Nele De Belie

Bio-deposition of a calcium carbonate layer on degraded limestone by Bacillus species

To obtain a restoring and protective calcite layer on degraded limestone, five different strains of the Bacillus sphaericus group and one strain of Bacillus lentus were tested for their ureolytic driven calcium carbonate precipitation. Although all the Bacillus strains were capable of depositing calcium carbonate, differences occurred in the amount of precipitated calcium carbonate on agar plate colonies. Seven parameters involved in the process were examined: calcite deposition on limestone cubes, pH increase, urea degrading capacity, extracellular polymeric substances (EPS)-production, biofilm formation, ζ-potential and deposition of dense crystal layers. The strain selection for optimal deposition of a dense CaCO3 layer on limestone, was based on decrease in water absorption rate by treated limestone. Not all of the bacterial strains were effective in the restoration of deteriorated Euville limestone. The best calcite precipitating strains were characterised by high ureolytic efficiency, homogeneous calcite deposition on limestone cubes and a very negative ζ-potential.

Self-Healing in Cementitious Materials—A Review

Concrete is very sensitive to crack formation. As wide cracks endanger the durability, repair may be required. However, these repair works raise the life-cycle cost of concrete as they are labor intensive and because the structure becomes in disuse during repair. In 1994, C. Dry was the first who proposed the intentional introduction of self-healing properties in concrete. In the following years, several researchers started to investigate this topic. The goal of this review is to provide an in-depth comparison of the different self-healing approaches which are available today. Among these approaches, some are aimed at improving the natural mechanism of autogenous crack healing, while others are aimed at modifying concrete by embedding capsules with suitable healing agents so that cracks heal in a completely autonomous way after they appear. In this review, special attention is paid to the types of healing agents and capsules used. In addition, the various methodologies have been evaluated based on the trigger mechanism used and attention has been paid to the properties regained due to self-healing.

Self-healing cementitious materials by the combination of microfibres and superabsorbent polymers

Concrete cracks due to its low tensile strength. The presence of cracks endangers the durability as they generate a pathway for harmful particles dissolved in fluids and gases. Without a proper treatment, maintenance costs will increase. Self-healing can prevail in small cracks due to precipitation of calcium carbonate and further hydration. Therefore, the use of microfibres is proposed to control the crack width and thus to promote the self-healing efficiency. In the current research, crack sealing is also enhanced by the application of superabsorbent polymers. When cracking occurs, superabsorbent polymers are exposed to the humid environment and swell. This swelling reaction seals the crack from intruding potentially harmful substances. Mortar mixtures with microfibres and with and without superabsorbent polymers were investigated on their crack sealing and healing efficiency. Regain in mechanical properties upon crack healing was investigated by the performance of four-point-bending tests, and the sealing capacity of the superabsorbent polymer particles was measured through a decrease in water permeability. In an environment with a relative humidity of more than 60%, only samples with superabsorbent polymers showed healing. Introducing 1 m% of superabsorbent polymer gives the best results, considering no reduction of the mechanical properties in comparison to the reference, and the superior self-sealing capacity.

INFLUENCE OF POLYMER ADDITION ON BIOGENIC SULFURIC ACID ATTACK OF CONCRETE

A simple and reproducible microbiological simulation procedure in combination with a chemical procedure was used to test concrete for its potential resistance towards biogenic sulfuric acid. Concerning fundamental aspects of the corrosion reaction, it was shown that particularly the penetration of H2S inside the concrete crevices accelerated the corrosion process. The influence of different polymer types and silica fume additions on the resistance of the concrete samples was determined. The addition of the styrene acrylic ester polymer resulted in an increased resistance while the addition of the acrylic polymer or silica fume caused less resistant concrete. For the vinylcopolymer and the styrene butadiene polymer, no significant effect was observed on the resistance of the concrete samples. The results of the two different test methods confirmed the difference between corrosion due to purely chemical sulfuric acid and corrosion due to microbiologically produced sulfuric acid.

Influence of the cement type on the resistance of concrete to feed acids

Abstract Concrete in animal houses is subject to aggressive substances from feed and manure. Chemical attack by the most important feed acids, lactic and acetic acid and abrasion caused by animals and cleaning, were simulated and studied using accelerated corrosion tests. The resistance of concrete prisms with different cement types and approximately constant water-to-cement ratio, to simulation liquids with different pH-values, was investigated. The decrease of volume in terms of percentage and the mass loss per unit area were measured, as well as the pH-change and calcium content of the liquids. It appeared that the cement type had an important influence on concrete resistance in the highly to very highly aggressive simulation liquids. Four groups with decreasing vulnerability to the attack were distinguished: portland cement without C3A, ordinary portland cement, cement containing fly ashes, blastfurnace slag cement. The percentage of slag in the slag cement and the cement content of the pozzolanic cement had no significant influence.

