O. van Breemen

Geochronological studies of the Bohemian massif, Czechoslovakia, and their significance in the evolution of Central Europe

U–Pb zircon and Rb–Sr whole-rock analyses from various gneisses and plutonie rocks of the Moldanubian and Moravo-Silesian zones and the stable foreland of the Hercynian (Variscan) orogenic belt indicate that most of the crust in Central Europe was first formed during the Cadomian orogeny which straddles the Precambrian–Cambrian boundary. Zircons, however, have a memory of older ages which correspond with those of events known in Fennoscandia. The new radiometrie data are consistent with the stratigraphie record in that they do not provide any evidence for a major early Palaeozoic tectonothermal event between the Cadomian and Hercynian orogenies. Granulites from two localities in the Moldanubian zone yield U–Pb zircon ages of 345 ± 5 Ma; discordant zircon data points indicate that the granulite facies metamorphism was not of long duration. Tectonic units containing these high grade rocks were emplaced amongst amphibolite facies rocks during an event of widespread shearing which has been dated at 341 ± 4 Ma on the basis of a lower U–Pb zircon intercept age from one of the sheared gneisses and 338 ± 3 Ma U–Pb ages from monazites. Rb–Sr muscovite ages of 331 ± 5 Ma from pegmatites axial planar to asymmetrical folds date the last stage of SE-directed simple shear. A Rb–Sr whole-rock isochron of 331 ± 4 Ma from a principal magmatic type of the Central Bohemian pluton confirms the field evidence that the large NE-trending plutons of the Moldanubian zone were emplaced during a late stage of the deformation. The strong disturbance of the U–Pb zircon isotopic system in the sheared gneisses suggests U loss while a high U/Th ratio in monazite from one of these tectonised rocks suggests the simultaneous passage of hydrothermal fluids. Thus a crustal source is indicated for the uranium deposits of the Moldanubian zone. Critical to any plate tectonic model for the development of the Middle European Hercynides was the existence of an ocean in Early Devonian times which separated a North European continent from a South European continent(s). The northward movement of the South European continent over a shallowly-dipping subduction zone and subsequent continental collision can explain the high T–low P metamorphism and the imbricated tectonic style of the Moldanubian zone and adjacent Moravo-Silesian zone along the southeastern Hercynian foreland. The temporal separation of granulites and granites implies distinct conditions of formation and it has been suggested that the plutonism, following on from the imbrication of the Cadomian crust, was initiated by the subduction of wet oceanic sediments.

Baddeleyite-zircon relationships in coronitic metagabbro, Grenville Province, Ontario: implications for geochronology

In the high grade gneiss terranes of the Grenville Province in Ontario, metagabbro with silicate coronas around primary olivine and Fe-Ti oxide contains trace amounts of both baddeleyite and zircon. Single baddeleyite crystals with radiating columnar coronas of polycrystalline zircon, in places with outer rims of garnet, are analogous to the coronas around olivine and ilmenite. Single crystals of zircon and baddeleyite without zircon coronas also occur in the same rocks. Both zirconium minerals have been isotopically dated at three widely separated localities. In each case baddeleyite records an igneous crystallization age of ca.1170 Ma, 125 Ma older than the ca.1045 Ma age of the zircons, interpreted to be the age of metamorphism. These data agree well with U-Pb ages obtained from other rocks in the same region and refute the alternative interpretation that silicate coronas in these metagabbros formed during cooling following magmatic crystallization. The age does not support direct correlation with diabase dykes of either the Sudbury or Abitibi swarms northwest of the Grenville Front.

Proterozoic (1.85–1.75 Ga) igneous suites of the Western Churchill Province: granitoid and ultrapotassic magmatism in a reworked Archean hinterland

