Nicolas Dauphas

Hf–W–Th evidence for rapid growth of Mars and its status as a planetary embryo

Terrestrial planets are thought to have formed through collisions between large planetary embryos of diameter ∼1,000–5,000 km. For Earth, the last of these collisions involved an impact by a Mars-size embryo that formed the Moon 50–150 million years (Myr) after the birth of the Solar System. Although model simulations of the growth of terrestrial planets can reproduce the mass and dynamical parameters of the Earth and Venus, they fall short of explaining the small size of Mars. One possibility is that Mars was a planetary embryo that escaped collision and merging with other embryos. To assess this idea, it is crucial to know Mars’ accretion timescale, which can be investigated using the 182Hf–182W decay system in shergottite-nakhlite-chassignite meteorites. Nevertheless, this timescale remains poorly constrained owing to a large uncertainty associated with the Hf/W ratio of the Martian mantle and as a result, contradicting timescales have been reported that range between 0 and 15 Myr (refs 6–10). Here we show that Mars accreted very rapidly and reached about half of its present size in only Myr or less, which is consistent with a stranded planetary embryo origin. We have found a well-defined correlation between the Th/Hf and 176Hf/177Hf ratios in chondrites that reflects remobilization of Lu and Th during parent-body processes. Using this relationship, we estimate the Hf/W ratio in Mars’ mantle to be 3.51 ± 0.45. This value is much more precise than previous estimates, which ranged between 2.6 and 5.0 (ref. 6), and lifts the large uncertainty that plagued previous estimates of the age of Mars. Our results also demonstrate that Mars grew before dissipation of the nebular gas when ∼100-km planetesimals, such as the parent bodies of chondrites, were still being formed. Mars’ accretion occurred early enough to allow establishment of a magma ocean powered by decay of 26Al.

Iron Isotope Fractionation During Magmatic Differentiation in Kilauea Iki Lava Lake

Magmatic differentiation helps produce the chemical and petrographic diversity of terrestrial rocks. The extent to which magmatic differentiation fractionates nonradiogenic isotopes is uncertain for some elements. We report analyses of iron isotopes in basalts from Kilauea Iki lava lake, Hawaii. The iron isotopic compositions (56Fe/54Fe) of late-stagemeltveins are 0.2 permil (‰) greater than values for olivine cumulates. Olivine phenocrysts are up to 1.2‰ lighter than those of whole rocks. These results demonstrate that iron isotopes fractionate during magmatic differentiation at both whole-rock and crystal scales. This characteristic of iron relative to the characteristics of magnesium and lithium, for which no fractionation has been found, may be related to its complex redox chemistry in magmatic systems and makes iron a potential tool for studying planetary differentiation.

The nitrogen record of crust^mantle interaction and mantle convection from Archean to Present

Mantle fluids sampled by mid-ocean ridge basalts and by diamonds are depleted in the heavy isotope of nitrogen, 15 N, by about 3^5 parts per mil relative to atmosphere, suggesting a common nitrogen end-member since at least the Archean. In contrast, deep mantle material sampled by mantle plumes (Kola Devonian magmatic province, Iceland, Loihi Seamount, Hawaii, Society Islands) is enriched in 15 N by up to 8 parts per mil, as are post-Archean sediments. Several independent lines of evidence strongly suggest that mantle nitrogen is mostly recycled. Notably, the ratio between nitrogen and an incompatible lithophile element like potassium is nearly constant between the surface of the Earth and the different mantle reservoirs, whereas the ratio between nitrogen and a noble gas like 36 Ar varies over two orders of magnitude between these reservoirs. We propose that the large-scale N isotope heterogeneity of the mantle results from secular variation of the nitrogen isotope composition of recycled sediments, which is governed by specific metabolic paths having changed with the advent of oxygenated ocean. If this is the case, the contrast between mantle reservoirs reflects a profound change in the mantle convection regime through time. In the Archean, recycled material was stored in a mantle domain sampled by diamonds and by mid-ocean ridges. Starting from the Proterozoic, slabs reached deep, volatile-rich regions of the mantle which are now sampled by mantle plumes. 9 2002 Elsevier Science B.V. All rights reserved.

