Olivier Magand

Ground-based measurements of spatial and temporal variability of snow accumulation in East Antarctica

The East Antarctic Ice Sheet is the largest, highest, coldest, driest, and windiest ice sheet on Earth. Understanding of the surface mass balance (SMB) of Antarctica is necessary to determine the present state of the ice sheet, to make predictions of its potential contribution to sea level rise, and to determine its past history for paleoclimatic reconstructions. However, SMB values are poorly known because of logistic constraints in extreme polar environments, and they represent one of the biggest challenges of Antarctic science. Snow accumulation is the most important parameter for the SMB of ice sheets. SMB varies on a number of scales, from small-scale features (sastrugi) to ice-sheet-scale SMB patterns determined mainly by temperature, elevation, distance from the coast, and wind-driven processes. In situ measurements of SMB are performed at single points by stakes, ultrasonic sounders, snow pits, and firn and ice cores and laterally by continuous measurements using ground-penetrating radar. SMB for large regions can only be achieved practically by using remote sensing and/or numerical climate modeling. However, these techniques rely on ground truthing to improve the resolution and accuracy. The separation of spatial and temporal variations of SMB in transient regimes is necessary for accurate interpretation of ice core records. In this review we provide an overview of the various measurement techniques, related difficulties, and limitations of data interpretation; describe spatial characteristics of East Antarctic SMB and issues related to the spatial and temporal representativity of measurements; and provide recommendations on how to perform in situ measurements.

Climate variability along latitudinal and longitudinal transects in East Antarctica

Abstract In the framework of the International Trans-Antarctic Scientific Expedition (ITASE) programme, France and Italy carried out a traverse along one west–east and two north–south transects in East Antarctica from November 2001 to January 2002. Eighteen shallow snow–firn cores were drilled, and surface snow samples were collected every 5km along the traverse. Firn temperatures were measured in boreholes down to 30 m. The cores were analyzed for β radioactivity to obtain snow accumulation-rate data. The surface snow samples were analyzed for δ18O to correlate isotopic values with borehole temperatures. Multiple regression analysis shows a global near-dry-adiabatic lapse rate and a latitudinal lapse rate of 1.05˚C(˚ lat. S)–1, in the Dome C drainage area. Analysis of firn temperatures reveals a super-adiabatic lapse rate along the ice divide between Talos Dome and the Southern Ocean coast, and in some sectors along the ice divide between the Astrolabe Basin and D59. Snow accumulation rates and firn temperatures show warmer temperatures and higher accumulation values close to the ice divides extending from Talos Dome and Dome C to the Southern Ocean. The spatial pattern of data is linked with a katabatic-wind-source basin and moisture-source region.

Atmospheric mercury concentrations observed at ground-based monitoring sites globally distributed in the framework of the GMOS network

Long-term monitoring of data of ambient mercury (Hg) on a global scale to assess its emission, transport, atmospheric chemistry, and deposition processes is vital to understanding the impact of Hg pollution on the environment. The Global Mercury Observation System (GMOS) project was funded by the European Commission (http://www.gmos.eu) and started in November 2010 with the overall goal to develop a coordinated global observing system to monitor Hg on a global scale, including a large network of ground-based monitoring stations, ad hoc periodic oceanographic cruises and measurement flights in the lower and upper troposphere as well as in the lower stratosphere. To date, more than 40 ground-based monitoring sites constitute the global network covering many regions where little to no observational data were available before GMOS. This work presents atmospheric Hg concentrations recorded worldwide in the framework of the GMOS project (2010-2015), analyzing Hg measurement results in terms of temporal trends, seasonality and comparability within the network. Major findings highlighted in this paper include a clear gradient of Hg concentrations between the Northern and Southern hemispheres, confirming that the gradient observed is mostly driven by local and regional sources, which can be anthropogenic, natural or a combination of both.

Volcanic and solar activity, and atmospheric circulation influences on cosmogenic 10Be fallout at Vostok and Concordia (Antarctica) over the last 60 years

