Oleg Y. Lyakin | Researchain

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Featured researches published by Oleg Y. Lyakin.

Journal of the American Chemical Society | 2009

EPR spectroscopic trapping of the active species of nonheme iron-catalyzed oxidation.

Oleg Y. Lyakin; Konstantin P. Bryliakov; George J. P. Britovsek; Evgenii P. Talsi

The key intermediate of a bioinspired iron catalyst for selective hydrocarbon oxidation based on hydrogen peroxide and an iron complex with a tetradentate aminopyridine ligand was trapped by EPR. On the basis of EPR and reactivity data this intermediate is tentatively proposed to be an oxoiron(V) complex.

ACS Catalysis | 2012

Asymmetric Epoxidations with H2O2 on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study

Oleg Y. Lyakin; Roman V. Ottenbacher; Konstantin P. Bryliakov; Evgenii P. Talsi

Journal of Catalysis | 2009

Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features

Marina V. Kirillova; Yuriy N. Kozlov; Lidia S. Shul’pina; Oleg Y. Lyakin; Alexander M. Kirillov; Evgenii P. Talsi; Armando J. L. Pombeiro; Georgiy B. Shul’pin

Inorganic Chemistry | 2011

EPR, 1H and 2H NMR, and reactivity studies of the iron-oxygen intermediates in bioinspired catalyst systems.

Oleg Y. Lyakin; Konstantin P. Bryliakov; Evgenii P. Talsi

ACS Catalysis | 2015

EPR Spectroscopic Detection of the Elusive FeV═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes

Oleg Y. Lyakin; Alexandra M. Zima; D. G. Samsonenko; Konstantin P. Bryliakov; Evgenii P. Talsi

Organometallics | 2010

In Situ EPR Monitoring of Chromium Species Formed during Cr−Pyrrolyl Ethylene Trimerization Catalyst Formation

Igor Y. Skobelev; Valentina N. Panchenko; Oleg Y. Lyakin; Konstantin P. Bryliakov; Vladimir A. Zakharov; Evgenii P. Talsi

Catalysis Communications | 2012

EPR detection of Fe(V)=O active species in nonheme iron-catalyzed oxidations

Oleg Y. Lyakin; Irene Prat; Konstantin P. Bryliakov; Evgenii P. Talsi

Organometallics | 2009

Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

Igor E. Soshnikov; Nina V. Semikolenova; Alexey Bushmelev; Konstantin P. Bryliakov; Oleg Y. Lyakin; Carl Redshaw; Vladimir A. Zakharov; Evgenii P. Talsi

ACS Catalysis | 2016