Naiara Fernández

Fold patterns and multilayer rheology of the Lurestan Province, Zagros Simply Folded Belt (Iran)

Abstract: Anticlines of the Lurestan Province in the Zagros fold–thrust belt have been studied by integrating field-based analysis with the use of high-resolution satellite images and data available from the literature. The distribution of folds in the southeastern Lurestan Province, expressed in terms of axial length and wavelength distribution, shows a direct link with the characteristics of the sedimentary multilayer in which the folds developed. Within the carbonate deposits of the Late Cretaceous Bangestan Group the transition from pelagic to neritic facies determines a threefold increase in anticline spacing and promotes the development of thrust structures in the forelimb of anticlines. The Oligocene–Miocene Shahbazan–Asmari unit folds harmonically with the Bangestan Group, except in the areas where the Palaeogene deposits interposed between the two units exceed 1300 m of thickness. In these areas the Shahbazan–Asmari carbonates display short-wavelength folds indicating a complete decoupling from the underlying folds of the Bangestan Group. It is suggested that this decoupling occurs because the summed thickness of the incompetent units separating the two carbonate units exceeds the extension of the zone of effective contact strain of the Bangestan Group folds.

Sub-seismic fractures in foreland fold and thrust belts: insight from the Lurestan Province, Zagros Mountains, Iran

ABSTRACT The Simply Folded Belt of the Zagros Mountains, Iran, is a spectacularly well-exposed example of a foreland fold and thrust belt. A regional analysis of the Cenomanian–Coniacian Sarvak and Ilam Formations, exposed in the southern Lurestan Province, is presented as a case study for sub-seismic fracture development in this type of compressive setting. The area is characterized by gentle to tight anticlines and synclines parallel to the NW–SE trend of the belt. In the Lurestan Province, the Cenomanian–Coniacian interval is exposed in the core of most of the outcropping anticlines. Fold style is intimately related to both vertical and lateral facies distribution. Geometry, kinematics and timing of sub-seismic fractures were characterized through extensive fieldwork, interpretation of orthorectified QuickBird imagery and interpretation of 3D photorealistic models derived from LiDAR. Data were collected from 12 anticlines covering an area of approximately 150 × 200 km. Key outcrops for understanding fracture geometry, kinematics and timing are presented. Field observations and interpretation of QuickBird and 3D photorealistic models reveal the complexity of fracture geometry and timing. Fractures record pre-, syn- and post-folding stages of deformation. Pre-folding structures include synsedimentary normal faults, and subsequent small-scale thrusts, systematic veins and stylolites. During folding, pre-existing fracture planes were re-activated and through-going fractures and reverse faults developed. Strike-slip faults typically postdate pre- and syn-folding structures and are probably related to the late stages of fold tightening. All structures are geometrically and kinematically consistent with the trend of the Arabian passive margin and its subsequent tectonic inversion.

Basin architecture and growth folding of the NW Zagros early foreland basin during the Late Cretaceous and early Tertiary

Abstract: We present and use the chronostratigraphy of 13 field logs and detailed mapping to constrain the evolution of the early Zagros foreland basin, in NW Iran. Large foraminifera, calcareous nannofossil, palynological and 87Sr/86Sr analysis supplied ages indicating a Campanian–early Eocene age of the basin infill, which is characterizd by a diachronous, southwestward migrating, shallowing upwards, mixed clastic–carbonate succession. Growth synclines and local palaeoslope variations indicate syndepositional folding from Maastrichtian to Eocene time and suggest forelandward migration of the deformation front. We also illustrate the basin architecture with a synthetic stratigraphic transect. From internal to external areas, time lines cross the formation boundaries from continental Kashkan red beds to Taleh Zang mixed clastic–carbonate platforms, Amiran slope deposits and basinal Gurpi–Pabdeh shales and marls. The foreland basin depocentres show a progressive migration from the Campanian to Eocene (c. 83–52.7 Ma), with rates of c. 2.4 mm a−1 during the early–middle Palaeocene (c. 65.5–58.7 Ma) increasing to c. 6 mm a−1 during the late Palaeocene–earliest Eocene (c. 58.7–52.8 Ma). Coeval subsidence remained at c. 0.27 mm a−1 during the first 12.7 Ma and decreased to c. 0.16 mm a−1 during the last 4.2 Ma of basin filling. Finally, we integrate our results with published large-scale maps and discuss their implications in the context of the Zagros orogeny. Supplementary material: Tables with dating results are available at http://www.geolsoc.org.uk/SUP18439.

