Nirupama Singh

PHOTOELECTROCHEMICAL WATER SPLITTING USING BILAYERED ZnO/SrTiO3 PHOTOELECTRODES

Nanostructured zinc oxide overlayered by nanoporous strontium titanate was synthesized using sol-gel method and tested in a photoelectrochemical (PEC) cell for splitting of water. It was found that compared to the pristine ZnO and SrTiO3, the resistivity of bilayered thin film was reduced and a negative shift in open circuit potential and flatband potential of bilayered ZnO/SrTiO3 was observed, thus improving the photocurrent density and photoconversion efficiency. Significantly, bilayered ZnO/SrTiO3 thin film offered the best photocurrent density i.e. 0.46 mA/cm2 at 0 V/SCE. XRD, SEM and UV-Vis spectroscopic studies were carried out to explore the structural, surface morphological and optical properties of various thin films.

Synthesis and Characterization of CuO-TiO2 Core Shell Nanocomposites for Hydrogen Generation Via Photoelectrochemical Splitting of Water

Sol–gel derived CuO–TiO2 core shell nanocomposites were synthesized by modified Stober method [1] and characterized. XRD analysis revealed dominant evolution of CuO (tenorite phase) at the core on to which TiO2 (anatase) was coated. The average crystallite size, estimated from Scherrer’s computations was 30–33 nm. PEC studies indicated that core shell composites offer significant photocurrent. The effect of variation in concentration of titanium (IV) butoxide (precursor used for generating TiO2 coat over CuO) was also investigated. The increase in concentration of TBOT led to increase in photocurrent.

Caking and characterizing graphene oxide thin films via electrodeposition technique for possible application in photoelectrochemical spliting of water

In the present study Readymade Graphene oxide (GO) has been coated using electrochemical deposition technique [1] on to the conducting glass (ITO) substrate. Raman spectra generated D and G Peaks obtained at 1346 and 1575 cm−1 confirmed the presence of GO [2]. The UV-Visible absorption measurements provided absorption peak at 262 nm and the Tauc plots yielded band-gap energy of sample around 3.9 eV. The PEC measurements involved determination of current-voltage (I-V) characteristics, both under darkness as well as under illumination. The photocurrent of 1.21 mA/cm−2 at 0.5 V applied voltage (vs. saturated calomel electrode), was recorded under the illumination of 150 Wcm−2 (Xenon arc lamp; Oriel, USA). The photocurrent values were utilized further to calculate applied bias photon-to-current efficiency (% ABPE), which was estimated to 0.98 % at 0.5 V bias.

A Clean and Green Hydrogen Energy Production Using Nanostructured ZnO and Fe-ZnO via Photoelectrochemical Splitting of Water

To meet tomorrow’s demand of cheap, environment friendly and renewable hydrogen, the industries must find new ways of producing it. One solution, with a high potential, is extracting hydrogen by direct splitting of water using solar energy. This study deals with photoelectrochemical splitting of water by using nanostructured ZnO and Fe-ZnO thin films as a working photoelectrode. ZnO and Fe-ZnO films were synthesized by sol-gel spin coating method and were characterized for formed crystalline phase by XRD analysis, band gap energy by spectrometric measurement and surface topography by AFM analysis. Subsequently, these were used as working electrode in PEC cell in conjunction with a platinum counter electrode, saturated calomel reference electrode and 150 W Xenon Arc Light Source for illumination, and PEC current densities were recorded, using aqueous solution of NaOH and KOH.

Synthesis and Characterization of Fe2O3-ZnO Nanocomposites for Efficient Photoelectrochemical Splitting of Water

It is indispensable to construct clean energy systems in order to solve the current energy crisis issues. In the present work nanocomposite Fe2O3-ZnO powders have been prepared. XRD analysis revealed dominant evolution of wurtzite ZnO and α-Fe2O3 at Zn/Fe molar ratios being, respectively, ≥ 19.0 and ≤ 0.05. However, at intermediate concentrations, simultaneous growth of two oxides along with cubic ZnFe2O4 has been observed. Optical characterization led to prominent absorption threshold, which is shifted towards higher wavelength with increasing Fe amount. Results indicate that Fe2O3-ZnO nanocomposite at optimized Zn/Fe molar ratio yields significantly increased photoresponse compared to pure ZnO or Fe2O3.