O. Galao

Multifunctional Cement Composites Strain and Damage Sensors Applied on Reinforced Concrete (RC) Structural Elements

In this research, strain-sensing and damage-sensing functional properties of cement composites have been studied on a conventional reinforced concrete (RC) beam. Carbon nanofiber (CNFCC) and fiber (CFCC) cement composites were used as sensors on a 4 m long RC beam. Different casting conditions (in situ or attached), service location (under tension or compression) and electrical contacts (embedded or superficial) were compared. Both CNFCC and CFCC were suitable as strain sensors in reversible (elastic) sensing condition testing. CNFCC showed higher sensitivities (gage factor up to 191.8), while CFCC only reached gage factors values of 178.9 (tension) or 49.5 (compression). Furthermore, damage-sensing tests were run, increasing the applied load progressively up to the RC beam failure. In these conditions, CNFCC sensors were also strain sensitive, but no damage sensing mechanism was detected for the strain levels achieved during the tests. Hence, these cement composites could act as strain sensors, even for severe damaged structures near to their collapse.

Mechanical Properties and Durability of CNT Cement Composites

In the present paper, changes in mechanical properties of Portland cement-based mortars due to the addition of carbon nanotubes (CNT) and corrosion of embedded steel rebars in CNT cement pastes are reported. Bending strength, compression strength, porosity and density of mortars were determined and related to the CNT dosages. CNT cement paste specimens were exposed to carbonation and chloride attacks, and results on steel corrosion rate tests were related to CNT dosages. The increase in CNT content implies no significant variations of mechanical properties but higher steel corrosion intensities were observed.

Highly Conductive Carbon Fiber Reinforced Concrete for Icing Prevention and Curing

This paper aims to study the feasibility of highly conductive carbon fiber reinforced concrete (CFRC) as a self-heating material for ice formation prevention and curing in pavements. Tests were carried out in lab ambient conditions at different fixed voltages and then introduced in a freezer at −15 °C. The specimens inside the freezer were exposed to different fixed voltages when reaching +5 °C for prevention of icing and when reaching the temperature inside the freezer, i.e., −15 °C, for curing of icing. Results show that this concrete could act as a heating element in pavements with risk of ice formation, consuming a reasonable amount of energy for both anti-icing (prevention) and deicing (curing), which could turn into an environmentally friendly and cost-effective deicing method.

Self-Sensing Properties of Alkali Activated Blast Furnace Slag (BFS) Composites Reinforced with Carbon Fibers

In recent years, several researchers have shown the good performance of alkali activated slag cement and concretes. Besides their good mechanical properties and durability, this type of cement is a good alternative to Portland cements if sustainability is considered. Moreover, multifunctional cement composites have been developed in the last decades for their functional applications (self-sensing, EMI shielding, self-heating, etc.). In this study, the strain and damage sensing possible application of carbon fiber reinforced alkali activated slag pastes has been evaluated. Cement pastes with 0, 0.29 and 0.58 vol % carbon fiber addition were prepared. Both carbon fiber dosages showed sensing properties. For strain sensing, function gage factors of up to 661 were calculated for compressive cycles. Furthermore, all composites with carbon fibers suffered a sudden increase in their resistivity when internal damages began, prior to any external signal of damage. Hence, this material may be suitable as strain or damage sensor.

Carbon Nanofiber Cement Sensors to Detect Strain and Damage of Concrete Specimens Under Compression

Cement composites with nano-additions have been vastly studied for their functional applications, such as strain and damage sensing. The capacity of a carbon nanofiber (CNF) cement paste has already been tested. However, this study is focused on the use of CNF cement composites as sensors in regular concrete samples. Different measuring techniques and humidity conditions of CNF samples were tested to optimize the strain and damage sensing of this material. In the strain sensing tests (for compressive stresses up to 10 MPa), the response depends on the maximum stress applied. The material was more sensitive at higher loads. Furthermore, the actual load time history did not influence the electrical response, and similar curves were obtained for different test configurations. On the other hand, damage sensing tests proved the capability of CNF cement composites to measure the strain level of concrete samples, even for loads close to the material’s strength. Some problems were detected in the strain transmission between sensor and concrete specimens, which will require specific calibration of each sensor one attached to the structure.

Electronic and Electrolytic Conduction of Cement Pastes with Additions of Carbonaceous Materials

Additions to concrete may change some of its basic properties in several ways depending on the nature of these additions. The addition of fibers, in particular, has enabled new concrete characteristics, making standard concrete a very modern composite material. If the fibers are electrical conductors, the properties that change in addition to the mechanical ones, are the thermal and electrical conductivities. The results indicate that the arrangement of the electrodes and the electrode-material interface are relevant, because the use of sponges between electrode and concrete prevents the contact between the metallic electrode and the carbon material which ends in different values of electrical resistance with and without sponges. Moisture conditions, that critically influence the electrical resistance of concrete without additions, resulted, also very relevant when conductive substances are present in the matrix. If the proportion of the carbonaceous addition, that lowers significantly the resistivity, is to be quantified, the best procedure seems to measure in dry concrete (0 % relative humidity) with sponges or, alternatively, wet concrete (100 % relative humidity) with silver painted electrodes (without sponges).

Durability and Mechanical Properties of CNT Cement Composites

Due to their unique intrinsic properties, carbon nanotubes (CNT) are considered potential candidates for developing new functional properties when they are included into the cementitious matrix. This work has the aim of characterising the main properties of CNT Portland cement composites, regarding their mechanical properties and their durability facing corrosion processes. Variation in mechanical properties of mortars with different dosages of CNT and corrosion of embedded steel rebars in CNT cement pastes were investigated. Firstly, bending strength, compression strength, porosity and density of CNT mortars were obtained and compared with the reference (without CNT). Afterwards, CNT reinforced paste specimens were prepared to be exposed to carbonation and chloride attacks. The results on steel corrosion rate tests were related to CNT dosages. The increase in CNT addition implied no significant variations of mechanical properties but slightly higher steel corrosion intensities were found.