Oleg B. Vitrik

Formation of nanobumps and nanoholes in thin metal films by strongly focused nanosecond laser pulses

Nanobumps and nanoholes have been formed in gold and silver films with various thicknesses on a dielectric substrate by strongly focused single nanosecond pulses of a Nd:YAG laser. An apertureless dielectric fiber probe and an aspherical lens with a numerical aperture of 0.5 were used to focus laser radiation into a diffraction-limited spot on the surface of gold and silver films, respectively. Atomic force and electron microscopy studies have demonstrated that the shape and dimension of nanostructures, as well as the threshold parameters of laser radiation for their formation, are determined by the thickness of a modified film (“size effect”) and by the duration of a laser pulse owing to the lateral heat conduction in films (nonlocal energy deposition effect). Mechanisms of the dynamic formation of such structures in metallic films by nanosecond laser pulses due to phase transformations of their material have been discussed.

Ion-beam assisted laser fabrication of sensing plasmonic nanostructures

Simple high-performance, two-stage hybrid technique was developed for fabrication of different plasmonic nanostructures, including nanorods, nanorings, as well as more complex structures on glass substrates. In this technique, a thin noble-metal film on a dielectric substrate is irradiated by a single tightly focused nanosecond laser pulse and then the modified region is slowly polished by an accelerated argon ion (Ar+) beam. As a result, each nanosecond laser pulse locally modifies the initial metal film through initiation of fast melting and subsequent hydrodynamic processes, while the following Ar+-ion polishing removes the rest of the film, revealing the hidden topography features and fabricating separate plasmonic structures on the glass substrate. We demonstrate that the shape and lateral size of the resulting functional plasmonic nanostructures depend on the laser pulse energy and metal film thickness, while subsequent Ar+-ion polishing enables to vary height of the resulting nanostructures. Plasmonic properties of the fabricated nanostructures were characterized by dark-field micro-spectroscopy, Raman and photoluminescence measurements performed on single nanofeatures, as well as by supporting numerical calculations of the related electromagnetic near-fields and Purcell factors. The developed simple two-stage technique represents a new step towards direct large-scale laser-induced fabrication of highly ordered arrays of complex plasmonic nanostructures.

Nanoscale boiling during single-shot femtosecond laser ablation of thin gold films

A nanoscale chaotic relief structure appears as a result of subthreshold single-shot femtosecond laser ablation of gold films in the regimes of fabrication of microbumps and nanospikes, but only for a relatively thick film. The observed nanoablation tendency versus film thickness makes it possible to suppose the existence of a sub-surface temperature maximum in thicker gold films and its absence within thinner film, which results from competing evaporative cooling and electronic heat conduction, as demonstrated by numerical simulations of the thermal dynamics.

High-quality fiber microaxicons fabricated by a modified chemical etching method for laser focusing and generation of Bessel-like beams

The fabrication method of the high-quality fiber microaxicons (FMAs) on the endface of the optical fiber was developed. Using several types of the commercially available optical fibers we experimentally demonstrated the fabrication of a high-quality FMA focusing a laser beam into a tiny spot with a FWHM≈0.6λ and Bessel-like field distribution. It was also demonstrated that choosing the appropriate chemical composition of the etching solution makes it possible to change the shape of the FMA tip from conical to hemispherical. This allows one to change the spatial distribution of the output laser beam, which can represent both the Bessel-like beam with a depth of focus of up to 49λ and a very tiny focal spot close to the diffraction limit size. Experimentally measured focusing characteristics of the fabricated FMAs obtained using a homemade collection-mode scanning near-field optical microscope setup demonstrate good agreement with numerical simulations based on the 3D finite-difference time-domain simulations.

Fabrication of porous metal nanoparticles and microbumps by means of nanosecond laser pulses focused through the fiber microaxicon

We present a novel optical element - fiber microaxicon (FMA) for laser radiation focusing into a diffraction-limited spot with Bessel-like profile as well as for precision laser nanostructuring of metal film surfaces. Using the developed FMA for single-pulse irradiation of Au/Pd metal films on quartz substrate we have demonstrated the formation of submicron hollow microbumps with a small spike atop as well as hollow spherical nanoparticles. Experimental conditions for controllable and reproducible formation of ordered arrays of such microstructures were defined. The internal structure of the fabricated nanoparticles and nanobumps was experimentally studied using both argon ions polishing and scanning electron microscopy. These methods reveal a porous inner structure of laser-induced nanoparticles and nanobumps, which presumably indicates that a subsurface boiling of the molten metal film is a key mechanism determining the formation process of such structures.

