Ning Xu

Mushrooms as Efficient Solar Steam-Generation Devices

Solar steam generation is emerging as a promising technology, for its potential in harvesting solar energy for various applications such as desalination and sterilization. Recent studies have reported a variety of artificial structures that are designed and fabricated to improve energy conversion efficiencies by enhancing solar absorption, heat localization, water supply, and vapor transportation. Mushrooms, as a kind of living organism, are surprisingly found to be efficient solar steam-generation devices for the first time. Natural and carbonized mushrooms can achieve ≈62% and ≈78% conversion efficiencies under 1 sun illumination, respectively. It is found that this capability of high solar steam generation is attributed to the unique natural structure of mushroom, umbrella-shaped black pileus, porous context, and fibrous stipe with a small cross section. These features not only provide efficient light absorption, water supply, and vapor escape, but also suppress three components of heat losses at the same time. These findings not only reveal the hidden talent of mushrooms as low-cost materials for solar steam generation, but also provide inspiration for the future development of high-performance solar thermal conversion devices.

Direct Conversion of Perovskite Thin Films into Nanowires with Kinetic Control for Flexible Optoelectronic Devices

With significant progress in the past decade, semiconductor nanowires have demonstrated unique features compared to their thin film counterparts, such as enhanced light absorption, mechanical integrity and reduced therma conductivity, etc. However, technologies of semiconductor thin film still serve as foundations of several major industries, such as electronics, displays, energy, etc. A direct path to convert thin film to nanowires can build a bridge between these two and therefore facilitate the large-scale applications of nanowires. Here, we demonstrate that methylammonium lead iodide (CH3NH3PbI3) nanowires can be synthesized directly from perovskite film by a scalable conversion process. In addition, with fine kinetic control, morphologies, and diameters of these nanowires can be well-controlled. Based on these perovskite nanowires with excellent optical trapping and mechanical properties, flexible photodetectors with good sensitivity are demonstrated.

Tuning Transpiration by Interfacial Solar Absorber-Leaf Engineering

Abstract Plant transpiration, a process of water movement through a plant and its evaporation from aerial parts especially leaves, consumes a large component of the total continental precipitation (≈48%) and significantly influences global water distribution and climate. To date, various chemical and/or biological explorations have been made to tune the transpiration but with uncertain environmental risks. In recent years, interfacial solar steam/vapor generation is attracting a lot of attention for achieving high energy transfer efficiency. Various optical and thermal designs at the solar absorber–water interface for potential applications in water purification, seawater desalination, and power generation appear. In this work, the concept of interfacial solar vapor generation is extended to tunable plant transpiration by showing for the first time that the transpiration efficiency can also be enhanced or suppressed through engineering the solar absorber–leaf interface. By tuning the solar absorption of membrane in direct touch with green leaf, surface temperature of green leaf will change accordingly because of photothermal effect, thus the transpiration efficiency as well as temperature and relative humidity in the surrounding environment will be tuned. This tunable transpiration by interfacial absorber‐leaf engineering can open an alternative avenue to regulate local atmospheric temperature, humidity, and eventually hydrologic cycle.

Anomalous thermal anisotropy of two-dimensional nanoplates of vertically grown MoS2

Heat flow control plays a significant role in thermal management and energy conversion processes. Recently, two dimensional (2D) materials with unique anisotropic thermal properties are attracting a lot of attention, as promising building blocks for molding the heat flow. Originated from its crystal structure, in most if not all the 2D materials, the thermal conductivity along the Z direction (kz) is much lower than x-y plane thermal conductivity (kxy). In this work, we demonstrate that 2D nanoplates of vertically grown molybdenum disulfide (VG MoS2) can have anomalous thermal anisotropy, in which kxy (about 0.83u2009W/mu2009K at 300u2009K) is ∼1 order of magnitude lower than kz (about 9.2u2009W/mu2009K at 300u2009K). Lattice dynamics analysis reveals that this anomalous thermal anisotropy can be attributed to the anisotropic phonon dispersion relations and the anisotropic phonon group velocities along different directions. The low kxy can be attributed to the weak phonon coupling near the x-y plane interfaces. It is expected th...