N.O. Cabrera

Fatigue Properties of Highly Oriented Polypropylene Tapes and All-Polypropylene Composites

This paper describes the fatigue behaviour of newly developed all-polypropylene (all-PP) tapes and composites, with reference to the composite processing conditions, testing temperature and making a comparison with commercial alternatives. All-PP tapes are highly oriented and their failure behaviour follows that of other highly oriented polymers. All-PP woven composites fail ultimately due to PP tape failure. However, this failure mode is accompanied by delamination of fabrics in the woven structure. Consolidation pressure plays a decisive role in controlling the interlaminar properties and hence the delamination resistance and furthermore the fatigue limit of the composite. Comparison of all-PP woven composites with commercial alternatives based on glass and natural fibres reveals the excellent relative performance of all-PP composites under fatigue loads. Fatigue properties of all-PP composites are however sensitive to the testing temperature, and elevated temperatures can lead to a rapid reduction of the fatigue resistance of these all-polymer systems.

Processing of all-polypropylene composites for ultimate recyclability

Abstract This paper describes the development of so-called all-polypropylene composites, namely polypropylenes (PPs) reinforced with oriented polypropylene fibres rather than glass or natural fibres. These all-polypropylene composites have specific economic and ecological advantages since, upon recycling, a polypropylene blend is obtained that can be reused to make all-PP composites again or, alternatively, be used for other PP-based applications. One of the main challenges in the development of all-PP composites is to create a processing window that is large enough to keep the oriented PP reinforcement intact while this is combined or impregnated with PP resin. The technological breakthrough in the processing of all-PP composite that has been established is based on the hot compaction (welding) of coextruded tapes. These coextruded tapes consist of an oriented polymer core, providing strength and stiffness, and a polymer skin with a lower melting temperature than the core material forming the matrix and bonding the tapes together. Consolidation is achieved by simply ‘welding’ the tapes together, thus avoiding typical impregnation problems encountered in traditional thermoplastic composite manufacturing. Pilot studies have already shown the potential of a wide range of manufacturing technologies including thermoforming and filament winding.