Paleoproterozoic igneous rocks in the Archean hinterland of the Paleoproterozoic Trans-Hudson orogen (THO) consist of voluminous late syn-orogenic to post-orogenic monzonite to granite (Hudson granitoids; ≈1850–1810 Ma), and contemporaneous ultrapotassic lamprophyre dykes and volcanic rocks (Dubawnt minettes) that are interbedded with alluvial fan and fluvial deposits (Baker Lake Group, lower Dubawnt Supergroup). They were followed at approximately 1750 Ma by rapakivi granite (Nueltin granite) and porphyritic rhyolite associated with aeolian sandstone (Pitz Formation, middle Dubawnt Supergroup). The tectonic cycle ended with the deposition of conglomerates and sandstones in a large sag basin (Thelon Formation, upper Dubawnt Supergroup, ≈1.72 Ga). The Hudson granitoids, which are strongly concentrated northwest of the THO, were broadly synchronous with terminal collision between the Archean Churchill and Superior cratons and the development of NE-trending ductile structures in the Western Churchill Province (WCP) that may be related to tectonic escape to the northeast. They were emplaced at mid-crustal level and no volcanic equivalents are preserved. Fault-bounded basins containing the minette volcanic rocks are located farther west in a domain dominated more by brittle faulting. The Nueltin granites, emplaced during a period of active extensional faulting, are present in a band extending southwest from the minette basins toward a preserved remnant of the sag basin (the Athabasca basin). Hudson granitoids are largely absent from this band but reappear west of it, indicating a higher crustal level of exposure in a downdropped Nueltin ‘corridor’. The Nd isotope composition of the three suites is similar (minettes: eNd,1830 Ma=−5 to −11; Hudson granitoids: eNd,1830 Ma=−7 to −13.5; Nueltin suite: eNd,1750 Ma=−7 to −10.5), and they have late Archean model ages that match those of average Archean WCP rocks. The Hudson granitoids are rich in inherited Archean zircon, and both granitoid suites are interpreted as crustal melts. Some Nueltin granites and Pitz rhyolites are mingled with basalt, and the Nueltin suite fits a commonly cited model for rapakivi granite production, which postulates injection of basalt into extending, brittly faulted crust. The Hudson granitoids are similar to late syn- to post-orogenic plutons in numerous other collisional hinterlands, which are typically associated with ultrapotassic lamprophyres. The minettes, which have high mg# and bear mantle xenocrysts, must have a mantle source component, and their source region could have been subduction-enriched lithospheric mantle. However, their source had only slightly lower time-integrated LREE enrichment than did that of the granitoids, and the incompatible element signatures of the two suites are strikingly similar. The minette source region may have been in a zone of mixed crust and upper mantle, formed during a shortening event which resulted in crustal thickening and subsequent melting at mid-crustal layers to form the Hudson granitoid plutons. The generation and emplacement of minette melts may have been promoted by extension related to a combination of slab breakoff, gravitational collapse of thickened crust, and strike-slip faulting in the deforming hinterland. Subsequent anorogenic rapakivi granite-basalt activity may have been triggered by lithospheric mantle delamination. The hinterland tectonic cycle of the WCP was repeated in other large Archean terranes that were deformed during the early Proterozoic, but the igneous and sedimentary record is unusually complete in the WCP.

Age and origin of the Nigerian mesozoic granites: A Rb-Sr isotopic study

Sixty-four Rb-Sr and two K-Ar isotopic measurements from seven ring complexes in central Nigeria provide evidence for a systematic age trend along a 200 km zone ranging from 174±5 m.y. in the north to 154±4 m.y. in the south. A peak of anorogenic magmatism occurred in the Jos Plateau region about 164±4 m.y. ago. Although a small syenitetrachyte complex at Zaranda, near Bauchi, gives an age of 190±15 m.y., unpublished ages of 290–330 m.y. for the southern Niger ring complexes confirm the existence of an overall southerly decreasing age trend in the Niger-Nigeria province of West Africa.Isotopic measurements on two small, oversaturated syenite intrusions at Zaranda and Pankshin suggest that syenitic liquids had initial 87Sr/86Sr ratios of 0.7048—not significantly different from the mantle range of values, but that related peralkaline silicic variants from the same complexes are depleted in total Sr and have higher 87Sr/86Sr initial ratios characteristic of the earths crust. This variation of initial 87Sr/86Sr ratios in syenite-related granitic liquids of the peralkaline spectrum has also been noted at the Shere Hills, near Jos, and at Liruei, near Kano, and may be representative for all syenite-granite occurrences in the Nigerian Younger Granite province. Such isotopic variations in the initial 87Sr/86Sr ratio may be attributed to “crustal enrichment” of syenitic liquids whose source lies in the mantle.Coarse-grained, peraluminous biotite granites have consistently low initial 87Sr/86Sr ratios in the range 0.706–0.709 (similar to the ca. 600 m.y. Pan-African granites of the basement), and may represent further modifications of originally syenitic liquids in the crust, or the granites may have originated from an independent source within a “dioritio” lower crust.Although the magmatic trends show small variations in the initial 87Sr/86Sr ratio, much higher initial ratios are recorded in granites which have been modified within their roof zone by deuteric (autometamorphic) and/or metasomatic processes.

