Oliver Nebel

Eoarchean within-plate basalts from southwest Greenland

The majority of >3 Ga metabasalts have chemical features, such as high field strength element (HFSE) depletions, that are characteristic of modern island-arc basalts. These compositions have been interpreted as evidence for subduction of oceanic crust early in Earth’s history. Alternatively, the apparent absence of Archean mafic rocks with mid-oceanic ridge basalt (MORB) and ocean island basalt (OIB) compositions and the ubiquitous occurrence of metabasalts with HFSE anomalies suggest that these chemical features may instead be a widespread characteristic of the Archean mantle related to early chemical differentiation and unrelated to modern-style recycling of crust. Here we present major- and trace-element data for a suite of metabasalts from Innersuartuut Island, southwest Greenland, which have a minimum age constraint of 3.75 Ga and are likely as old as ≥3.85 Ga. Samples from Innersuartuut show no evidence for crustal contamination or subduction-related magmatism, and have a petrogenesis comparable to modern OIB. The new data demonstrate that a compositional range for volcanic rocks comparable to that seen in the Phanerozoic existed in the Eoarchean. Therefore, rather than a global anomaly, subduction-related processes are the likely origin for the compositions of the most commonly preserved Archean mafic rocks with island-arc basalt characteristics.

Selective ingress of a Samoan plume component into the northern Lau backarc basin

Intra-plate basalt isotopic trends require mixing between enriched mantle components (EM1, EM2, HIMU) and a primordial component with high (3)He/(4)He termed FOZO. However, proportions of components, geometric distributions within individual plumes, relative proportions of melting components and loci of mixing of melts and residues remain poorly understood. Here we present new Hf-Nd isotopic data of dredged sea floor basalts from the northern Lau backarc basin, ~250 km south of the subaerial and submerged Samoan chain, with high (3)He/(4)He, (20)Ne/(22)Ne and primordial (129)Xe/(130)Xe, characteristic of the FOZO component. Combined Hf-Nd-noble gas isotope systematics require mixing of refractory, sub-northwestern Lau backarc mantle only with a spatially restricted FOZO component, most plausibly sourced from part of the Samoan plume. Other geographically restricted and possibly volumetrically minor enriched Samoan plume components are not detectable in northern Lau backarc samples, consistent with selective plume ingress of the FOZO component beneath the basin.

Maturing Arc Signatures Monitored by Trace Element and Hf Isotope Systematics in the Early Cretaceous Zacatecas Volcanic Field, Mexico

Mesozoic growth of continental crust along the southwestern margin of North America and its southern extension in Mexico has been partly explained by the accretion of terranes. These terranes have been considered to be fragments of exotic, intraoceanic island arcs that approached mainland Mexico after the Early Cretaceous. Trace elements and Lu-Hf isotopic systematics for primitive arc successions of the Zacatecas Volcanic Field indicate a close relationship with parts of the northern Guerrero superterrane. Major and trace element systematics of lava flows and dioritic rocks from laccoliths suggest a cogenetic origin of the Zacatecas Formation and Las Pilas Complex rocks, here combined in the Zacatecas Group. This group represents a single arc succession that evolves from a primitive to mature arc. Initial 176Hf/177Hf (age corrected to 130 Ma) ranges from 0.28296 to 0.28307, corresponding to εHf(t) = +9.3 to +13.4, indicating a source related to a depleted mantle wedge with a superimposed subducted sediment contribution. Based on combined field and geochemical evidence, we propose an arc model and suggest a spatial extension of paleoarc spreading north–south from Baja California beyond the present-day Trans-Mexican Volcanic Belt in the Early Cretaceous.

