P. G. J. Irwin

Structure and dynamics of the Martian lower and middle atmosphere as observed by the Mars Climate Sounder: Seasonal variations in zonal mean temperature, dust, and water ice aerosols

[1] The first Martian year and a half of observations by the Mars Climate Sounder aboard the Mars Reconnaissance Orbiter has revealed new details of the thermal structure and distributions of dust and water ice in the atmosphere. The Martian atmosphere is shown in the observations by the Mars Climate Sounder to vary seasonally between two modes: a symmetrical equinoctial structure with middle atmosphere polar warming and a solstitial structure with an intense middle atmosphere polar warming overlying a deep winter polar vortex. The dust distribution, in particular, is more complex than appreciated before the advent of these high (∼5 km) vertical resolution observations, which extend from near the surface to above 80 km and yield 13 dayside and 13 nightside pole-to-pole cross sections each day. Among the new features noted is a persistent maximum in dust mass mixing ratio at 15-25 km above the surface (at least on the nightside) during northern spring and summer. The water ice distribution is very sensitive to the diurnal and seasonal variation of temperature and is a good tracer of the vertically propagating tide.

Cloud structure and atmospheric composition of Jupiter retrieved from Galileo near‐infrared mapping spectrometer real‐time spectra

The first four complete spectra recorded by the near infrared mapping spectrometer (NIMS) instrument on the Galileo spacecraft in 1996 have been analyzed. These spectra remain the only ones which have been obtained at maximum resolution over the entire NIMS wavelength range of 0.7–5.2 μm. The spectra cover the edge of a “warm” spot at location 5°N, 85°W. We have analyzed the spectra first with reflecting layer models and then with full multiple scattering models using the method of correlated-k. We find that there is strong evidence for three different cloud layers composed of a haze consistent with 0.5-μm radius tholins at 0.2 bar, a cloud of 0.75-μm NH3 particles at about 0.7 bar, and a two-component NH4SH cloud at about 1.4 bars with both 50.0- and 0.45-μm particles, the former being responsible for the main 5-μm cloud opacity. The NH3 relative humidity above the cloud tops is found to decrease slightly as the 5-μm brightness increases, with a mean value of approximately 14%. We also find that the mean volume mixing ratio of ammonia above the middle (NH4SH) cloud deck is (1.7±0.1) × 10−4 and shows a similar, though less discernible decrease with increasing 5-μm brightness. The deep volume mixing ratios of deuterated methane and phosphine are found to be constant and we estimate their mean values to be (4.9±0.2) × 10−7 and (7.7±0.2) × 10−7, respectively. The fractional scale height of phosphine above the 1 bar level is found to be 27.1±1.4% and shows a slight decrease with increasing 5-μm brightness. The relative humidity of water vapor is found to be approximately 7%, but while this and all the previous observations are consistent with the assumption that “hot spots” are regions of downwelling, desiccated air, we find that the water vapor relative humidity increases as the 5-μm brightness increases.

Exposed water ice on the nucleus of comet 67P/Churyumov–Gerasimenko

Although water vapour is the main species observed in the coma of comet 67P/Churyumov–Gerasimenko and water is the major constituent of cometary nuclei, limited evidence for exposed water-ice regions on the surface of the nucleus has been found so far. The absence of large regions of exposed water ice seems a common finding on the surfaces of many of the comets observed so far. The nucleus of 67P/Churyumov–Gerasimenko appears to be fairly uniformly coated with dark, dehydrated, refractory and organic-rich material. Here we report the identification at infrared wavelengths of water ice on two debris falls in the Imhotep region of the nucleus. The ice has been exposed on the walls of elevated structures and at the base of the walls. A quantitative derivation of the abundance of ice in these regions indicates the presence of millimetre-sized pure water-ice grains, considerably larger than in all previous observations. Although micrometre-sized water-ice grains are the usual result of vapour recondensation in ice-free layers, the occurrence of millimetre-sized grains of pure ice as observed in the Imhotep debris falls is best explained by grain growth by vapour diffusion in ice-rich layers, or by sintering. As a consequence of these processes, the nucleus can develop an extended and complex coating in which the outer dehydrated crust is superimposed on layers enriched in water ice. The stratigraphy observed on 67P/Churyumov–Gerasimenko is therefore the result of evolutionary processes affecting the uppermost metres of the nucleus and does not necessarily require a global layering to have occurred at the time of the comet’s formation.

