Nur Shaylinda Mohd Zin

Application of a pre-hydrolyzed iron coagulant on partially stabilized leachate

AbstractLeachate is a liquid produced from the biodegradation of solid waste in landfill and is normally referred as highly polluted wastewater. Various treatment methods are available and it is highly depended on the characteristics of the leachate. One of the common and simplest methods is using coagulation process. The application of pre-hydrolyzed coagulants in coagulation process is well known for water and wastewater treatment. However, information on the application of pre-hydrolyzed coagulants, especially pre-hydrolyzed iron (PHI), in partially stabilized leachate treatments is not well documented. This study examined the application of PHI on the partially stabilized leachate by determining the optimum basicity ratio, pH, and dose through the removals percentage of suspended solid (SS), color, and chemical oxygen demand (COD). Laboratory jar tests revealed that the optimum PHI basicity ratio, pH, and dosage were 0.1, 5, and 0.2 g/L Fe, respectively. The optimum removals of SS, color, and COD were...

A Comparative Study of Matang and Kuala Sembeling Landfills Leachate Characteristics

Understanding the characteristic of leachate is important since it has complexity properties because of the variation in its composition. This study, analyzed and compared two leachate from two landfill sites, namely, Matang and Kuala Sembeling landfill. Leachate raw samples were collected by grab sampling and were analyzed for 11 parameters. The average concentrations of MLS and KSLS leachate such as BOD5 (146 and 61 mg/L), COD (828 and 363 mg/L), pH (7.6 and 8), SS (407 and 220 mg/L), ammonia (868 and 367 mg/L) , BOD/COD (0.18 and 0.14), cadmium (0.19 and 0.1 mg/L), cuprum (0.09 and 0.1 mg/L), nickel (0.17 and 0.1 mg/L), manganese (0.09 and 0.22 mg/L), and ferum (2.3 and 8.3 mg/L) were recorded, respectively. The results revealed that the both landfills are categorized as partially stabilized leachate. The strength of leachate pollutants from MLS are higher than KSLS because of the higher fraction of organics concentration. There are 5 parameters (BOD5, COD, ammonia, SS and cadmium) in MLS and 7 parameters (BOD5, COD, ammonia, SS, cadmium, manganese and ferum) in KSLS exceeded the permissible limit stated by MEQA (1974), and so leachates from both landfill sites need a suitable treatment to reduce the concentration of the leachate pollutants before discharge into environment.

Removal Efficiency of Electrocoagulation Treatment Using Aluminium Electrode for Stabilized Leachate

This research was conducted to investigate the performance of aluminium electrode in electrocoagulation process removing chemical oxygen demand (COD), ammonia, turbidity, colour and suspended solid (SS) from Simpang Renggam landfill leachate. Effects of current density, electrolysis duration and pH were observed in this study. From the data obtained, optimum condition at current density was recorded at 200 A/m2with the electrolysis duration of 20-minutes and optimum pH value at 4. The removal recorded at this condition for COD, ammonia, colour, turbidity and suspended solid were 60%, 37%, 94%, 88% and 89% respectively. Electrocoagulation treatment give a better result and can be applied for leachate treatment in future. Thus, electrocoagulation treatment has the potential to be used in treatment of leachate.

Optimisation of coagulation (poly iron chloride) process for partially stabilised leachate using response surface methodology

A coagulation and flocculation treatment method was applied on partially stabilised leachate of Matang landfill. The interactions and effects of dose and pH on the removal of suspended solid (SS), colour and chemical oxygen demand (COD) were investigated, analysed and optimised through RSM. The optimal condition obtained from the satisfactory mathematical model was 0.24 g/L Fe and 4.94 of poly iron chloride (PHI) dose and pH, respectively. Confirmatory experiment indicates good agreement between model prediction and experimental value. Therefore, RSM is an appropriate statistical tool in the optimisation of PHI coagulation and flocculation process.

A comparative study of floc and sludge of leachate under different types of coagulants

This study compared the floc and sludge formed during the coagulation of leachate by different types of coagulants. The coagulants tested in this study were Ferric chloride (FC), pre-hydrolyzed iron (PHI), dual coagulant (PHI+TF(tapioca flour)), and composite coagulant (pre mix of PHI and TF (PHITF)). The floc and sludge were characterized by measuring the sludge volume index (SVI), sludge velocity (SV), and floc size. Results showed that the hierarchy for SVI, SV, and floc size were FC>PHI>PHI+TF>PHITF, PHITF>PHI+TF>PHI>FC, and PHI+TF>PHITF>PHI>FC, respectively. PHITF demonstrated the lowest SVI and the shortest sludge settling time among the tested coagulants. PHI+TF produced the largest floc size. The addition of TF in PHI as a composite and dual coagulant significantly improved the floc and sludge characteristics. PHITF improved the floc and sludge formation of partially stabilized leachate.This study compared the floc and sludge formed during the coagulation of leachate by different types of coagulants. The coagulants tested in this study were Ferric chloride (FC), pre-hydrolyzed iron (PHI), dual coagulant (PHI+TF(tapioca flour)), and composite coagulant (pre mix of PHI and TF (PHITF)). The floc and sludge were characterized by measuring the sludge volume index (SVI), sludge velocity (SV), and floc size. Results showed that the hierarchy for SVI, SV, and floc size were FC>PHI>PHI+TF>PHITF, PHITF>PHI+TF>PHI>FC, and PHI+TF>PHITF>PHI>FC, respectively. PHITF demonstrated the lowest SVI and the shortest sludge settling time among the tested coagulants. PHI+TF produced the largest floc size. The addition of TF in PHI as a composite and dual coagulant significantly improved the floc and sludge characteristics. PHITF improved the floc and sludge formation of partially stabilized leachate.