N. Nishi

Balloon-borne observations of water vapor and ozone in the tropical upper troposphere and lower stratosphere

[1]xa0Balloon-borne observations of frost-point temperature and ozone in the equatorial western, central and eastern Pacific as well as over equatorial eastern Brazil provide a highly accurate data set of water vapor across the tropical tropopause. Data were obtained at San Cristobal, Galapagos, Ecuador (0.9°S, 89.6°W), during the late northern winter and the late northern summer in 1998 and 1999 and at Juazeiro do Norte, Brazil (7.2°S, 39.3°W), in February and November 1997. Earlier data in the western Pacific region in March 1993 were reanalyzed to extend the scope of the observations. The data show three different circumstances in which saturation or supersaturation occurs and imply different mechanisms for dehydration at the tropical tropopause: (1) convective dehydration, (2) slow-ascent dehydration, and (3) large-scale wave-driven dehydration. Furthermore, air that crosses the tropical tropopause in the late northern summer may be dehydrated further during late northern fall, as the average tropical tropopause rises and cools. Not all soundings show dehydration, and there are clear differences in the frequency and depth of saturation in different regions and seasons. The tropopause transition region can be identified in accurate measurements of relative humidity, even under conditions where ozone observations are ambiguous. Deep convection plays an important role in setting up this transition region, which is then subject to large-scale wave activity and wave breaking at the tropopause or midlatitude intrusions. High relative humidities over regions of strong subsidence show that descending motion in the troposphere is limited to levels below the transition region.

Correlations and emission ratios among bromoform, dibromochloromethane, and dibromomethane in the atmosphere

[1] Bromoform (CHBr 3 ), dibromochloromethane (CHBr 2 Cl), and dibromomethane (CH 2 Br 2 ) in the atmosphere were measured at various sites, including tropical islands, the Arctic, and the open Pacific Ocean. Up to 40 ppt of bromoform was observed along the coasts of tropical islands under a sea breeze. Polybromomethane concentrations were highly correlated among the coastal samples, and the ratios CH 2 Br 2 /CHBr 3 and CHBr 2 Cl/ CHBr 3 showed a clear tendency to decrease with increasing CHBr 3 concentration. These findings are consistent with the observations that polybromomethanes are emitted mostly from macroalgae whose growth is highly localized to coastal areas and that CHBr 3 has the shortest lifetime among these three compounds. The relationship between the concentration ratios CHBr 3 /CH 2 Br 2 and CHBr 2 Cl/CH 2 Br 2 suggested a large mixing/ dilution effect on bromomethane ratios in coastal regions and yielded a rough estimate of 9 for the molar emission ratio of CHBr 3 /CH 2 Br 2 and of 0.7 for that of CHBr 2 Cl/CH 2 Br 2 . Using these ratios and an global emission estimate for CH 2 Br 2 (61 Gg/yr (Br)) calculated from its background concentration, the global emission rates of CHBr 3 and CHBr 2 Cl were calculated to be approximately 820(±310) Gg/yr (Br) and 43(±16) Gg/yr (Br), respectively, assuming that the bromomethanes ratios measured in this study are global representative. The estimated CHBr 3 emission is consistent with that estimated in a very recent study by integrating the sea-to-air flux database. Thus the contribution of CHBr 3 and CHBr 2 Cl to inorganic Br in the atmosphere is likely to be more important than previously thought.

Emission estimates of selected volatile organic compounds from tropical savanna burning in northern Australia

[i] Here we present measurements of a range of carbon-based compounds: carbon dioxide (CO 2 ), carbon monoxide (CO), methane (CH 4 ), nonmethane hydrocarbons (NMHCs), methyl halides, and dimethyl sulfide (DMS) emitted by Australian savanna fires studied as part of the Biomass Burning and Lightning Experiment (BIBLE) phase B aircraft campaign, which took place during the local late dry season (28 August to 13 September 1999). Significant enhancements of short-lived NMHCs were observed in the boundary layer (BL) over the region of intensive fires and indicate recent emissions for which the mean transport time was estimated to be about 9 hours. Emission ratios relative to CO were determined for 20 NMHCs, 3 methyl halides, DMS, and CH 4 based on the BL enhancements in the source region. Tight correlations with CO were obtained for most of those compounds, indicating the homogeneity of the local savanna source. The emission ratios were in good agreement with some previous measurements of savanna fires for stable compounds but indicated the decay of emission ratios during transport for several reactive compounds. Based on the observed emission ratios, emission factors were derived and compared to previous studies. While emission factors (g species/kg dry mole) of CO 2 varied little according to the vegetation types, those of CO and NMHCs varied significantly. Higher combustion efficiency and a lower emission factor for methane in this study, compared to forest fires, agreed well with results for savanna fires in other tropical regions. The amount of biomass burned was estimated by modeling methods using available satellite data, and showed that 1999 was an above average year for savanna burning. The gross emissions of the trace gases from Australian savanna fires were estimated.

