P. J. Moreira

Hybrid sol-gel channel waveguide patterning using photoinitiator-free materials

Fabrication of organic-inorganic sol-gel glass channel waveguides by ultraviolet (UV) photopolymerization of material synthesized from the precursor methacryloxypropyltrimethoxysilane is performed using a pulsed 248-nm excimer laser without the need of photoinitiators. The transmission spectra of channel waveguides are presented. Absorption bands are identified, revealing high loss (4-5 dB/cm) at 1.55 /spl mu/m mainly due to strong OH group content and an acceptable value of 0.4 dB/cm at 1.3 /spl mu/m. Heat treatment and UV irradiation showed similar effects on the transmission spectra of channel waveguides, revealing no loss improvement in the 1.55-/spl mu/m region.

Hybrid sol-gel planar optics for astronomy.

Hybrid sol-gel planar optics devices for astronomy are produced for the first time. This material system can operate from the visible (0.5 microm) up to the edge of astronomical J-band (1.4 microm). The design, fabrication and characterization results of a coaxial three beam combiner are given as an example. Fringe contrasts above 94% are obtained with a source with spectral bandwidth of 50 nm. These results demonstrate that hybrid sol-gel technology can produce devices with high quality, opening the possibility of rapid prototyping of new designs and concepts for astronomical applications.

Hybrid silica sol-gel symmetric buried channel waveguide on silicon

Symmetric buried channel waveguides fabricated on silicon substrates by the organic-inorganic hybrid sol-gel process are reported. The buffer/cladding layer material is composed of methyl-modified silanes and presents high network flexibility and low refractive index, at low cost. Film thickness above 10 mm is possible without cracks, even after thermally baking the films at 150°C, and the refractive index is 1.468 at 632.8 nm. The influence of the methylsiloxane species on the material absorption loss was investigated, in particular at 1.55 mm. For channel waveguide core definition, a photopatternable layer was polymerised by 248 nm laser radiation through an amplitude mask, and the unexposed material was simply removed by an organic solvent. The transmission spectrum of the waveguides is presented and reveals an acceptable loss level of 0.3dB/cm at 1300 nm, but larger loss in the 1550 nm region. The procedure developed is compatible with optoelectronic integration in silicon.

Performance of astronomical beam combiner prototypes fabricated by hybrid sol-gel technology.

Integrated optics coaxial two, three and four telescope beam combiners have been fabricated by hybrid sol-gel technology for astronomical applications. Temporal and spectral analyses of the output interferometric signal have been performed, and their results are in mutual good agreement. The results of the characterization method employed are cross-checked using contrast measurements obtained independently, demonstrating that the chromatic differential dispersion is the main contributer to contrast reduction. The mean visibility of the fabricated devices is always higher than 95 %, obtained using a source with spectral bandwidth of 50 nm. These results show the capability of hybrid sol-gel technology for fast prototyping of complex chip designs used in astronomical applications.

Fabrication and test of an integrated optical sensor with high sensitivity and high dynamic range based on a Mach-Zehnder interferometric configuration

Integrated optics (IO) technology has been primarily used in optical communication applications but it is expanding fast into the field of optical sensing. In this work we report the fabrication of integrated devices using hybrid sol-gel technology and in particular its application in the fabrication of a refractive index integrated sensor based in a Mach-Zehnder interferometric configuration. In one of the interferometer arms, a analysis chamber is created by exposing the waveguide through the removal of the device cladding. On the same arm, two Bragg gratings with the same period are fabricated: one in the unprotected waveguide area and another in close proximity (cladded area); because of the different effective index in the two grating regions, two peaks are observed in reflection if the device is tested with a broadband source. Any change of the refractive index of the material filling the analysis chamber can be detected in two ways: by measuring the intensity of the interferometric output (at a wavelength different from the Bragg wavelength of the two gratings) or by measuring the spectrum of the reflected signal. The high sensitivity is obtained by measuring the interferometric output, while the high dynamic range can be achieved by measuring the reflected signal from the grating structures.

Advanced hybrid sol-gel material processing for higher transparency at 1.5 μm

The hybrid sol-gel process is recognized to be an alternative route for production of low cost silica-based integrated optic devices, since it allows the elaboration of ridge waveguides without recourse to high cost processing, like ion etching. However, the high absorption of these materials in the NIR region (1300 and 1550 nm) has limited so far their use. The main objective of this article is to describe the major factors that lead to high losses in the final material and to give solutions to overcome this drawback. The choice of hybrid precursors and the influence of the experimental conditions of gel preparation are of paramount importance. Appropriate synthesis conditions allow a significant decrease of the gel losses (to 0,5 dB/cm) while keeping good wetability and UV-patternability. Each step of the waveguides elaboration was studied separately (UV-irradiation, etching, overcladding, storage) regarding the losses of the material. Post-baking of the waveguides is a way to significantly decrease the losses at 1550 nm. Under appropriate conditions, the losses measured in the waveguides can be kept below 1 dB/cm.

Rapid prototyping of integrated sol-gel devices for astronomical interferometry

Integrated optics is a mature technology with standard applications to telecommunications. Since the pioneering work of Berger et al. 1999 beam combiners for optical interferometry have been built using this technology. Classical integrated optics device production is very expensive and time consuming. The rapid production of devices using hybrid sol-gel materials in conjunction with UV laser direct writing techniques allows overcoming these limitations. In this paper this technology is tested for astronomical applications. We report on the design, fabrication and characterization of multiaxial two beam combiners and a coaxial beam combiner for astronomical interferometry. Different multiaxial two beam combiner designs were tested and high contrast (better than 90%) was obtained with a 1.3 μm laser diode and with an SLD ( λ0 = 1.26 μm, FWHM of 60 nm). High contrast fringes were produced with 1.3 μm laser diode using the coaxial two beam combiner. These results show that hybrid sol-gel techniques produce devices with high quality, allowing the rapid prototyping of new designs and concepts for astronomy.

Photosensitive Materials for Integrated Optic Applications

Abstract This article presents results of device fabrication using UV processing of materials and integrated optic components produced by flame hydrolysis deposition and hybrid sol-gel technology. Photosensitive materials were employed in the fabrication of channel waveguides and channel photo-imprinted waveguides incorporating Bragg gratings through single and double-step exposure.

Sol-gel hybrid channel waveguide fabrication using UV excimer laser patterning

Definition of channel waveguides on hybrid sol-gel material was demonstrated using a 248 nm UV excimer laser, without mixing organic photoinitiators in the solution preparation step. Thin films fabricated by hydrolysis and polycondensation of methacryloxypropyltrimethoxysilane (MAPTMS) doped with zirconium oxide were deposited by spin-coating on soda-lime glass substrates (n = 1.514). Channel waveguides were defined by microlithography and then covered by a protective layer composed of a combination of MAPTMS and tetramethoxysilane (TMOS). Finally, after cutting and polishing, the waveguides were optically characterized.