Analysis of Jupiter north equatorial belt hot spots in the 4–5 μm range from Galileo/near-infrared mapping spectrometer observations: Measurements of cloud opacity, water, and ammonia

This paper presents the analysis of hot spot observations in the Jovian North Equatorial Belt obtained with the near-infrared mapping spectrometer (NIMS) instrument on the Galileo spacecraft. The data were acquired during the closest approach sequences between June 1996 and April 1997. We focus on the spectral window between 4.5 and 5.2 μm determining the cloud opacity above 2 bar, the water vapor relative humidity, and the ammonia abundance between 4 and 8 bar. We find a linear relationship between the cloud opacity and the continuum level of the spectrum. For a given radiance level of an individual spectrum, significant variations in the water vapor relative humidity are seen. However, no clear evidence for a relationship between the cloud opacity and the water relative humidity is seen. A cloud structure similar to that measured by the Galileo entry probe, with no significant cloud opacity below 2 bar, is adequate. The air in the hot spots is found to be overall dry, consistent with the probe measurements. None of the considered spectra show water vapor relative humidities exceeding 10%. Significant spatial variations of the water vapor relative humidity are found, and the distribution over the observed hot spot regions is complex. Because of a low sensitivity of the NIMS spectra to ammonia, uncertainties in the derived ammonia abundance are much higher than for water. There is, however, a possible trend in all the observed hot spots toward more ammonia inside than outside the hot spots at the sounded pressure levels.

Isotopic Ratios in Titan's Methane: Measurements and Modeling

The existence of methane in Titan’s atmosphere (∼ 6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20 Myr. In this paper, we examine the clues available from isotopic ratios ( 12 C/ 13 C and D/H) in Titan’s methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13 CH4, 12 CH3D, and 13 CH3D. From these we compute estimates of 12 C/ 13 C = 86.5 ± 8.2 and D/H = (1.59 ± 0.33) × 10 −4 , in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan’s methane: CH4 +C 2H → CH3 +C 2H2. Using these new measurements and predictions we proceed to model the time evolution of 12 C/ 13 C and D/H in Titan’s methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH4), we find that the present-day 12 C/ 13 C implies that the CH4 entered the atmosphere 60–1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently—most likely less than 10 Myr ago—if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

Retrieval of air temperature profiles in the Venusian mesosphere from VIRTIS-M data: Description and validation of algorithms

[1]xa0We present here methods developed for the retrieval of air temperature profiles in the Venusian mesosphere from the absolute radiances measured by the Visual and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the Venus Express satellite. The infrared M channel of the instrument acquires multispectral images between 1000 and 5000 nm. In nighttime measurements, radiance in the range 3800–5000 nm is dominated by the thermal emission and absorption by the clouds and carbon dioxide. Since the latter is the main atmospheric component, it is possible to exploit the strong variability of its opacity in this spectral range, as resolved by the instrument, to reconstruct the vertical air temperature profile as a function of pressure. In this context we decided to adopt the Twomey et al. (1977) relaxation scheme. The resulting code was extensively tested on a set of simulated VIRTIS-M data. Comparison of the known input conditions with the results of analysis code allowed us to evaluate the systematic and random errors affecting the retrievals procedures on a statistical basis. The code returns the vertical air temperature profile with an uncertainty of less than 1 K in the region between 70 and 7 mbar (66 and 77 km above the reference surface) and less than 4 K throughout the entire range 100–0.1 mbar (64–95 km). Finally, we present the first examples of the code applied to actual measured Venusian data, demonstrating its capability to achieve a satisfactory modeling of the observations and provide physically reasonable results.