17 We have compared the yearly production rates of Be by cosmic rays in the Earths polar 18 atmosphere over the last 50-70 years with Be measurements from two separate ice cores in 19 Greenland. These ice cores provide measurements of the annual Be concentration and Be 20 flux levels during this time. The scatter in the ice core yearly data vs. the production data is 21 larger than the average solar 11 year production variations that are being measured. The cross 22 correlation coefficients between the yearly Be production and the ice core Be measurements 23 for this time period are <0.4 in all comparisons between ice core data and Be production, 24 including Be concentrations, Be fluxes and in comparing the two separate ice core 25 measurements. In fact, the cross correlation between the two ice core measurements, which 26 should be measuring the same source, is the lowest of all, only ~0.2. These values for the 27 correlation coefficient are all indicative of a “poor” correlation. The regression line slopes for 28 the best fit lines between the Be production and the Be measurements used in the cross 29 correlation analysis are all in the range 0.4-0.6. This is a particular problem for historical 30 projections of solar activity based on ice core measurements which assume a 1:1 correspondence. 31 We have made other tests of the correspondence between the Be predictions and the ice core 32 measurements which lead to the same conclusion, namely that other influences on the ice core 33 measurements, as large as or larger than the production changes themselves, are occurring. 34 These influences could be climatic or instrumentally based. We suggest new ice core 35 measurements that might help in defining more clearly what these influences are and-if possible36 to correct for them. 37

Sea-spray deposition in Antarctic coastal and plateau areas from ITASE traverses

Abstract Sea-salt markers (Na+, Mg2+ and Cl–) were analyzed in recent snow collected at more than 600 sites located in coastal and central areas of East Antarctica (northern Victoria Land–Dome C–Wilkes Land), in order to understand the effect of site remoteness, transport efficiency and depositional and post-depositional processes on the spatial distribution of the primary marine aerosol. Firn-core, snow-pit and 1m integrated superficial snow samples were collected in the framework of the International Trans-Antarctic Scientific Expeditions (ITASE) project during recent Italian Antarctic Campaigns (1992–2002). The sampling sites were mainly distributed along coast–inland traverses (northern Victoria Land– Dome C) and an east–west transect following the 2100m contour line (Wilkes Land). At each site, the snow ionic composition was determined. Here, we discuss the distribution of sea-spray components (Na+, Mg2+ and Cl–) as a function of distance from the sea, altitude and accumulation rate, in order to discover the pulling-down rate, possible fractionating phenomena and alternative sources moving inland from coastal areas. Sea-spray depositional fluxes decrease as a function of distance from the sea and altitude. A two-order-of-magnitude decrease occurs in the first 200km from the sea, corresponding to about 2000ma.s.l. Correlations of Mg2+ and Cl– with Na+ and trends of Mg2+/Na+ and Cl–/Na+ ratios showed that chloride has other sources than sea spray (HCl) and is affected by post-depositional processes. Accumulation rate higher than 80 kgm–2 a–1 preserves the chloride record in the snow. Sea-spray atmospheric scavenging is dominated by wet deposition in coastal and inland sites.

Radionuclides deposition over Antarctica

A detailed and comprehensive map of the distribution patterns for both natural and artificial radionuclides over Antarctica has been established. This work integrates the results of several decades of international programs focusing on the analysis of natural and artificial radionuclides in snow and ice cores from this polar region. The mean value (37+/-20 Bq m(-2)) of (241)Pu total deposition over 28 stations is determined from the gamma emissions of its daughter (241)Am, presenting a long half-life (432.7 yrs). Detailed profiles and distributions of (241)Pu in ice cores make it possible to clearly distinguish between the atmospheric thermonuclear tests of the fifties and sixties. Strong relationships are also found between radionuclide data ((137)Cs with respect to (241)Pu and (210)Pb with respect to (137)Cs), make it possible to estimate the total deposition or natural fluxes of these radionuclides. Total deposition of (137)Cs over Antarctica is estimated at 760 TBq, based on results from the 90-180 degrees East sector. Given the irregular distribution of sampling sites, more ice cores and snow samples must be analyzed in other sectors of Antarctica to check the validity of this figure.

Influence of Oceanic Boundary Conditions in Simulations of Antarctic Climate and Surface Mass Balance Change during the Coming Century

Abstract This article reports on high-resolution (60 km) atmospheric general circulation model simulations of the Antarctic climate for the periods 1981–2000 and 2081–2100. The analysis focuses on the surface mass balance change, one of the components of the total ice sheet mass balance, and its impact on global eustatic sea level. Contrary to previous simulations, in which the authors directly used sea surface boundary conditions produced by a coupled ocean–atmosphere model for the last decades of both centuries, an anomaly method was applied here in which the present-day simulations use observed sea surface conditions, while the simulations for the end of the twenty-first century use the change in sea surface conditions taken from the coupled simulations superimposed on the present-day observations. It is shown that the use of observed oceanic boundary conditions clearly improves the simulation of the present-day Antarctic climate, compared to model runs using boundary conditions from a coupled climate ...

Do climate models underestimate snow accumulation on the Antarctic plateau? A re-evaluation of/from in situ observations in East Wilkes and Victoria Lands.