Seasonal to Decadal Variations of Water Vapor in the Tropical Lower Stratosphere Observed with Balloon-Borne Cryogenic Frost Point Hygrometers

[1]xa0We investigated water vapor variations in the tropical lower stratosphere on seasonal, quasi-biennial oscillation (QBO), and decadal time scales using balloon-borne cryogenic frost point hygrometer data taken between 1993 and 2009 during various campaigns including the Central Equatorial Pacific Experiment (March 1993), campaigns once or twice annually during the Soundings of Ozone and Water in the Equatorial Region (SOWER) project in the eastern Pacific (1998–2003) and in the western Pacific and Southeast Asia (2001–2009), and the Ticosonde campaigns and regular sounding at Costa Rica (2005–2009). Quasi-regular sounding data taken at Costa Rica clearly show the tape recorder signal. The observed ascent rates agree well with the ones from the Halogen Occultation Experiment (HALOE) satellite sensor. Average profiles from the recent five SOWER campaigns in the equatorial western Pacific in northern winter and from the three Ticosonde campaigns at Costa Rica (10°N) in northern summer clearly show two effects of the QBO. One is the vertical displacement of water vapor profiles associated with the QBO meridional circulation anomalies, and the other is the concentration variations associated with the QBO tropopause temperature variations. Time series of cryogenic frost point hygrometer data averaged in a lower stratospheric layer together with HALOE and Aura Microwave Limb Sounder data show the existence of decadal variations: The mixing ratios were higher and increasing in the 1990s, lower in the early 2000s, and probably slightly higher again or recovering after 2004. Thus linear trend analysis is not appropriate to investigate the behavior of the tropical lower stratospheric water vapor.

Ozonesonde observations at Christmas Island (2°N, 157°W) in the equatorial central Pacific

[1]xa0Ozone and water vapor observations have been conducted at Christmas/Kiritimati Island (2°N, 157°W) in the equatorial central Pacific as a part of the Soundings of Ozone and Water in the Equatorial Region (SOWER)/Pacific mission. We launched 33 ozonesondes and 33 chilled-mirror hygrometers in nine observation campaigns from 1999 to 2003 for various seasons. We found that ozone concentrations at Christmas Island are low in the whole troposphere (∼10–35 ppbv), particularly in the marine boundary layer (MBL). Ozone variation is small throughout the year compared with other tropical stations, though annual and interannual variations of meteorological fields are large over the equatorial central Pacific. Just below the tropopause, during the August 2002 campaign, we observed substantially reduced ozone concentrations (<10 ppbv) similar to those found in the MBL, which are maintained at least for the observation period. From meteorological conditions, we found that air mass was advected from the Inter-Tropical Convergence Zone (ITCZ), located to the north of Christmas Island, in accordance with the northeasterly wind that is only observed during northern summer in the upper troposphere. The origin of air mass is supposed to be from the MBL in the ITCZ.

Cirrus cloud appearance in a volcanic aerosol layer around the tropical cold point tropopause over Biak, Indonesia, in January 2011

[1]xa0An aerosol layer was found 1–2 km around the tropical cold point tropopause by observations using ground-based lidar and balloon-borne optical particle counters (OPC) over Biak, Indonesia, in January 2011. The layer was observed throughout the survey period from 6 to 13 January. The backscattering coefficient of the layer was about 5 times larger than that of the background aerosols. The lidar-observed depolarization ratio of the layer was very low, and the wavelength dependence of the backscattering coefficients of the layer was similar to that of stratospheric aerosols. A layer of the particles at the size of the accumulation mode was also observed by an OPC at ambient temperature, but the particles were volatile at 200°C. These properties indicate that the aerosol layer was composed of liquid phase aqueous sulfuric acid solution particles and probably originated from a volcanic eruption. It was observed by lidar that a thin cirrus cloud layer appeared within this aerosol layer. Backward trajectory analysis and satellite-observed equivalent blackbody temperature indicate that the cirrus cloud layer probably formed in situ. The estimated upper limit of the number concentration of cloud particles was 105 m−3. The number concentration of the volatile aerosol particles (∼3 × 106 m−3) was 30 times larger than this upper limit. This upper limit, however, is comparable to the aerosol particle concentration observed by the OPC at 200°C. These results are consistent with the cirrus cloud formation with solid sulfate particles in tropical upper troposphere suggested by previous studies.