Evidence for anomalous cloud particles at the poles of Venus

[1]xa0An analysis of near-infrared emissions on the nightside of Venus observed by the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) instrument on board Venus Express reveals anomalous cloud particles in the polar regions of Venus. These anomalous particles are found within the centers of polar vortices at both poles and are either larger or different in composition from those elsewhere in the planet. We find no persistent latitudinal variation in cloud properties at low to midlatitudes, nor do we find asymmetry between the southern and northern hemispheres. These findings arise from analysis of the relative brightness of 1.74 and 2.30 μm infrared radiation thermally emitted from the deep atmosphere of Venus. Larger cloud particles cause relatively more attenuation at 2.30 μm than at 1.74 μm, so we use a “size parameter,” m = (I1.74μm)/(I2.30μm)0.53, as a proxy for particle size. This methodology follows that of Carlson et al. (1993), supported by new radiative transfer modeling.

Calculated k distribution coefficients for hydrogen‐ and self‐broadened methane in the range 2000–9500 cm−1 from exponential sum fitting to band‐modelled spectra

The spectral band data derived by Strong et al. [1993] for laboratory-measured transmission spectra of hydrogen-broadened methane at 10 cm−1 resolution have been fitted with k coefficients over a wide range of pressures and temperatures representing those likely to be encountered in the atmosphere of Jupiter. The mean fitting error is found to be only 2.0 × 10−3 in transmission. These data are essential for the scattering calculations likely to be necessary for analysis of the data from the Near Infrared Mapping Spectrometer aboard the NASA Galileo spacecraft. The new data have significant advantages over those previously derived by Baines et al. [1993] in that they cover a wider spectral range, are applicable to longer paths, and also apply to the hydrogen-broadened case, which is the dominant broadening mechanism in this atmosphere. A similar table has also been calculated for the self-broadening case for comparison.

Titan's winter polar vortex structure revealed by chemical tracers

[1]xa0The winter polar vortex on Saturns largest moon Titan has profound effects on atmospheric circulation and chemistry and for the current northern midwinter season is the major dynamical feature of Titans stratosphere and mesosphere. We use 2 years of observations from Cassinis composite infrared spectrometer to determine cross sections of five independent chemical tracers (HCN, HC3N, C2H2, C3H4, and C4H2), which are then used to probe dynamical processes occurring within the vortex. Our results provide compelling evidence that the vortex acts as a strong mixing barrier in the stratosphere and mesosphere, effectively separating a tracer-enriched air mass in the north from air at lower latitudes. In the mesosphere, above the level of the vortex jet, a tracer-depleted zone extends away from the north pole toward the equator and enrichment is confined to high northern latitudes. However, below this level, mixing processes cause tongues of gas to extend away from the polar region toward the equator. These features are not reproduced by current general circulation models and suggest that a residual polar circulation is present and that waves and instabilities form a more important part of Titans atmospheric dynamics than previously thought. We also observe an unexpected enrichment of C4H2 in the northern stratosphere, which suggests photochemical polymerization of C2H2. Our observations provide stringent new constraints for dynamical and photochemical models and identify key polar processes for the first time. Some of the processes we see have analogues in Earths polar vortex, while others are unique to Titan.

Titan's prolific propane: The Cassini CIRS perspective

Abstract Although propane gas ( C 3 H 8 ) was first detected in the stratosphere of Titan by the Voyager IRIS infrared spectrometer in 1980, obtaining an accurate measurement of its abundance has proved difficult. All existing measurements have been made by modeling the ν 26 band at 748 cm - 1 : however, different analyzes over time have yielded quite different results, and it also suffers from confusion with the strong nearby ν 5 band of acetylene. In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30 ∘ S–30 ∘ N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new linelist for the range 1300–1400xa0 cm - 1 , along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376xa0 cm - 1 . At 748xa0 cm - 1 xa0we retrieve 4.2 ± 0.5 × 10 - 7 ( 1 - σ error) at 2xa0mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 ± 0.8 × 10 - 7 at 2xa0mbar from the 1376xa0 cm - 1 xa0band — a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperfect model of the ν 6 band of ethane. This study clearly shows for the first time the ubiquity of propanes emission bands across the thermal infrared spectrum of Titan, and points to an urgent need for further laboratory spectroscopy work, both to provide the line positions and intensities needed to model these bands, and also to further characterize haze spectral opacity. The present lack of accurate modeling capability for propane is an impediment not only for the measurement of propane itself, but also for the search for the emissions of new molecules in many spectral regions.