Age and isotopic studies of some Pan-African granites from North-Central Nigeria

Abstract Twenty-nine Rb-Sr whole-rock isotopic analyses and three U-Pb zircon analyses on foliated granites and largely unfoliated charnockitic rocks indicate that the central part of the Pan-African belt in west Africa was characterised by intense orogenic plutonism. These data and Rb-Sr analyses on muscovite books from late cross-cutting pegmatites indicate that the peak of magmatic activity occurred 610 ± 10 m.y. ago. Initial 87 Sr/ 86 Sr ratios for the granitic and charnockitic rocks are in the range 0.7065–0.7125, and indicate a significantly older crustal component in the magmas.

Field and isotopic evidence for a c. 750 Ma tectonothermal event in Moine rocks in the Central Highland region of the Scottish Caledonides

Evidence is presented for a late Proterozoic, tectonothermal event which affected the rocks of the Moine assemblage in the Central Highland region of the Scottish Caledonides c. 750 Ma ago. This is about 200 Ma before the early Palaeozoic Grampian orogeny, whose effects are superimposed on the Moine rocks as well as dominating the tectonism in the Dalradian Supergroup. Field and isotopic studies are integrated in zones of ductile thrusting (sliding) which are typified by belts of tectonic schists with related swarms of quartz and muscovite-bearing pegmatite veins. Of particular significance is a ductile thrust (the Grampian slide) which separates deeper crustal rocks (the Central Highland division), interpreted as showing the imprint of the Grenville orogeny, from shallower rocks (the Grampian division) representing a supracrustal assemblage formed between the Grenville and the c. 750 Ma events. The Grampian slide is the structurally highest member of a system of related, previously unrecorded slides affecting the Central Highland division. New structural, petrographic and Rb-Sr isotopic data, obtained largely from a recently recognised inlier of the Central Highland division at Laggan, bear out that the quartz and pegmatite veins are segregations formed during ductile shearing under amphibolite facies conditions. Muscovites from these veins yield ages between 780 and 730 Ma, and a regression analysis of tectonic schists and the muscovites gives an age of 740 ± 40 Ma. These data substantiate our previous hypothesis that the deeper-seated Moine rocks were affected by a distinct orogenic event at 750 ± 30 Ma. In the Northern Highlands, similar vein swarms are related to the Sgurr Beag slide and to belts of previously unrecorded tectonic schists in the Glenfinnan division of the Moine assemblage. A new, 755 ± 8 Ma age obtained from such a tectonic schist at Kinloch Hourn, combined with previous, similar age data from lensoid pegmatites, imply that the c. 750 Ma event may have also affected the Morar and Glenfinnan divisions.

Sm-Nd isotopic study of garnets and their metamorphic host rocks

In this feasibility study, Sm/Nd and 143 Nd/ 144 Nd ratios have been determined on garnets and coexisting mineral and whole-rock phases from a selection of amphibolite facies rocks, granulite facies rocks and an eclogite. In two micaceous schists and an eclogite the distribution coefficient of the Sm/Nd ratio in garnet relative to other phases is in the range 2-3, i.e. comparable to values for phenocrysts in igneous rocks. In two granulite facies rocks the garnets have Sm/Nd distribution coefficients relative to other phases in the range 13-20 and have yielded precise ages. Garnet from a granulite facies shear zone from the Limpopo belt in southern Africa, of Archaean age, has yielded concordant duplicate ages of 1974±14 Ma and 1988±14 Ma. These results have been interpreted as relating to the last tectonic event in the region, long after the main gneiss-forming event. Garnet from a granulite facies xenolith from a Carboniferous vent in the Midland Valley of Scotland has yielded an age of 356±10 Ma; this is related to the onset of basic magmatism in the region.

