Omar M. Basha

CFD Modeling with Experimental Validation of the Internal Hydrodynamics in a Pilot-Scale Slurry Bubble Column Reactor

Abstract A multiphase-Eulerian, three-dimensional (3-D), computational fluid dynamics (CFD) model was built to investigate the local hydrodynamics of a pilot-scale (0.29 m ID, 3 m height) Slurry Bubble Column Reactor (SBCR). The model was first validated against the gas holdup radial profiles in an air-water-glass beads system obtained in a 0.254 m ID and 2.5 m height column under ambient conditions at various superficial gas velocities by Yu and Kim (Bubble characteristics in the radial direction of three-phase fluidized beds. AIChE Journal 34, 2069–2072, 1988). The model was next validated against the gas holdup radial profile data for N2-Drakeol-glass beads system obtained in a 0.44 m ID and 2.44 m height reactor, including internals, operating under ambient conditions at various superficial gas velocities by Chen et al. (Fluid dynamic parameters in bubble columns with internals. Chemical Engineering Science 54, 2187–2197, 1999). The model was also validated against experimental data obtained in our lab for N2-Fischer Tropsch (F-T) reactor wax-Fe catalyst system obtained in a pilot-scale, Slurry Bubble column Reactor, SBCR (0.29 m ID, 3 m height) under pressures and temperatures up to 25.9 bar and 490 K, respectively. These three validations led to the selection of the turbulence and interphase drag coefficient models, and the optimization of the solution method, mesh size and structure and the step size. Moreover, the inclusion of RNG k-ε turbulence model coupled with the Wen-Yu (Mechanics of Fluidization. Chemical Engineering Progress Symposium Series 62, 100–111, 1966) / Schiller-Naumann (A drag coefficient correlation. Zeitung Ver. Deutsch. Ing 77, 318–320, 1935) drag correlations, and the mass transfer coefficients were found to provide the most accurate predictions of the experimental data. The CFD model was then used to investigate local gas holdup, liquid recirculation, local turbulence intensities, bubble diameters, and solids distribution throughout our pilot-scale SBCR, operating under typical F-T process conditions. The model predictions showed strong liquid recirculation and backmixing near the walls of the reactor, and the solid-phase velocity vectors closely followed those of the liquid-phase. A relatively high liquid turbulence intensities were observed in the vicinity of the sparger upon startup, however, after reaching a steady state, the liquid turbulence intensities became more evenly distributed throughout the reactor. The liquid turbulence intensities were slightly higher near the center of the reactor, and closely resembled the velocity vectors. Also, the Sauter mean bubble diameters increased, whereas the solids distribution decreased with reactor height above the gas distributor.

Coal-Agglomeration Processes: A Review

ABSTRACT This article presents an extensive review of the coal-agglomeration process, including oil-agglomeration theory, characterization methods of coal hydrophobicity, and the main factors affecting the agglomeration-process performance in terms of combustible recovery and ash rejection. Coal rank and oxidation state, coal petrography and composition, coal-particle size, pulp density, and pH, bridging-liquid type and concentration, presence of surfactant and electrolytes, bridging-oil emulsification, and agitation intensity as well as time are among the factors here discussed. A chronological overview of the development and milestones of the coal-agglomeration processes is also provided.

Mass Transfer in Multiphase Systems

Mass transfer in reactive and non-reactive multiphase systems is of vital impor‐ tance in chemical, petrochemical, and biological engineering applications. In this chapter, theories and models of mass transfer in gas-liquid, gas-solid and gasliquid-solid systems with and without chemical reactions are briefly reviewed. Literature data on the mass transfer characteristics in multiphase reactors over the last two decades with applications to the Fischer-Tropsch (F-T) synthesis are summarized. Moreover, the F-T reactions are described and an overview of the use of Slurry Bubble Column Reactors (SBCRs) and Multitubular Fixed Bed Reactors (MTFBRs) for low temperature F-T (LTFT) synthesis are discussed. The important factors affecting the hydrodynamic (gas holdup, bubble size/distribu‐ tion) and mass transfer parameters (volumetric mass transfer coefficients) in SBCRs for F-T synthesis, including operating conditions, gas-liquid-solid properties, reactor geometry and internals as well as gas distributors are also discussed. The discussion reveals that the performance of the LTFT SBCR operating in the churnturbulent flow regime is controlled by the resistance in the liquid-side film and/or the F-T reaction kinetics depending on the operating conditions prevailing in the reactor. Also, there is a great need to understand the behavior and quantify the hydrodynamics and mass transfer in SBCRs operating with syngas (H2 + CO) and F-T reactor wax in the presence of active catalyst (iron or cobalt) under typical FT synthesis conditions in a large SBCR with an inside diameter ≥0.15m.

Effect of coal nature on the gasification process

Abstract This chapter presents a comprehensive review of the effects of the physical and chemical properties of coal on the gasification process. These include coal reactivity (rank, macerals, porosity, surface area, mineral matter contents, etc.); ash and slag properties (mineral matter transformation, ash fusibility, slag viscosity, ash agglomeration, fouling, clinkering, etc.); coal particle size and fragmentation; and caking and swelling. Different considerations, such as gasifier types, syngas compositions and ash-related problems during gasification are also discussed. Moreover, methods for preventing ash-related problems during gasification are summarized.

Effects of Sparger and Internals Designs on the Local Hydrodynamics in Slurry Bubble Column Reactors Operating under Typical Fischer-Tropsch Process Conditions - I

Abstract Our rigorously validated Computational Fluid Dynamics (CFD) model (Basha Omar, M., L. Weng, Z. Men, and I. Morsi Badie. 2016. “CFD Modeling with Experimental Validation of the Internal Hydrodynamics in a Pilot-Scale Slurry Bubble Column Reactor.” International Journal of Chemical Reactor Engineering 14(2):599–619), was used to predict the effects of spargers design and internals configuration on the local hydrodynamics and flow structure in a pilot-scale (0.3-m ID) and a large-scale (10-m ID) Slurry Bubble Column Reactors (SBCRs), operating under Fisher-Tropsch (F-T) process conditions. In the pilot-scale SBCR without internals, the 6-arms spider created small/fast liquid recirculations in the vicinity of the sparger and slow/large liquid recirculations at about 1.2 times reactor diameter, whereas, the 3-concentric-rings and perforated plate spargers created slow/large recirculations throughout the reactor. In the pilot-scale SBCR with internals, spargers with downward-pointing orifices created larger Sauter mean bubble diameters (ds), leading to more effective solids suspension when compared with those with upward-pointing orifices. Also, 3-concentric-rings spargers resulted in larger Sauter mean bubble diameter values when compared with those of 6-arms spiders. In the large-scale SBCR provided with a large 3-concentric-rings sparger, the effects of vertical parallel and bundled internals on the local hydrodynamics and flow structures were predicted. Bundled internals led to slower and smaller liquid recirculations, smoother radial gas holdup profiles, larger average gas bubbles size, and smaller local gas holdups, when compared those predicted when using parallel internals.