Nicholas I. Boyd

A global Mars dust composition refined by the Alpha‐Particle X‐ray Spectrometer in Gale Crater

Modern Martian dust is similar in composition to the global soil unit and bulk basaltic Mars crust, but it is enriched in S and Cl. The Alpha Particle X-ray Spectrometer (APXS) on the Mars Science Laboratory Curiosity rover analyzed air fall dust on the science observation tray (o-tray) in Gale Crater to determine dust oxide compositions. The o-tray dust has the highest concentrations of SO3 and Cl measured in Mars dust (SO3 8.3%; Cl 1.1 wt %). The molar S/Cl in the dust (3.35 ± 0.34) is consistent with previous studies of Martian dust and soils (S/Cl = 3.7 ± 0.7). Fe is also elevated ~25% over average Mars soils and the bulk crust. These enrichments link air fall dust with the S-, Cl-, and Fe-rich X-ray amorphous component of Gale Crater soil. Dust and soil have the same S/Cl, constraining the surface concentrations of S and Cl on a global scale.

APXS-derived chemistry of the Bagnold dune sands: Comparisons with Gale crater soils and the global martian average

We present APXS data for the active Bagnold dune field within the Gale impact crater (MSL mission). We derive an APXS-based Average Basaltic Soil (ABS) composition for Mars based on past and recent data from the MSL and MER missions. This represents an update to the Taylor and McLennan (2009) average martian soil, and facilitates comparison across martian datasets. The active Bagnold dune field is compositionally distinct from the ABS, with elevated Mg, Ni and Fe, suggesting mafic mineral enrichment, and uniformly low levels of S, Cl and Zn, indicating only a minimal dust component. A relationship between decreasing grain size and increasing felsic content is revealed. The Bagnold Sands possess the lowest S/Cl of all martian unconsolidated materials.. Gale soils exhibit relatively uniform major element compositions, similar to Meridiani Planum and Gusev Crater basaltic soils (MER missions). However, they show minor enrichments in K, Cr, Mn and Fe, which may signify a local contribution. The lithified eolian Stimson Formation within the Gale impact crater is compositionally similar to the ABS and Bagnold sands, which provide a modern analogue for these ancient eolian deposits. Compilation of APXS-derived soil data reveals a generally homogenous global composition for martian soils, but one that can be locally modified due to past or extant geologic processes that are limited in both space and time.

Potassium‐rich sandstones within the Gale impact crater, Mars: The APXS perspective

The Alpha Particle X-ray spectrometer (APXS) onboard the Curiosity rover at the Kimberley location within Gale crater, Mars, analyzed basaltic sandstones that are characterized by potassium enrichments of two to eight times estimates for average martian crust. They are the most potassic rocks sampled on Mars to date. They exhibit elevated Fe, Mg, Mn and Zn, and depleted Na, Al and Si. These compositional characteristics are common to other potassic sedimentary rocks analyzed by APXS at Gale, but distinct from other landing sites and martian meteorites. CheMin and APXS analysis of a drilled sample indicate mineralogy dominated by sanidine, Ca-rich and Ca-poor clinopyroxene, magnetite, olivine and andesine. The anhydrous mineralogy of the Kimberley sample, and the normative mineralogy derived from APXS of other Bathurst class rocks, together indicate provenance from one or more potassium-rich magmatic or impact-generated source rocks on the rim of Gale crater or beyond. Elevated Zn, Ge and Cu suggest that a localized area of the source region(s) experienced hydrothermal alteration, which was subsequently eroded, dispersed and diluted throughout the unaltered sediment during transport and deposition. The identification of the basaltic, high potassium Bathurst class and other distinct rock compositional classes by the APXS, attests to the diverse chemistry of crustal rocks within and in the vicinity of Gale crater. We conclude that weathering, transport and diagenesis of the sediment did not occur in a warm and wet environment, but instead under relatively cold and wet conditions, perhaps more fitting with processes typical of glacial/periglacial environments.

MSL‐APXS titanium observation tray measurements: Laboratory experiments and results for the Rocknest fines at the Curiosity field site in Gale Crater, Mars

The Mars Science Laboratory (MSL) rover, Curiosity, has a titanium science observation tray (o-tray), upon which portions from drilled and scooped Martian samples can be delivered for analyses by the Alpha-Particle X-ray Spectrometer (APXS). The standard APXS calibration approach to derive elemental concentrations cannot be applied to samples on the o-tray because they (1) have a nonuniform three-dimensional distribution within the APXS field of view and (2) are thin ( 90 µm). To develop techniques for interpreting MSL-APXS o-tray measurements, we conducted laboratory measurements of thin particulate basalt samples on Ti metal with the Flight Equivalent APXS Unit. The experiments demonstrate that, relative to an “infinitely thick” sample, increasing areal coverage of particulates on a Ti metal substrate results in a proportional decrease in the Ti signal and increase in the sample signal. Count rates for heavier elements (Mn and Fe) drop with decreasing sample thickness because the mean thickness is smaller than the APXS information depth. Similar effects were seen in the MSL-APXS o-tray measurement of Rocknest fines on Martian solar day 95, an aliquot of material delivered to Sample Analysis at Mars and Chemistry and Mineralogy. The thin layer effect caused a drop in Mn and Fe signals, which cannot be quantitatively compared to the in situ Rocknest target “Portage” because sample thickness was unknown. Otherwise, Rocknest fines on the o-tray had no significant compositional differences from Portage, except for slight increases in S and Cl.