Nanase Harada

The 2014 KIDA network for interstellar chemistry

Chemical models used to study the chemical composition of the gas and the ices in the interstellar medium are based on a network of chemical reactions and associated rate coefficients. These reacti ...

Submillimeter ALMA Observations of the Dense Gas in the Low-Luminosity Type-1 Active Nucleus of NGC1097

We present the first 100 pc scale view of the dense molecular gas in the central ~ 1.3 kpc region of the type-1 Seyfert NGC 1097 traced by HCN (J=4-3) and HCO+ (J=4-3) lines afforded with ALMA band 7. This galaxy shows significant HCN enhancement with respect to HCO+ and CO in the low-J transitions, which seems to be a common characteristic in AGN environments. Using the ALMA data, we study the characteristics of the dense gas around this AGN and search for the mechanism of HCN enhancement. We find a high HCN (J=4-3) to HCO+ (J=4-3) line ratio in the nucleus. The upper limit of the brightness temperature ratio of HCN (v2=1^{1f}, J=4-3) to HCN (J=4-3) is 0.08, which indicates that IR pumping does not significantly affect the pure rotational population in this nucleus. We also find a higher HCN (J=4-3) to CS (J=7-6) line ratio in NGC 1097 than in starburst galaxies, which is more than 12.7 on the brightness temperature scale. Combined from similar observations from other galaxies, we tentatively suggest that this ratio appears to be higher in AGN-host galaxies than in pure starburst ones similar to the widely used HCN to HCO+ ratio. LTE and non-LTE modeling of the observed HCN and HCO+ lines using J=4-3 and 1-0 data from ALMA, and J=3-2 data from SMA, reveals a high HCN to HCO+ abundance ratio (5 < [HCN]/[HCO+] < 20: non-LTE analysis) in the nucleus, and that the high-J lines (J=4-3 and 3-2) are emitted from dense (10^{4.5} < n_H2 [/cc] < 10^6), hot (70 < Tkin [K] < 550) regions. Finally we propose that the high temperature chemistry is more plausible to explain the observed enhanced HCN emission in NGC 1097 than the pure gas phase PDR/XDR chemistry.

Carbon and oxygen isotope ratios in starburst galaxies: New data from NGC 253 and Mrk 231 and their implications

Carbon and oxygen isotope ratios are excellent measures of nuclear processing, but few such data have been taken toward extragalactic targets so far. Therefore, using the IRAM 30-m telescope, CN and CO isotopologues have been measured toward the nearby starburst galaxy NGC 253 and the prototypical ultraluminous infrared galaxy Mrk 231. Toward the center of NGC 253, the CN and (CN)-C-13 N = 1 -> 0 lines indicate no significant deviations from expected local thermodynamical equilibrium after accounting for moderate saturation effects (10 and 25%) in the two detected spectral components of the main species. Including calibration uncertainties, which dominate the error budget, the C-12/C-13 ratio becomes 40 +/- 10. This is larger than the ratio in the central molecular zone of the Galaxy, suggesting a higher infall rate of poorly processed gas toward the central region. Assuming that the ratio also holds for the CO emitting gas, this yields O-16/O-18 = 145 +/- 36 and O-16/O-17 = 1290 +/- 365 and a S-32/S-34 ratio close to the one measured for the local interstellar medium (2025). No indication of vibrationally excited CN is found in the lower frequency fine structure components of the N = 1 -> 0 and 2 -> 1 transitions at rms noise levels of 3 and 4 mK (15 and 20 mJy) in 8.5 km s-1 wide channels. Peak line intensity ratios between NGC 253 and Mrk 231 are similar to 100 for (CO)-C-12-O-16 and (CO)-C-12-O-18 J = 1 -> 0, while the ratio for (CO)-C-13-O-16 J = 1 -> 0 is similar to 250. This and similar (CO)-C-13 and (CO)-O-18 line intensities in the J = 1 -> 0 and 2 -> 1 transitions of Mrk 231 suggest C-12/C-13 similar to 100 and O-16/O-18 similar to 100, in agreement with values obtained for the less evolved ultraluminous merger Arp 220. Also, when accounting for other (scarcely available) extragalactic data, C-12/C-13 ratios appear to vary over a full order of magnitude, from >100 in ultraluminous high redshift galaxies to similar to 100 in more local such galaxies to similar to 40 in weaker starbursts that are not undergoing a large scale merger to 25 in the central molecular zone of the Milky Way. With C-12 being predominantly synthesized in massive stars, while C-13 is mostly ejected by longer lived lower mass stars at later times, this is qualitatively consistent with our results of decreasing carbon isotope ratios with time and rising metallicity. It is emphasized, however, that both infall of poorly processed material, initiating a nuclear starburst, and the ejecta from newly formed massive stars (in particular in the case of a top-heavy stellar initial mass function) can raise the carbon isotope ratio for a limited amount of time.