The dual origin of the terrestrial atmosphere

The origin of the terrestrial atmosphere is one of the most puzzling enigmas in the planetary sciences. It is suggested here that two sources contributed to its formation, fractionated nebular gases and accreted cometary volatiles. During terrestrial growth, a transient gas envelope was fractionated from nebular composition. This transient atmosphere was mixed with cometary material. The fractionation stage resulted in a high Xe/Kr ratio, with xenon being more isotopically fractionated than krypton. Comets delivered volatiles having low Xe/Kr ratios and solar isotopic compositions. The resulting atmosphere had a near-solar Xe/Kr ratio, almost unfractionated krypton delivered by comets, and fractionated xenon inherited from the fractionation episode. The dual origin therefore provides an elegant solution to the long-standing “missing xenon” paradox. It is demonstrated that such a model could explain the isotopic and elemental abundances of Ne, Ar, Kr, and Xe in the terrestrial atmosphere.

A Perspective from Extinct Radionuclides on a Young Stellar Object: The Sun and Its Accretion Disk

Meteorites, which are remnants of solar system formation, provide a direct glimpse into the dynamics and evolution of a young stellar object (YSO), namely our Sun. Much of our knowledge about the astrophysical context of the birth of the Sun, the chronology of planetary growth from micrometer- sized dust to terrestrial planets, and the activity of the young Sun comes from the study of extinct radionuclides such as 26 Al (t1/2 = 0.717 Myr). Here we review how the signatures of extinct radionuclides (short-lived isotopes that were present when the solar system formed and that have now decayed below detection level) in planetary materials influence the current paradigm of solar system formation. Particular attention is given to tying meteorite measurements to remote astronomical observations of YSOs and modeling efforts. Some extinct radionuclides were inherited from the long-term chem- ical evolution of the Galaxy, others were injected into the solar system by a nearby supernova, and some were produced by particle irradiation from the T-Tauri Sun. The chronology inferred from extinct radionuclides reveals that dust agglomeration to form centimeter-sized particles in the inner part of the disk was very rapid (<50 kyr), planetesimal formation started early and spanned several million years, planetary embryos (possibly like Mars) were formed in a few million years, and terrestrial planets (like Earth) completed their growths several tens of million years after the birth of the Sun.

NEUTRON-RICH CHROMIUM ISOTOPE ANOMALIES IN SUPERNOVA NANOPARTICLES

Neutron-rich isotopes with masses near that of iron are produced in Type Ia and II supernovae (SNeIa and SNeII). Traces of such nucleosynthesis are found in primitive meteorites in the form of variations in the isotopic abundance of ^(54)Cr, the most neutron-rich stable isotope of chromium. The hosts of these isotopic anomalies must be presolar grains that condensed in the outflows of SNe, offering the opportunity to study the nucleosynthesis of iron-peak nuclei in ways that complement spectroscopic observations and can inform models of stellar evolution. However, despite almost two decades of extensive search, the carrier of ^(54)Cr anomalies is still unknown, presumably because it is fine grained and is chemically labile. Here, we identify in the primitive meteorite Orgueil the carrier of ^(54)Cr anomalies as nanoparticles ( 3.6 × solar). Such large enrichments in ^(54)Cr can only be produced in SNe. The mineralogy of the grains supports condensation in the O/Ne-O/C zones of an SNII, although a Type Ia origin cannot be excluded. We suggest that planetary materials incorporated different amounts of these nanoparticles, possibly due to late injection by a nearby SN that also delivered ^(26)Al and ^(60)Fe to the solar system. This idea explains why the relative abundance of ^(54)Cr and other neutron-rich isotopes vary between planets and meteorites. We anticipate that future isotopic studies of the grains identified here will shed new light on the birth of the solar system and the conditions in SNe.

Constraining the astrophysical origin of the p-nuclei through nuclear physics and meteoritic data

