Olga Starostenko

Irradiated Recycled High Density Polyethylene Usage as a Modifier for Bitumen

AbstractThis paper studies the use of recycled high-density polyethylene (HDPER) obtained from waste bottle crates as modifier in bitumen. Post-consumer HDPE was irradiated in order to casue a chemical interaction with bitumen. Accordingly, Fourier transform infrared (FTIR) spectroscopy was employed to determine the effects of the electron beam irradiation on the chemical structure of HDPE. Differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and fluorescent microscopy results signified that there might be a chemical interaction between electron beam irradiated HDPE (HDPERe) and bitumen. Physical and rheological tests were applied to the binders to investigate the effects of HDPERe polymer on the performance of the bitumen. Fundamental rheological tests performed using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) indicate that the HDPERe modifier provides a clear improvement in temperature susceptibility of bitumen. Thus, the HDPERe modification produces enhanced ...

Effect of Gamma-Irradiated Recycled Low-Density Polyethylene on the High- and Low-Temperature Properties of Bitumen

This paper describes polymer modification of bitumen with gamma-irradiated recycled (γ-) low-density polyethylene. The recycled low-density polyethylene () was obtained from greenhouse films exposed to sunlight at least one year. The surface of the was treated by gamma beam irradiation that provided formation of free radicals and some functional groups that may contribute to the creation of strong chemical bonds between polymer modifier and bitumen. Five different samples of bitumen/γ- compositions with the modifier content, wt. %: 1, 3, 5, 7 and 9, were prepared. The effects of the γ- on original and aged bitumen were investigated by means of morphological, chemical, and physical testing program, including FTIR spectroscopy, conventional tests, rotational viscosity (RV), dynamic shear rheometer (DSR), and bending beam rheometer (BBR) tests. Superior performing asphalt pavements (Superpave) specifications were used to analyze mechanical test results as well as to determine the performance grades (PG) of the binders. Optimum usage of the γ- as modifier in bitumen were suggested after testing program. The results reveal the stiffening effect of the γ- on bitumen that provide enhanced temperature susceptibility and also promise better performance grades (PG) with γ- polymer modification.

High Value Composites from Recycled Polyolefins and Rubbers

The novel technology for producing high value thermoplastic dynamic vulcanizates (TDVs) from recycled polyolefins and ground tire rubber (GTR) has been developed. The producing high performance composites of tensile properties on the level of TDV s based on virgin components is assured by using ethylene-propylene-diene monomer rubber (EPDM) as a rubber compatibilizer, bitumen as a devulcanizing agent for GTR as well as plasticizing and compatibilizing agent for TDV components.

Use of maleic anhydride grafted recycled polyethylene treated by irradiation in bitumen modification

Most of the polymers currently used as additive in bitumen are not economically attractive. Thus, employing recycled materials in flexible highway instead of virgin ones has become a fundamental case for researchers especially in terms of cost efficiency and environmental awareness. To date, many studies have been made to investigate using of recycled polymers in bitumen and generally improved mechanical properties of bitumen were determined. This paper aims to present the modification of bitumen by maleic anhydride (MAH) grafted recycled low density polyethylene treated by irradiation (g-LDPEr-g-MA). Maleic anhydride was dissolved and mixed with recycled polyethylene which was proved by the Fourier infrared (FT-IR) spectrum. Subsequently, pre-treated LDPEr granules were subjected to gamma irradiation doze of 10kGy to provide formation of free radicals and some functional groups which can contribute to creation of strong chemical bonds between polymer modifier and bitumen. Six different binders (one base and five modified) were prepared to investigate the effects of g-LDPEr-g-MA modifier on properties of bitumen. The dispersion of g-LDPEr-g-MA modifier in bitumen was examined by florescent microscope. Conventional tests and rotational viscosity test was used to determine physical properties of bitumens. Complex shear modulus (G*) and phase angle (δ) of base and modified bitumens were measured by means of dynamic shear rheometer (DSR) for different traffic speed and in-service pavement temperature. Tests results reveal that a gradually increment in g-LDPEr-g-MA modification leads to a decrease in penetration and an increase in softening point. According to DSR test results, g-LDPEr-g-MA modifier provides an increased rutting parameter. Thus, flexible pavement could become more resistant against permeant deformations by g-LDPEr-g-MA modification.

Viscoelastic behaviour, thermal properties and morphology for new composites from recycled HDPE, EPDM, ground tyre rubber (GTR) and bitumen

ABSTRACT Structure-property relationships for new composites prepared from recycled HDPE, EPDM, ground tyre rubber (GTR) and bitumen have been studied by a combination of DMTA, DSC and SEM techniques and tensile tests. The better mechanical performance determined for a composition containing a preheated and rolled mixture of GTR and bitumen have been explained by a better mixing of the components and formation of the essential interface layer due to the reclaiming (for GTR) and compatibilizing (for composite) role of the bitumen.