Performance of cement-based materials in aggressive aqueous environments

Concrete and cement-based materials must operate in increasingly aggressive aqueous environments, which may be either natural or Industrial. These materials may suffer degradation in which ion addition and/or ion exchange reactions occur, leading to a breakdown of the matrix microstructure and consequent weakening. Sometimes this degradation can be extremely rapid and serious such as in acidic environments, while in other cases degradation occurs over long periods. Consequences of material failure are usually severe - adversely affecting the health and well-being of human communities and distrurbing ecological balances. there are also large direct costs of maintaining and replacing deteriorated infrastructure and indirect costs from loss of production during maintenance work, which place a great burden on society. The focus of this book is on addressing issues concerning performance of cement-based materials in aggressive aqueous environments, by way of this State-of-the-art Report. The book represents the work of many well-known and respected authors who contributed chapters or parts of chapters. Four main themes were addressed : I. Nature and kinetics of degradation and deterioration mechanisms of cement-based materials in aggressive aqueous environments. II. Modelling of deterioration in such environments. III. Test methodes to assess performance of cement-based materials in such environments, and which can be used to characterise and rate relative performance and inform long term predictions. IV. Engineering implications and consequences of deterioration in aggressive aqueous environments, and engineering approaches to the problem.

Influence of Pore Structure on the Effectiveness of a Biogenic Carbonate Surface Treatment for Limestone Conservation

ABSTRACT A ureolytic biodeposition treatment was applied to five types of limestone in order to investigate the effect of pore structure on the protective performance of a biogenic carbonate surface treatment. Protective performance was assessed by means of transport and degradation processes, and the penetration depth of the treatment was visualized by microtomography. Pore size governs bacterial adsorption and hence the location and amount of carbonate precipitated. This study indicated that in macroporous stone, biogenic carbonate formation occurred to a larger extent and at greater depths than in microporous stone. As a consequence, the biodeposition treatment exhibited the greatest protective performance on macroporous stone. While precipitation was limited to the outer surface of microporous stone, biogenic carbonate formation occurred at depths of greater than 2 mm for Savonnières and Euville. For Savonnières, the presence of biogenic carbonate resulted in a 20-fold decreased rate of water absorption, which resulted in increased resistance to sodium sulfate attack and to freezing and thawing. While untreated samples were completely degraded after 15 cycles of salt attack, no damage was observed in biodeposition-treated Savonnières. From this study, it is clear that biodeposition is very effective and more feasible for macroporous stones than for microporous stones.

Life Cycle Assessment of Completely Recyclable Concrete

Since the construction sector uses 50% of the Earth’s raw materials and produces 50% of its waste, the development of more durable and sustainable building materials is crucial. Today, Construction and Demolition Waste (CDW) is mainly used in low level applications, namely as unbound material for foundations, e.g., in road construction. Mineral demolition waste can be recycled as crushed aggregates for concrete, but these reduce the compressive strength and affect the workability due to higher values of water absorption. To advance the use of concrete rubble, Completely Recyclable Concrete (CRC) is designed for reincarnation within the cement production, following the Cradle-to-Cradle (C2C) principle. By the design, CRC becomes a resource for cement production because the chemical composition of CRC will be similar to that of cement raw materials. If CRC is used on a regular basis, a closed concrete-cement-concrete material cycle will arise, which is completely different from the current life cycle of traditional concrete. Within the research towards this CRC it is important to quantify the benefit for the environment and Life Cycle Assessment (LCA) needs to be performed, of which the results are presented in a this paper. It was observed that CRC could significantly reduce the global warming potential of concrete.

Application of modified-alginate encapsulated carbonate producing bacteria in concrete: a promising strategy for crack self-healing

Self-healing concrete holds promising benefits to reduce the cost for concrete maintenance and repair as cracks are autonomously repaired without any human intervention. In this study, the application of a carbonate precipitating bacterium Bacillus sphaericus was explored. Regarding the harsh condition in concrete, B. sphaericus spores were first encapsulated into a modified-alginate based hydrogel (AM-H) which was proven to have a good compatibility with the bacteria and concrete regarding the influence on bacterial viability and concrete strength. Experimental results show that the spores were still viable after encapsulation. Encapsulated spores can precipitate a large amount of CaCO3 in/on the hydrogel matrix (around 70% by weight). Encapsulated B. sphaericus spores were added into mortar specimens and bacterial in situ activity was demonstrated by the oxygen consumption on the mimicked crack surface. While specimens with free spores added showed no oxygen consumption. This indicates the efficient protection of the hydrogel for spores in concrete. To conclude, the AM-H encapsulated carbonate precipitating bacteria have great potential to be used for crack self-healing in concrete applications.

Bioreceptivity evaluation of cementitious materials designed to stimulate biological growth

Ordinary Portland cement (OPC), the most used binder in construction, presents some disadvantages in terms of pollution (CO2 emissions) and visual impact. For this reason, green roofs and façades have gain considerable attention in the last decade as a way to integrate nature in cities. These systems, however, suffer from high initial and maintenance costs. An alternative strategy to obtain green facades is the direct natural colonisation of the cementitious construction materials constituting the wall, a phenomenon governed by the bioreceptivity of such material. This work aims at assessing the suitability of magnesium phosphate cement (MPC) materials to allow a rapid natural colonisation taking carbonated OPC samples as a reference material. For that, the aggregate size, the w/c ratio and the amount of cement paste of mortars made of both binders were modified. The assessment of the different bioreceptivities was conducted by means of an accelerated algal fouling test. MPC samples exhibited a faster fouling compared to OPC samples, which could be mainly attributed to the lower pH of the MPC binder. In addition to the binder, the fouling rate was governed by the roughness and the porosity of the material. MPC mortar with moderate porosity and roughness appears to be the most feasible material to be used for the development of green concrete walls.