From outcrop to 3D modelling: a case study of a dolomitized carbonate reservoir, Zagros Mountains, Iran

ABSTRACT Outcrop data derived from fieldwork, remote sensing satellite and LiDAR-derived 3D models were used to build an integrated dual porosity-permeability static reservoir model which captured stratigraphic, diagenetic and structural heterogeneities. The study focuses upon the Mishrif-Mauddud/Sarvak interval, one of the most prolific reservoir units in the Middle East. The study area is exceptionally well exposed in deep gorges which cut transversally across anticlines of the Simply Folded Belt of the Zagros Mountains. The outcrops reveal volumetrically significant dolomitization of the latest Albian to Turonian carbonates of the Lower and Upper Sarvak formations. Three different dolomite bodies, which are spatially connected and genetically linked to the same fluid flow event, were recognized and mapped: (1) a thick dolomite body replacing the Lower Sarvak and forming a massive dolomite core; (2) horizontally extensive stratabound dolomite bodies (sheets), emanating laterally from the massive dolomite; and (3) vertically elongated dolomite pipes, rooted in the massive dolomite and typically replacing slope facies of the Upper Sarvak Formation. The widespread development of tight, non-planar dolomite textures (a typical feature of high temperature dolomitization) drastically reduces the reservoir potential of the dolomitized geobody in the study area. In particular, this is present in the massive dolomitized body. Vuggy porosity seems to increase porosity only locally and to a limited extent, developing a non-connected pore network. The dominant porous dolomite textures are more abundant in the peripheral part of the geobody (dolomite sheets), where they are strongly controlled by precursor facies and diagenesis. Three main dolomite pore types were identified (intercrystalline, interparticle and mouldic), linked to the depositional environment of the precursor limestone. These pore types were used for petrophysical modelling. The approach adopted in this study allowed the distribution of rock properties in the dolomitized geobody to mimic the main depositional facies architecture. The study area is characterized by a simple fracture network. Two main fracture sets and two major sets of conjugate normal faults were recognized in the field and mapped on 3D virtual outcrop data. Non-stratabound fracture density varied according to stratigraphic unit and/or dolomite body type (pipes/massive/sheets), showing a general increase from precursor limestone to dolomite. Fracture density also varied according to distance from faults (fault damage zone). This was particularly true in the limestone. The data also showed a prominent increase in fracture height from limestone to dolomite bodies, indicating that the dolomitized geobodies are likely sites for high production and early water breakthrough.

Reservoir characteristics of fault-controlled hydrothermal dolomite bodies: Ramales Platform case study

Abstract Hydrothermal dolomite (HTD) bodies are known as high-quality hydrocarbon reservoirs; however few studies focus on the geometry and distribution of reservoir characteristics. Across the platform-to-basin transition of the Ramales Platform, fault-controlled HTD bodies are present. Three kinds of bodies can be distinguished based on their morphology, that is, elongated HTD corridors, a massive HTD body (Pozalagua body) and an HTD-cemented breccia body. The differences in size and shape of the HTD bodies can be attributed to differences in local structural setting. For the Pozalagua body, an additional sedimentological control is invoked to explain the difference in HTD geometry. A (geo)-statistical investigation of the reservoir characteristics in the Pozalagua body revealed that the HTD types (defined based on their texture) show spatial clustering controlled by the orientation of faults, joints and the platform edge. Porosity and permeability values are distributed in clusters of high and low values; however, they are not significantly different for the three HTD types. Two dolomitization phases (i.e. ferroan and non-ferroan) can be observed in all HTD bodies. In general, the HTDs resulting from the second non-ferroan dolomitization phase have lower porosity values. No difference in permeability is found for the ferroan and non-ferroan dolomites.

