrates. Aluminum-coated polymer films were attached on top of the channel parts in the flexible OFETs to block any influence by light illumination. The present flexible OFET-based thermal sensors exhibited typical p-type transistor characteristics at a temperature range of 25–100 °C, while the hole mobility of devices was linearly increased with the temperature. The drain current could be amplified at various temperatures by adjusting the gate and drain voltages. In particular, stable sensing performances were measured during the repeated approaching/retreating cycle with a heat source. The flexible OFET thermal sensors attached on human fingers could sense heat from human fingers as well as from approaching objects.