A small number of naturally occurring, proton-rich nuclides (the p-nuclei) cannot be made in the s- and r-processes. Their origin is not well understood. Massive stars can produce p-nuclei through photodisintegration of pre-existing intermediate and heavy nuclei. This so-called γ-process requires high stellar plasma temperatures and occurs mainly in explosive O/Ne burning during a core-collapse supernova. Although the γ-process in massive stars has been successful in producing a large range of p-nuclei, significant deficiencies remain. An increasing number of processes and sites has been studied in recent years in search of viable alternatives replacing or supplementing the massive star models. A large number of unstable nuclei, however, with only theoretically predicted reaction rates are included in the reaction network and thus the nuclear input may also bear considerable uncertainties. The current status of astrophysical models, nuclear input and observational constraints is reviewed. After an overview of currently discussed models, the focus is on the possibility to better constrain those models through different means. Meteoritic data not only provide the actual isotopic abundances of the p-nuclei but can also put constraints on the possible contribution of proton-rich nucleosynthesis. The main part of the review focuses on the nuclear uncertainties involved in the determination of the astrophysical reaction rates required for the extended reaction networks used in nucleosynthesis studies. Experimental approaches are discussed together with their necessary connection to theory, which is especially pronounced for reactions with intermediate and heavy nuclei in explosive nuclear burning, even close to stability.

IRON 60 EVIDENCE FOR EARLY INJECTION AND EFFICIENT MIXING OF STELLAR DEBRIS IN THE PROTOSOLAR NEBULA

Among extinct radioactivities present in meteorites, 60 Fe (t1/2 = 1.49 Myr) plays a key role as a high-resolution chronometer, a heat source in planetesimals, and a fingerprint of the astrophysical setting of solar system formation. A critical issue with 60 Fe is that it could have been heterogeneously distributed in the protoplanetary disk, calling into question the efficiency of mixing in the solar nebula or the timing of 60 Fe injection relative to planetesimal formation. If this were the case, one would expect meteorites that did not incorporate 60 Fe (either because of late injection or incomplete mixing) to show 60 Ni deficits (from lack of 60 Fe decay) and collateral effects on other neutron-rich isotopes of Fe and Ni (coproduced with 60 Fe in core-collapse supernovae and AGB-stars). Here, we show that measured iron meteorites and chondrites have Fe and Ni isotopic compositions identical to Earth. This demonstrates that 60 Fe must have been injected into the protosolar nebula and mixed to less than 10 % heterogeneity before formation of planetary bodies. Subject headings: solar system: formation — nuclear reactions, nucleosynthesis, abundances — methods: analytical — supernovae: general

Molybdenum Nucleosynthetic Dichotomy Revealed in Primitive Meteorites

The collapse of the presolar cloud gave rise to a global homogenization of material available to form the Sun and planets. In the resulting, presumably homogeneous solar system, the nuclides are present in proportions referred to as their cosmic abundances. Here we report molybdenum isotopic compositions of bulk samples and leachate fractions of the primitive meteorites Orgueil and Allende. Two complementary nucleosynthetic components are revealed in Orgueil. One (Mo-m) is enriched in s-process nuclides and may be hosted in presolar grains while the other (Mo-w) is probably distributed in various phases and is depleted in s-process nuclides. The most likely carrier of Mo-m is silicon carbide, although we cannot exclude graphite or an unidentified presolar phase. Excesses in Mo-w are also detected in the bulk sample and all leachate fractions of Allende. These results illustrate that the apparent cosmic abundance pattern of the nuclides, in fact, reflects a mixture of various nucleosynthetic components that survived planetary-scale homogenization in the protosolar nebula.

Distribution coefficients of 60 elements on TODGA resin: application to Ca, Lu, Hf, U and Th isotope geochemistry.

Batch equilibration experiments are conducted to measure the distribution coefficients (K(d)) of a large number of elements in nitric, nitric plus hydrofluoric, and hydrochloric acids on Eichrom TODGA extraction chromatography resin. The K(d)s are used to devise a multi-element extraction scheme for high-precision elemental and isotopic analyses of Ca, Hf, Lu, Th and U in geological materials, using high-purity lithium metaborate (LiBO(2)) flux fusion that allows rapid digestion of even the most refractory materials. The fusion melt, dissolved in nitric acid, is directly loaded to a TODGA cartridge on a vacuum chamber for elemental separation. An Ln-Spec cartridge is used in tandem with TODGA for Lu purification. The entire procedure, from flux digestion to preparation for isotopic analysis, can be completed in a day. The accuracy of the proposed technique is tested by measuring the concentrations of Ca (standard bracketing), Hf, Lu, Th and U (isotope dilution), and the isotopic composition of Hf in geostandards (USNM3529, BCR-2, BHVO-1, AGV-1 and AGV-2). All measurements are in excellent agreement with recommended literature values, demonstrating the effectiveness of the proposed analytical procedure and the versatility of TODGA resin.