Nicolas Tribovillard

Carbonate Grain-Size Distribution in Hemipelagic Sediments from a Laser Particle Sizer

Laser grain-sizer instruments provide the opportunity to study the grain size distribution of sediments across a wide size range in a short time. Automatic measurements can therefore be made, on a routine basis, for a great number of samples. Oceanic studies have proved the utility of these methods in characterizing both climatic changes and changes in sediment provenances. In addition, carbonate content is estimated either directly by CaCO 3 measurement, by visual observations, or by proxies such as sediment color reflectance. Nevertheless, the grain size distribution of the carbonate fraction is still a matter of speculation, and only optical observations can distinguish the nature of each carbonate fraction. Here we present the improvements on a method to study rapidly, with a high resolution, the grain size distribution of the carbonate fraction by use of a laser grain-sizer. We describe the basic methodology and apply it to an example from the Pleistocene of the Northern Atlantic Ocean.

Chapter 8Productivity and bottom water redox conditions at the Frasnian-Famennian boundary on both sides of the Eovariscan Belt: constraints from trace-element geochemistry

Abtract The Late Devonian Frasnian-Famennian (F-F) mass extinction event coincides in many places with the depositionof C org -rich “Kellwasser” facies. Four F-F boundary sections representative of platform and basin environments from widely separated locations (Morocco, Germany, and France) were analysed for inorganic geochemistry, especially trace elements (redox and productivity proxies), in order to describe paleodepositional environments for the Kellwasser horizons. Ni/Co, V/Cr, U/Th, and V/(V+Ni) ratios, as well as redox trace metal concentrations indicate that oxygen-depleted conditions existed during the times of Kellwasser facies deposition. In platform settings, dysoxic conditions seem to be limited to the Late Frasnian. In basinal settings, oxygen depletion was stronger and persisted into the Early Famennian. Enrichments of Ba, Cu, Ni, that are limited to the Late Frasnian, show that surface productivity was relatively high and organic matter could accumulate, especially in the deeper environments. The stratigraphical distribution of several geochemical markers are linked with two positive excursions of the δ 13 C carb signal that result from enhanced organic matter burial. Reducing conditions likely resulted from high productivity of Late Devonian marine ecosystems. Intense nutrient supply resulted probably from the biogeochemical recycling of nutrients, and/or runoff from emerged lands. Coupled with other factors, such as rapid sea-level fluctuations and climatic changes, oxygen-depleted conditions and eutrophication would have modified Late Devonian environments and could be possible factors in the F-F mass mortality.

Formation pathways of proto-kerogens in Holocene sediments of the upwelling influenced Cariaco Trench, Venezuela

Abstract Proto-kerogens were isolated, by extraction and HF/HC1 treatment, from core samples of Holocene sediments of the Cariaco Trench, with interpolated ages of 900, 2850 and 6000 years, and examined via a combination of microscopic, spectroscopic and pyrolytic methods. It appears that these proto-kerogens were chiefly formed from phytoplanktonic components via the degradation–recondensation pathway. The natural sulfurisation pathway only afforded a minor contribution, in spite of the conditions prevailing in the water column and sediments that correspond to those generally considered as especially favourable for the formation of sulfurised organic matter. Proto-kerogen formation via sulfurisation, i.e. the endpoint of the continuum leading to insoluble high molecular weight structures cross-linked by sulfur and resistant to acid hydrolysis, is therefore a rather slow process under these conditions. However, the contribution of sulfurised moieties to the total proto-kerogen substantially increased with depth due to continuous sulfurisation in the time/depth interval, whereas formation through degradation–recondensation is almost complete for the 900 years old sample onwards. Proto-kerogen formation via carbohydrate sulfurisation is faster than lipid sulfurisation and only sulfurised carbohydrates were detected in the shallowest sample. In contrast, sulfurised lipids occur in the other two proto-kerogens. Moreover, their contribution relative to sulfurised carbohydrates increases with depth, probably due to the higher resistance of lipids to mineralisation compared to carbohydrates.