Abstract It has been suggested that meteorological and climate models underestimate snow accumulation on the Antarctic plateau, because accumulation (or surface mass balance (SMB)) is dominated by clear-sky precipitation while this process is not properly taken into account in the models. Here, we show that differences between model and field SMB data are much reduced when the in situ SMB reports used to evaluate the models are filtered through quality-control criteria and less reliable reports are subsequently left out. We thus argue that, although not necessarily unsupported, model biases and their interpretations in terms of clear-sky vs synoptic precipitation on the Antarctic plateau may have been overstated in the past. To avoid such misleading issues, it is important that in situ SMB reports of insufficient or unassessed reliability are discarded, even at the cost of a strong reduction in spatial sampling and coverage.

Spatial distribution of biogenic sulphur compounds (MSA, nssSO4 2- ) in the northern Victoria Land-Dome C-Wilkes Land area, East Antarctica

Abstract During the 1992–2002 Antarctic expeditions, in the framework of the International Trans-Antarctic Expedition (ITASE) project, about 600 sites were sampled (superficial snow, snow pits and firn cores) along traverses in the northern Victoria Land–Dome C–Wilkes Land region. The sites were characterized by different geographical (distance from the sea, altitude) and climatological (annual mean accumulation rate, temperature) conditions and were affected by air masses from different marine sectors (Ross Sea, Pacific Ocean). Mean anion and cation contents were calculated at each site, in order to evaluate the spatial distribution of chemical impurities in snow. Here we discuss the distribution of non-sea-salt sulphate (nssSO4 2–) and of methanesulphonic acid (MSA) mainly originating from atmospheric oxidation of biogenic dimethyl sulphide; these compounds play a key role in climate control processes by acting as cloud condensation nuclei. The spatial distribution of nssSO4 2– and MSA is discussed as a function of distance from the sea, altitude and accumulation rate. Depositional fluxes of nssSO4 2– and MSA decrease as a function of distance from the sea, with a higher gradient in the first 200km step. There is an analogous trend with the site altitude, and the first 1600m step is relevant in determining the nssSO4 2– and MSA content in snow. The nssSO4 2–/MSA ratio depends on the distance from the sea and the biogenic source strength. At coastal sites, where biogenic inputs are dominant, this ratio is ~2. As biogenic input decreases (low MSA content) inland, the ratio increases, indicating the presence of alternative sources of nssSO4 2– (crustal, volcanic background) or advection of low-latitude air masses. By plotting total flux as a function of accumulation rate, dry depositional contributions were evaluated for nssSO4 2– and MSA in the Ross Sea and Pacific Ocean sectors. Non-sea-salt sulphate wet deposition prevails at sites where the accumulation rate (expressed as water equivalent) is higher than 70 kgm–2 a–1 (Ross Sea sector) or 370 kgm–2 a–1 (Pacific Ocean sector). MSA threshold values in these sectors are respectively 90 and 220 kgm–2 a–1.

A vegetation control on seasonal variations in global atmospheric mercury concentrations

Anthropogenic mercury emissions are transported through the atmosphere as gaseous elemental mercury (Hg(0)) before they are deposited to Earth’s surface. Strong seasonality in atmospheric Hg(0) concentrations in the Northern Hemisphere has been explained by two factors: anthropogenic Hg(0) emissions are thought to peak in winter due to higher energy consumption, and atmospheric oxidation rates of Hg(0) are faster in summer. Oxidation-driven Hg(0) seasonality should be equally pronounced in the Southern Hemisphere, which is inconsistent with observations of constant year-round Hg(0) levels. Here, we assess the role of Hg(0) uptake by vegetation as an alternative mechanism for driving Hg(0) seasonality. We find that at terrestrial sites in the Northern Hemisphere, Hg(0) co-varies with CO2, which is known to exhibit a minimum in summer when CO2 is assimilated by vegetation. The amplitude of seasonal oscillations in the atmospheric Hg(0) concentration increases with latitude and is larger at inland terrestrial sites than coastal sites. Using satellite data, we find that the photosynthetic activity of vegetation correlates with Hg(0) levels at individual sites and across continents. We suggest that terrestrial vegetation acts as a global Hg(0) pump, which can contribute to seasonal variations of atmospheric Hg(0), and that decreasing Hg(0) levels in the Northern Hemisphere over the past 20 years can be partly attributed to increased terrestrial net primary production.Terrestrial vegetation contributes to the seasonal variation of atmospheric mercury concentrations, according to analyses of atmospheric trace gas dynamics and satellite data. The data show that the photosynthetic activity of vegetation correlates with atmospheric mercury.