Pb isotopic composition of late Archaean granites and the extent of recycling early Archaean crust in the Slave Province, northwest Canada

Initial Pb isotopic compositions have been determined for potassium feldspar from ca. 2.58 to 2.62 Ga plutonic rocks in the southern and central Slave Province of northwestern Canada to evaluate the extent of recycling of ancient crust within the province. Large differences in initial Pb compositions were measured which correlate with geographical areas of the province. Plutons in the east-central part of the province have initial compositions only slightly more radiogenic than estimated mantle values (207Pb/204Pb 14.8–14.9), and were dominantly deruved from juvenile crustal sources. In contrast, plutons in the Point Lake and western Contwoyto Lake areas of the western Slave Province have radiogenic compositions (207Pb/204Pb 15.1–15.2), and indicate significant recycling of pre-3.5 Ga crust. The Pb data support previous interpretations, based on Nd isotopes, for a major isotopic boundary in the central part of the province. Granites from the southern part of the province, near Yellowknife, have intermediate compositions which indicate: (1) the age of the protolith to the granitoids in the Yellowknife area is younger than at Point Lake, but older than in the eastern Slave; or (2) the granitoids in the Yellowknife area contain a mixture of an older Point Lake-type component and younger crust. The absence of pre-3.2 Ga crust in the Yellowknife area and lack of evidence for pre-2.8 Ga inherited zircons in the Yellowknife granitoids favour the former possibility. Evidence for recycling of ancient crustal sources, such as the Acasta Gneiss, is limited to a relatively small area of the west-central part of the province, suggesting that Acasta aged, or derived, crust is not widespread in the province. The marked regionality of isotopic composition may reflect a basement in the western part of the province which is itself a collage of crust of different age, being younger (ca 3.2-2.9) in the south, relative to the Point Lake region (3.9-3.2 Ga).

U-Pb zircon, monazite and Rb-Sr whole rock systematics of granitic gneiss and psammitic to semi-pelitic host gneiss from Glenfinnan, Northwestern Scotland

New U-Pb zircon data from a segregation pegmatite in the granitic gneiss at Glenfinnan yield discordant points which appear to be aligned along a chord on a concordia diagram with upper and lower intersection ages of 1,517±30 Ma and 556±8 Ma, respectively. The results are similar to published U-Pb zircon data from the granitic gneiss but the lower intersection age does not correspond to concordant ages of 455±3 Ma obtained for monazites from the segregation pegmatite and from paragneiss which hosts the granitic gneiss. The apparent U-Pb zircon chord also gives no indication of a 1,030±50 Ma (large sample) Rb-Sr whole rock isochron age for the granitic gneiss (Brook et al. 1976). A traverse of adjacent 5–8 cm thick slabs in the paragneiss yields a Rb-Sr ‘errochron’ of 455±60 Ma which also does not agree with the U-Pb zircon lower intersection age. The scale of this Sr whole rock diffusion (ca. 10 cm) is not at variance with existing thermal, temporal and experimental constraints.A two episodic loss model has been applied to the zircon data from the segregation pegmatite, to the previously published zircon data on the granitic gneiss and to new U-Pb zircon data on the host paragneiss. The first lead loss event, if assumed to be in Grenville time, was computed to be strongest in the granitic gneiss and segregation pegmatite. For the three suites of zircon considered, primary ages converge in the 1,700–1,800 Ma range with a final disturbance event at ca. 490 Ma, i.e., close to a plausible prograde stage of Caledonian metamorphism.The zircons in both the granitic gneiss and the paragneiss are believed to have been derived from the ubiquitous early Proterozoic shields bordering the North Atlantic. Furthermore the above model is consistent with the hypothesis that the zircons in the granitic gneiss were largely derived from the paragneiss. However, the U-Pb zircon data are not inconsistent with new Sr-isotopic evidence which suggests an additional, possibly deeper source with lower 87Sr/ 86Sr ratios.

Sr isotopes and the structural state of feldspars as indicators of post-magmatic hydrothermal activity in continental dolerites

Late-crystallised interstitial alkali feldspars and a single epidote from selected Proterozoic dolerites in Sweden have higher initital 87Sr/86Sr ratios, (e.g., 0.709) than the early-crystallised minerals of the same rocks (∼ 0.704); anomalies in Rb and Sr concentrations are also noted. This radiogenically-enriched Sr must originate in the older host rocks of the intrusions. As the contaminated phases often occupy <1 % of the dolerite, only an aqueous fluid would have been capable of transporting the contamination through the 99% solid intrusions. Textural association of late feldspars with hydrous alteration products supports this interpretation. Feldspar structural data suggest that most dolerites have been affected by subsolidus aqueous fluids, causing extensive structural re-equilibration in interstitial K-feldspars, as well as occasional metasomatic effects. Anomalies in 87Sr developed only where the fluids interacted with host rocks.