N. Hari Babu

High intergranular critical currents in metallic MgB2 superconductor

Strong evidence for high intergranular critical current densities and large bulk magnetic flux pinning in superconducting polycrystalline MgB2 has been observed. The presence of strongly-coupled grain boundaries in this material has been confirmed by a dramatic collapse of the magnetic hysteresis loop when a bulk specimen is ground into a fine powder and re-measured under similar conditions. Further evidence for strong intergrain links in polycrystalline MgB2 is provided by the continuous variation of the remanent magnetic moment up to the full penetration field of a bulk sample. The absence of weak-link nature in this material has profound implications for its potential in a wide range of engineering applications.

Artificial flux pinning centers in large, single-grain (RE)-Ba-Cu-O superconductors

Second-phase, nanoscale inclusions of composition Y2Ba4CuMOy (M=U, Nb, Ta, W, Mo, and Re), which form artificial pinning centers, have been introduced into large, single-grain [rare-earth (RE)]-Ba-Cu-O superconductors. A significant improvement in critical current density is observed in these samples, due presumably to various combinations of normal conducting, paramagnetic, and geometrical properties of the Y2Ba4CuMOy particles in the superconducting (RE)Ba2Cu3O7−δ (RE-123) phase matrix. These Y2Ba4CuMOy phase particles are chemically stable in the Ba-Cu-O liquid during peritectic solidification, unlike Y2BaCuO5 (Y-211) phase particles in Y-Ba-Cu-O, which opens a processing window for the fabrication of nanostructured large, single-grain (RE)-Ba-Cu-O superconductors with enhanced flux pinning for high-field engineering applications.

Neutron irradiation of MgB2 bulk superconductors

Sintered samples of MgB2 were irradiated in a fission reactor. Defects in the bulk microstructure are produced during this process mainly by the 10B(n,α)7Li reaction while collisions of fast neutrons with the lattice atoms induce much less damage. Self-shielding effects turn out to be very important and lead to a highly inhomogeneous defect distribution in the irradiated samples. The resulting disorder enhances the normal state resistivity and the upper critical field. The irreversibility line shifts to higher fields at low temperatures and the measured critical current densities increase following irradiation.

Seeded infiltration and growth of large, single domain Y–Ba–Cu–O bulk superconductors with very high critical current densities

Single domain Y?Ba?Cu?O (YBCO) composed of a YBa2Cu3Oy (Y-123) superconducting bulk matrix with discrete, non-superconducting Y2BaCuO5 (Y-211) phase inclusions has been fabricated by a seeded infiltration and growth (IG) technique in the form of cylindrical pellets up to 32?mm in diameter. Sample shrinkage in the radial direction for single domains prepared by this technique is relatively low at 5% and independent of sample size, in contrast to the shrinkage observed in samples grown by conventional melt processing, which increases significantly with increasing sample diameter. Furthermore, samples grown by the IG technique exhibit low porosity of typically 0.9% of the bulk volume fraction, compared with a corresponding value of around 4.9% observed in samples fabricated by conventional melt processing. Fine Y-211 particles were observed to be embedded within the Y-123 superconducting matrix for the IG processed samples, leading to a high critical current density, Jc, of over 100?000?A?cm?2 at 77.3?K in self-field. The distribution of Y-211 particles in the IG sample microstructure, however, was inhomogeneous (unlike in previous reports), which leads to a variation in the spatial distribution of Jc. The volume fraction of Y-211 in the vicinity of the seed crystal (i.e.?corresponding to the initial c-sector growth stage), in particular, is typically around 5%, compared with a value of up to 30% in the a growth sectors more distant from the seed crystal (which corresponds well to the theoretical value for the sample composition studied here). The volume fraction of Y-211 inclusions in the c growth sector more distant from the seed was around 22%. Finally, a trend of the variation in the distribution of Y-211 particles in the Y-123 matrix grown by the IG technique was similar to that in sample grown by conventional melt processing.

A trapped field of >3 T in bulk MgB2 fabricated by uniaxial hot pressing

A trapped field of over 3 T has been measured at 17.5 K in a magnetized stack of two disc-shaped bulk MgB2 superconductors of diameter 25 mm and thickness 5.4 mm. The bulk MgB2 samples were fabricated by uniaxial hot pressing, which is a readily scalable, industrial technique, to 91% of their maximum theoretical density. The macroscopic critical current density derived from the trapped field data using the Biot–Savart law is consistent with the measured local critical current density. From this we conclude that critical current density, and therefore trapped field performance, is limited by the flux pinning available in MgB2, rather than by lack of connectivity. This suggests strongly that both increasing sample size and enhancing pinning through doping will allow further increases in trapped field performance of bulk MgB2.

Development of a generic seed crystal for the fabrication of large grain (RE)?Ba?Cu?O bulk superconductors

The critical current density, Jc, irreversibility field, Birr, and magnetic field trapping ability of (LRE)–Ba–Cu–O bulk superconductors, where LRE is a light rare earth element such as Nd, Sm, Eu and Gd, are generally superior to those of the more common melt-processed Y–Ba–Cu–O (YBCO). The lack of availability of a suitable seed crystal to grow large, single grain (LRE)–Ba–Cu–O superconductors with controlled orientation, however, has hindered severely the development of these materials for engineering applications over the past ten years. In this communication we report for the first time the development of a generic seed crystal that can be used to fabricate any rare earth (RE) based (RE)–Ba–Cu–O ((RE)BCO) superconductor in the form of a large single grain with controlled orientation. The new seed crystal will potentially enable large grain (LRE)–Ba–Cu–O bulk superconductors to be fabricated routinely, as is the case for YBCO. This will enable the field trapping and current-carrying characteristics of these materials to be explored in more detail than has been possible to date.

New chemically stable, nano-size artificial flux pinning centres in (RE)?Ba?Cu?O superconductors

Chemically stable, nanoscale (<50 nm) Y2Ba4CuMOy (M = Nb, Ta, W, Mo, Zr, Hf, etc,) phase inclusions, which potentially form a new type of artificial pinning centre, have been introduced successfully for the first time into large, single grain (RE)–Ba–Cu–O bulk superconductors.

Fabrication of large single-grain Y-Ba-Cu-O through infiltration and seeded growth processing

Large, single-grain Y–Ba–Cu–O (YBCO) was fabricated via the infiltration of Ba–Cu–O liquid into a precursor body composed of solid, porous Y 2 BaCuO 5 (Y-211) and observed to trap a magnetic field of 0.15 T at 77 K. In this process a NdBCO seed crystal was used to promote heterogeneous nucleation, which allows the fabrication of single-grain YBCO containing a uniform and very fine distribution of Y-211 inclusions in the YBa 2 Cu 3 O 7−δ (Y-123) matrix without the addition of Pt. These superior microstructural features and significant field trapping ability compared with samples processed by conventional top-seeded melt growth suggest this technique could be a practical alternative for processing large, single-grain superconductors for engineering applications.

Behavior of bulk high-temperature superconductors of finite thickness subjected to crossed magnetic fields : Experiment and model

Crossed-magnetic-field effects on bulk high-temperature superconductors have been studied both experimentally and numerically. The sample geometry investigated involves finite-size effects along both (crossed-)magnetic-field directions. The experiments were carried out on bulk melt-processed Y-Ba-Cu-O single domains that had been premagnetized with the applied field parallel to their shortest direction (i.e., the

The effect of Y-211 precursor particle size on the microstructure and properties of Y?Ba?Cu?O bulk superconductors fabricated by seeded infiltration and growth

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