Noye M. Johnson

Effects of Forest Cutting and Herbicide Treatment on Nutrient Budgets in the Hubbard Brook Watershed‐Ecosystem

All vegetation on Watershed 2 of the Hubbard Brook Experimental Forest was cut during November and December of 1965, and vegetation regrowth was inhibited for two years by periodic application of herbicides. Annual stream—flow was increased 33 cm or 39% the first year and 27 cm or 28% the second year above the values expected if the watershed were not deforested. Large increases in streamwater concentration were observed for all major ions, except NH4+, SO4 = and HCO3—, approximately five months after the deforestation. Nitrate concentrations were 41—fold higher than the undisturbed condition the first year and 56—fold higher the second. The nitrate concentration in stream water has exceeded, almost continuously, the health levels recommended for drinking water. Sulfate was the only major ion in stream water that decreased in concentration after deforestation. An inverse relationship between sulfate and nitrate concentrations in stream water was observed in both undisturbed and deforested situations. Average streamwater concentrations increased by 417% for Ca++, 408% for Mg++, 1558% for K+ and 177% for Na+ during the two years subsequent to deforestation. Budgetary net losses from Watershed 2 in kg/ha—yr were about 142 for NO3—N, 90 for Ca++, 36 for K+, 32 for SiO2—Si, 24 for Al+++, 18 for Mg++, 17 for Na+, 4 for Cl—, and 0 for SO4—S during 1967—68; whereas for an adjacent, undisturbed watershed (W6) net losses were 9.2 for Ca++, 1.6 for K+, 17 for SiO2—Si, 3.1 for A1+++, 2.6 for Mg++, 7.0 for Na+, 0.1 for C1—, and 3.3 for SO4—S. Input of nitrate—nitrogen in precipitation normally exceeds the output in drainage water in the undisturbed ecosystems, and ammonium—nitrogen likewise accumulates in both the undisturbed and deforested ecosystems. Total gross export of dissolved solids, exclusive of organic matter, was about 75 metric tons/km2 in 1966—67, and 97 metric tons/km2 in 1967—68, or about 6 to 8 times greater than would be expected for an undisturbed watershed. The greatly increased export of dissolved nutrients from the deforested ecosystem was due to an alteration of the nitrogen cycle within the ecosystem. The drainage streams tributary to Hubbard Brook are normally acid, and as a result of deforestation the hydrogen ion content increased by 5—fold (from pH 5.1 to 4.3). Streamwater temperatures after deforestation were higher than the undisturbed condition during both summer and winter. Also in contrast to the relatively constant temperature in the undisturbed streams, streamwater temperature after deforestation fluctuated 3—4°C during the day in summer. Electrical conductivity increased about 6—fold in the stream water after deforestation and was much more variable. Increased streamwater turbidity as a result of the deforestation was negligible, however the particulate matter output was increased about 4—fold. Whereas the particulate matter is normally 50% inorganic materials, after deforestation preliminary estimates indicate that the proportion of inorganic materials increased to 76% of the total particulates. Supersaturation of dissolved oxygen in stream water from the experimental watersheds is common in all seasons except summer when stream discharge is low. The percent saturation is dependent upon flow rate in the streams. Sulfate, hydrogen ion and nitrate are major constituents in the precipitation. It is suggested that the increase in average nitrate concentration in precipitation compared to data from 1955—56,as well as the consistent annual increase observed from 1964 to 1968, may be some measure of a general increase in air pollution.

‘Acid rain’, dissolved aluminum and chemical weathering at the Hubbard Brook Experimental Forest, New Hampshire

Abstract Contemporary ‘acid rain’ in the Hubbard Brook ecosystem has induced a series of geochemical responses. Neutralization is accomplished in essentially a 2-step process. Initially, hydrogen ion acidity is neutralized by the dissolution of reactive alumina primarilly found in the soil zone. In the Hubbard Brook area this reactive alumina has solution properties much like natural gibbsite. Aluminum-rich surface waters with a pH of 4.7 5.2 are typical of this neutralization stage. In a second step, both hydrogen ion acidity and aluminum acidity are neutralized by the chemical weathering of primary silicate minerals, i.e. by the alkali and alkaline earths contained in the bedrock and glacial till of the watershed. The chemical weathering reaction is much slower than the alumina dissolution reaction, so that the aluminum acidity stage (pH 4.7 5.2) may persist for substantial periods. Typically, however, in the Hubbard Brook area the aluminum acidity has been neutralized and a pH > 5.2 is obtained before surface waters reach a third-over stream channel. Because of the relatively low pHs throughout the soil zone and in the streamwater, carbonic acid reactions are essentially absent at the present time in the Hubbard Brook system. Water pathlength (or residence time) in the soil zone is the crucial factor in the state of acid rain neutralization, aluminum chemistry and chemical weathering. As measured by the losses of alkali and alkaline earths from the ecosystem, chemical weathering rate in the Hubhard Brook area at the present time is not especially high relative to other areas.

Paleomagnetic chronology, fluvial processes and tectonic implications of the Siwalik deposits near Chinji village, Pakistan.

A 2800-m section of Siwalik strata containing the stratotypes for both the Chinji and Nagri formations has been dated by magnetic polarity stratigraphy, and the observed polarity zonation has securely been correlated with the Chron 17-7 segment of the time scale. The base of the section is the base of the Kamlial formation, which occurs near the top of Chron 17 (18.3 m.y.). The Kamlial-Chinji formation boundary occurs in the middle of Chron 15 (14.3 m.y.), the Chinji-Nagri boundary near the bottom of Chron 10 (10.8 m.y.), and the Nagri-Dhok Pathan boundary at the Chron 8-9 boundary (8.5 m.y.). The Siwalik deposits near Chinji Village consist of four distinct classes of fluvial cycles, each with a characteristic periodicity: a first order of

Magnetic polarity stratigraphy and ages of Siwalik group rocks of the potwar plateau, Pakistan

10^{7} years, a second order of 10^{6} years, a third order of 10^{4}-10^{5} years

Magnetic polarity stratigraphy and vertebrate paleontology of the upper siwalik subgroup of northern Pakistan

, and a fourth order of

Neogene mammalian faunal change in southern Asia: Correlations with climatic, tectonic, and eustatic events

10^{0}-10^{4} years