Polymeric Redox Active Electrodes for Sodium Ion Batteries

Polymer binding agents are critical for the good performance of the electrodes of Na- and Li-ion batteries during cycling as they hold the electroactive material together to form a cohesive assembly because of their mechanical and chemical stability as well as adhesion to the current collector. New redox-active polymer binders that insert Na+ ions and show adhesion properties were synthesized by adding polyether amine blocks (Jeffamine) based on mixed propylene oxide and ethylene oxide blocks to p-phenylenediamine and terephthalaldehyde units to form electroactive Schiff-base groups along the macromolecule. The synthetic parameters and the electrochemical properties of these terpolymers as Na-ion negative electrodes in half cells were studied. Reversible capacities of 300 mAh g-1 (50 wt % conducting carbon) and 200 mAh g-1 (20 wt % conducting carbon) were achieved in powder and Cu-supported electrodes, respectively, for a polySchiff-polyether terpolymer synthesized by using a poly(ethylene oxide) block of 600 g mol-1 in place of one third of the aniline units. The new redox-active polymers were also used as a binding agent of another anode material (hard carbon), which led to an increase of the total capacity of the electrode compared to that prepared with other standard fluorinated polymer binders such as poly(vinylidene) fluoride.

Combining galvanic displacement and in situ polymerization in a new synthesis: micro-composite materials for Li-based batteries

Composite electrode materials offer some of the best electrochemical performances available for Li-based batteries. However, the development of economical and scalable synthetic methods for their production remains a significant challenge, especially for submicron and nano-sized composites. In this work, we demonstrate a novel synthetic method which combines galvanic displacement and cationic polymerization in a one-pot synthesis. The materials obtained are Sn-based organic–inorganic micro-composites whose morphology and chemical composition can be altered by changing a few key synthetic parameters. Extensive characterization of the materials by micro-analytical and bulk methods (SEM-SE, SEM-BSE, SEM-EDS, XRD, ATR-FTIR, TGA-DSC, ICP, and SSNMR), revealed the presence of crystalline phases of Sn, of Li-containing Sn-alloys, other crystalline inorganic phases, and carbonate-based polymer. Preliminary electrochemical evaluation revealed that the Sn-containing micro-composite shows better stability than commercial micro-crystalline Sn when cycled in a lithium half-cell.

Fault & Fracture Development in Foreland Fold and Thrust Belts - Insight from the Lurestan Province, Zagros Mountains, Iran

G. Casini* (StatoilHydro Research Center), J. Verges (Institute of Earth Sciences), I. Romaire (Institute of Earth Sciences), N. Fernandez (Institute of Earth Sciences), E. Casciello (Institute of Earth Sciences), S. Homke (StatoilHydro Research Center), E. Saura (StatoilHydro Research Center), J.C. Embry (StatoilHydro Research Center), D.W. Hunt (StatoilHydro Research Center), P. Gillespie (StatoilHydro), L. Aghajari (NIOC), H. Noroozi (NIOC), M. Sedigh (NIOC) & J. Bagheri (NIOC)

Fracture Distribution of a Non-cylindrical Anticline Located on a Major Basement Fault

The fracture and fault distribution along a sigmoidal shaped anticline of the Zagros mountain range of Iran was studied integrating field analysis with remote sensing data. Different generations of fracturing/faulting have been recognised, based on cross cutting relationships, which span from pre to post folding.

Geological Mapping and Structural Interpretation Using a Virtual Outcrop Digitiser, Examples from the Zagros (Iran)

A vast region of the Lurestan Province of the Zagron ountain range (Iran) was studied integrating conventional geological surveys with the use of a virtual digitiser (VOD) employing high resolution satellite images. Examples are shown of the potentialities of this tool.