Analysis of surface plasmon resonance in bent single-mode waveguides with metal-coated cladding by eigenmode expansion method

A numerical study is presented of surface plasmon waves excitation in a metal film applied to the cladding of a standard bent single-mode optical fiber. It was shown that by adjusting the bend radius and metal film thickness one can achieve effective coupling between the fiber fundamental mode and symmetric surface plasmon mode through the intermediary of whispering gallery modes supported by the cladding of the bent fiber. This effect is demonstrated to allow for refractometric measurement both in the wavelength and intensity-modulated regimes with a resolution of up to 10⁻⁸ RIU. Usage of standard noise reduction techniques for intensity-modulated optical signals promises further increase in accuracy.

Conditions for surface plasmon resonance excitation by whispering gallery modes in a bent single mode optical fiber for the development of novel refractometric sensors

This paper discusses a novel technique for high-precision refractometric measurements using surface plasmon resonance (SPR). A new SPR sensor configuration is proposed wherein surface plasmon resonance is excited on the metal-coated outside of a bent single mode optical fiber by whispering gallery modes. The conditions for SPR excitation and registration of SPR wavelength are discussed. The best metal for the proposed sensor configuration is found to be silver. Calculations are carried out on the dependence of SPR wavelength on the measured refractive index. The maximum resolution of refractometric measurements by the proposed technique is estimated at ?10?8.

Application of Optical Time-Domain Reflectometry for the Interrogation of Fiber Bragg Sensors

A reflectometric approach is proposed for the polling and multiplexing of sensitive elements on fiber Bragg gratings (FBGs). The method is based on the power measurement of the radiation reflected by the FBG using a conventional fiber-optic time-domain reflectometer. The multiplexing of sensors is based on the time separation of signals. Requirements on the Bragg diffraction gratings that provide the linear dependence of the received signal on the FBG mechanical stress and temperature are determined. In the measurements of the FBG relative elongation and temperature, the threshold sensitivities are 0.8 × 10−4 (80 μstrain) and 5°C, respectively. Due to its simplicity and efficiency, the reflectometric method of FBG polling and multiplexing can be used to solve various measurement problems, in particular, the safety monitoring of the stressed-strained elements in building structures.

Direct laser printing of chiral plasmonic nanojets by vortex beams

Donut-shaped laser radiation, carrying orbital angular momentum, namely optical vortex, was recently shown to provide vectorial mass transfer, twisting transiently molten material and producing chiral micro-scale structures on surfaces of different bulk materials upon their resolidification. In this paper, we show that at high-NA focusing nanosecond laser vortices can produce chiral nanoneedles (nanojets) of variable size on thin films of such plasmonic materials, as silver and gold films, covering thermally insulating substrates. Main geometric parameters of the produced chiral nanojets, such as height and aspect ratio, were shown to be tunable in a wide range by varying metal film thickness, supporting substrates, and the optical size of the vortex beam. Donut-shaped vortex nanosecond laser pulses, carrying two vortices with opposite handedness, were demonstrated to produce two chiral nanojets twisted in opposite directions. These results suggest optical interference of the incident and reflected laser beams as a source of complex surface intensity distributions in metal films, possessing spiral components and driving both center-symmetric and spiral thermocapillary melt flows to yield in frozen nanoneedles with their pre-determined spiral nanocarving.

Structure and laser-fabrication mechanisms of microcones on silver films of variable thickness

Submicron dimensions, nanoscale crystalline structure, and fabrication mechanisms of microcones on silver films of variable (50–380 nm) thickness deposited onto glass substrates by single strongly focused femtosecond laser pulses of different fluences are experimentally studied using scanning electron microscopy. Fabrication mechanisms for nanoholes and microcones are discussed for films of the different thickness, as well as the extraordinary shapes of their constituent nanocrystallites, strongly elongated along the melt flow direction in thin films.