Exploring the molecular chemistry and excitation in obscured luminous infrared galaxies - An ALMA mm-wave spectral scan of NGC 4418

Context. Extragalactic observations allow the study of molecular chemistry and excitation under physical conditions which may differ greatly from those found in the Milky Way. The compact, obscured nuclei (CON) of luminous infrared galaxies (LIRG) combine large molecular columns with intense infrared (IR), ultra-violet (UV), and X- radiation and represent ideal laboratories for the study of the chemistry of the interstellar medium (ISM) under extreme conditions. Aims. Our aim was to obtain for the first time a multi-band spectral scan of a LIRG, and to derive molecular abundances and excitation to be compared to other Galactic and extragalactic environments. Methods. We obtained an ALMA Cycle 0 spectral scan of the dusty LIRG NGC 4418, spanning a total of 70.7 GHz in bands 3, 6, and 7. We use a combined local thermal equilibrium (LTE) and non-LTE (NLTE) fit of the spectrum in order to identify the molecular species and to derive column densities and excitation temperatures. We derive molecular abundances and compare them with other Galactic and extragalactic sources by means of a principal component analysis. Results. We detect 317 emission lines from a total of 45 molecular species, including 15 isotopic substitutions and 6 vibrationally excited variants. Our LTE/NLTE fit find kinetic temperatures from 20 to 350 K, and densities between 105 and 107 cm-3. The spectrum is dominated by vibrationally excited HC3N, HCN, and HNC, with vibrational temperatures from 300 to 450 K. We find that the chemistry of NCG 4418 is characterized by high abundances of HC3N, SiO, H2S, and c-HCCCH but a low CH3OH abundance. A principal component analysis shows that NGC 4418 and Arp 220 share very similar molecular abundances and excitation, which clearly set them apart from other Galactic and extragalactic environments. Conclusions. Our spectral scan confirms that the chemical complexity in the nucleus of NGC 4418 is one of the highest ever observed outside our Galaxy. The similar molecular abundances observed toward NCG 4418 and Arp 220 are consistent with a hot gas-phase chemistry, with the relative abundances of SiO and CH3OH being regulated by shocks and X-ray driven dissociation. The bright emission from vibrationally excited species confirms the presence of a compact IR source, with an effective diameter smaller than 5 pc and brightness temperatures higher than 350 K. The molecular abundances and the vibrationally excited spectrum are consistent with a young AGN/starburst system. We suggest that NGC 4418 may be a template for a new kind of chemistry and excitation, typical of CON. Because of the narrow line widths and bright molecular emission, NGC 4418 is the ideal target for further studies of the chemistry in CONs.

The unbearable opaqueness of Arp220

We explore the potential of imaging vibrationally excited molecular emission at high angular resolution to better understand the morphology and physical structure of the dense gas in Arp~220 and to gain insight into the nature of the nuclear powering sources. Vibrationally excited emission of HCN is detected in both nuclei with a very high ratio relative to the total

SUBMILLIMETER-HCN DIAGRAM FOR ENERGY DIAGNOSTICS IN THE CENTERS OF GALAXIES

L_{FIR}

A multi-transition study of molecules toward NGC 1068 based on high-resolution imaging observations with ALMA

, higher than in any other observed galaxy and well above what is observed in Galactic hot cores. HCN

Chemical features in the circumnuclear disk of the Galactic center

v_2=1f

ALMA Astrochemical Observations of the Infrared-luminous Merger NGC 3256

is observed to be marginally resolved in

Diverse Nuclear Star-forming Activities in the Heart of NGC 253 Resolved with 10-pc-scale ALMA Images

\sim60\times50