Nelson Saksono

Degradation of Remazol Red in batik dye waste water by contact glow discharge electrolysis method using NaOH and NaCl electrolytes

Contact Glow Discharge Electrolysis (CGDE) method is one of Plasma Electrolysis technology which has been approved to degrade organic waste water because it is very productive in producing hydroxyl radical. This study aims to degrade Remazol Red by CGDE method and evaluate important parameters that have influent in degradation process of Remazol Red in Batik dye waste water in batch system. The kind of electrolyte (acid and base) and the addition of metal ion such as Fe2+ have affected Remazol Red degradation percentage. Ultraviolet-Visible (UV-Vis) absorption spectra were used to monitor the degradation process. The result of study showed that percentage degradation was 99.97% which obtained by using NaCl 0.02 M with addition Fe2+ 20 ppm, applied voltage 700 volt, anode depth 0.5 cm, initial concentration of Remazol Red 250 ppm and the temperature of solutions was maintained 50-60 ˚C.

Effect of Process Condition in Plasma Electrolysis of Chloralkali Production

Chlor-alkali is one of the most important processes in chemical industry. This process produces chlorine and caustic soda that becomes the main feedstock of daily needs products. In this study, the process condition on chlorine gas production by electrolysis plasma is examined. Plasma electrolysis can increase the chlorine gas production up to 24 times in single compartment reactor and can reach up to 59 times in double compartment reactor compared to electrolysis process. In reactor with single compartment, high voltage results high current then cause high-energy consumption. The highest chlorine gas production is at 0.5 M and 300 V that results 4.63 mmol within 15 minutes. On the other hand, using double compartment reactor, current is lower due to its higher distance between two electrodes that makes the higher resistance. In this case, the highest chlorine gas production is at 0.5 M NaCl and 700 V that results 11.25 mmol within 15 minutes. The use of ion selective membrane can keep the movement of charge from one electrode to other. Ion selective membrane can separate side product of NaOH, but side reaction of chlorine ion still exists. NaCl, will be decomposed in the solvent and form ions in the solution. Positive discharge electrode is called anode and the negative one is cathode. Each electrode bonds ions which have different discharge, so that ions with negative discharge will go to anode and the positive ions will go to cathode. Nevertheless, electrolysis of NaCl solution (brine electrolysis) used in chlor-alkali production has significant weaknesses, those are low conversion resulted by the electrolysis process and the use of high electric current when the electrolysis process occur (4). Hence, it is needed to observe other possible technologies that can be applied in the production of chlor-alkali to reduce the energy consumption. One of the technologies that can reduce the energy consumption is plasma electrolysis. The plasma electrolysis process is similar with electrolysis process, but it is done with high enough voltage until the electric spark is formed producing the plasma on the electrolyte solution. The plasma will produce reactive species such as radicals on large amount which are accelerated by the sharp potential gradient and have enough kinetic energy to induce unique chemical changes in aqueous solutions, so it is able to increase the formation of products in solution several more times than the Faraday electrolysis process (5), (6). Using this technology may reduce the energy consumption several times than conventional electrolysis so the productivity is more effective (6).

Application of contact glow discharge electrolysis method for degradation of batik dye waste Remazol Red by the addition of Fe2+ ion

Contact Glow Discharge Electrolysis (CGDE) has been shown to degrade much weight organic compounds such as dyes because the production of hydroxil radical (•OH) is excess. This research aims to degrade batik dye waste Remazol Red, using CGDE method with the addition of Fe2+ ion. The addition of iron salt compounds has proven to increase process efficiency. Dye degradation is known by measure its absorbances with Spectrophotometer UV-Vis. The result of study showed that percentage degradation was 99.92% in 20 minutes which obtained by using Na2SO4 0.01 M, with addition FeSO4 0,1 gram, applied voltage 860 volt, and 1 wolfram anode 5 mm depth.

Hydroxyl radical production in plasma electrolysis with KOH electrolyte solution

Plasma electrolysis is an effective technology for producing hydroxyl radical (•OH). This method can be used for waste degradation process. This study was conducted to obtain the influence of applied voltage, electrolyte concentration, and anode depth in the plasma electrolysis system for producing hydroxyl radical. The materials of anode and cathode, respectively, were made from tungsten and stainless steel. KOH solution was used as the solution. Determination of hydroxyl radical production was done by measuring H2O2 amount formed in plasma system using an iodometric titration method, while the electrical energy consumed was obtained by measuring the electrical current throughout the process. The highest hydroxyl radical production was 3.51 mmol reached with 237 kJ energy consumption in the power supply voltage 600 V, 0.02 M KOH, and 0.5 cm depth of anode.

Degradation of linear alkylbenzene sulfonate with contact glow discharge electrolysis

Contact Glow Discharge Electrolysis (CGDE) is one of electrolysis plasma technologies. CGDE can produce the hydroxyl radical in a large amount that can be used for wastewater degradation process. This study was conducted to obtain the influence of applied voltage, electrolyte concentration, and anode depth in the LAS degradation using CGDE and review its energy consumption. The greatest LAS degradation is achieved up to 99.14% with low energy consumption of 1149.88 kJ/mmol of the energy consumption that is obtained during 120 minutes by using 600 Volt, 0.02 M of KOH, and 0.5 cm of the anode depth and initial concentration of LAS is 100 ppm.