Coherence of the Dabie Shan UHPM terrane investigated by Lu-Hf and 40 Ar/ 39 Ar dating of eclogites

Publisher Summary The Central China Orogenic Belt (CCOB) is the largest known ultrahigh-pressure metamorphic (UHPM) belt. It extends from Sulu in Eastern China, via the Dabie, Qinling, and North Qaidam mountains to Altyn Tagh some 3000 km to the west. Since the discovery of coesite and diamond-bearing metamorphic rocks in Dabie Shan, the belt has been studied intensively. Some of the results have led to controversy regarding the number of (U)HP metamorphic events and their absolute and relative ages. The prominence of Dabie Shan as part of the largest UHPM belt is reflected by a wealth of published work since the discovery of coesite over 20 years ago. Despite two decades of efforts to decipher its geologic secrets, interpretation of the many reported isotopic ages of the Dabie Shan terrane that aimed to address its metamorphic history is still hampered by the absence of robust thermobarometric data for the same samples. Pre-Triassic metamorphism cannot be traced by Lu–Hf Grt–Cpx geochronology in the main volume of Dabie Shan, which was subjected to Triassic (U)HP metamorphism. The Triassic event erased previous signatures of some, but not all isotopic systems, as is evident from zircon U-Pb ages.

Refined separation of combined Fe-Hf from rock matrices for isotope analyses using AG-MP-1M and Ln-Spec chromatographic extraction resins

Graphical abstract

When crust comes of age: on the chemical evolution of Archaean, felsic continental crust by crustal drip tectonics

The secular evolution of the Earths crust is marked by a profound change in average crustal chemistry between 3.2 and 2.5 Ga. A key marker for this change is the transition from Archaean sodic granitoid intrusions of the tonalite–trondhjemite–granodiorite (TTG) series to potassic (K) granitic suites, akin (but not identical) to I-type granites that today are associated with subduction zones. It remains poorly constrained as to how and why this change was initiated and if it holds clues about the geodynamic transition from a pre-plate tectonic mode, often referred to as stagnant lid, to mobile plate tectonics. Here, we combine a series of proposed mechanisms for Archaean crustal geodynamics in a single model to explain the observed change in granitoid chemistry. Numeric modelling indicates that upper mantle convection drives crustal flow and subsidence, leading to profound diversity in lithospheric thickness with thin versus thick proto-plates. When convecting asthenospheric mantle interacts with lower lithosphere, scattered crustal drips are created. Under increasing P-T conditions, partial melting of hydrated meta-basalt within these drips produces felsic melts that intrude the overlying crust to form TTG. Dome structures, in which these melts can be preserved, are a positive diapiric expression of these negative drips. Transitional TTG with elevated K mark a second evolutionary stage, and are blends of subsided and remelted older TTG forming K-rich melts and new TTG melts. Ascending TTG-derived melts from asymmetric drips interact with the asthenospheric mantle to form hot, high-Mg sanukitoid. These melts are small in volume, predominantly underplated, and their heat triggered melting of lower crustal successions to form higher-K granites. Importantly, this evolution operates as a disseminated process in space and time over hundreds of millions of years (greater than 200 Ma) in all cratons. This focused ageing of the crust implies that compiled geochemical data can only broadly reflect geodynamic changes on a global or even craton-wide scale. The observed change in crustal chemistry does mark the lead up to but not the initiation of modern-style subduction. This article is part of a discussion meeting issue ‘Earth dynamics and the development of plate tectonics’.

A non-zircon Hf isotope record in Archean black shales from the Pilbara craton confirms changing crustal dynamics ca. 3 Ga ago

Plate tectonics and associated subduction are unique to the Earth. Studies of Archean rocks show significant changes in composition and structural style around 3.0 to 2.5 Ga that are related to changing tectonic regime, possibly associated with the onset of subduction. Whole rock Hf isotope systematics of black shales from the Australian Pilbara craton, selected to exclude detrital zircon components, are employed to evaluate the evolution of the Archean crust. This approach avoids limitations of Hf-in-zircon analyses, which only provide input from rocks of sufficient Zr-concentration, and therefore usually represent domains that already underwent a degree of differentiation. In this study, we demonstrate the applicability of this method through analysis of shales that range in age from 3.5 to 2.8 Ga, and serve as representatives of their crustal sources through time. Their Hf isotopic compositions show a trend from strongly positive εHfinitial values for the oldest samples, to strongly negative values for the younger samples, indicating a shift from juvenile to differentiated material. These results confirm a significant change in the character of the source region of the black shales by 3 Ga, consistent with models invoking a change in global dynamics from crustal growth towards crustal reworking around this time.