P.O. Ribeiro

Theoretical investigation on the magnetocaloric effect in amorphous systems, application to: Gd80Au20 and Gd70Ni30

The temperature dependence of the magnetocaloric effect in Gd80Au20 and Gd70Ni30 amorphous alloys were investigated, using the Handrich-Kobe model with a modified Brillouin function that takes an additional exchange fluctuation term. The exchange fluctuation parameters were determined to give better fits to magnetic entropy changes and adiabatic temperature changes. The magnetic entropy changes of 2.20 Jmol−1K−1 and 1.50 Jmol−1K−1 and the refrigerant capacity values of 135 Jmol−1 (ΔB=5 T) and 146 Jmol−1 (ΔB=7 T) are obtained for Gd80Au20 and Gd70Ni30, respectively. In addition, the influence of phase changes between crystalline and amorphous states on the isothermal entropy change was investigated.

Calculations of the magnetic entropy change in amorphous through a microscopic anisotropic model: Applications to Dy70Zr30 and DyCo3.4 alloys

We report theoretical investigations on the magnetocaloric effect, described by the magnetic entropy change in rare earth—transition metal amorphous systems. The model includes the local anisotropy on the rare earth ions in Harris-Plischke-Zuckermann assumptions. The transition metals ions are treated in terms of itinerant electron ferromagnetism and the magnetic moment of rare earth ions is coupled to the polarized d-band by a local exchange interaction. The magnetocaloric effect was calculated in DyCo3.4 system, which presents amorphous sperimagnetic configuration. The calculations predict higher refrigerant capacity in the amorphous DyCo3.4 than in DyCo2 crystal, highlighting the importance of amorphous magnetocaloric materials. Our calculation of the magnetocaloric effect in Dy70Zr30, which presents amorphous asperomagnetic configuration, is in good agreement with the experimental result. Furthermore, magnetic entropy changes associated with crystal-amorphous configurations change are estimated.

Spin reorientation and the magnetocaloric effect in HoyEr(1−y)N

We report on the magnetic and magnetocaloric effect calculations in rare earth mononitrides HoyEr(1−y)N (y = 0, 0.5, 0.75, and 1). The magnetic Hamiltonian includes the crystalline electrical field in both magnetic sublattices; disorder in exchange interactions among Ho-Ho, Er-Er, and Ho-Er magnetic ions and the Zeeman effect. The theoretical results for the magnetic entropy change and adiabatic temperature change are in good agreement with the available experimental data. Besides, ferrimagnetic arrangement, inverse magnetocaloric effect, and spin reorientation transition (spin flop process) were predicted and quantitatively described.

Electric field triggering the spin reorientation and controlling the absorption and release of heat in the induced multiferroic compound EuTiO3

We report remarkable results due to the coupling between the magnetization and the electric field induced polarization in EuTiO3. Using a microscopic model Hamiltonian to describe the three coupled sublattices, Eu-(spin-up), Eu-(spin-down), and Ti-(moment), the spin flop and spin reorientation phase transitions were described with and without the electric-magnetic coupling interaction. The external electric field can be used to tune the temperature of the spin reorientation phase transition TSR = TSR(E). When the TSR is tuned around the EuTiO3—Neel temperature (TN = 5.5 K), an outstanding effect emerges in which EuTiO3 releases heat under magnetic field change. The electric field controlling the spin reorientation transition and the endo-exothermic processes are discussed through the microscopic interactions model parameters.

Theoretical investigation on the barocaloric and magnetocaloric properties in the Gd5Si2Ge2 compound

We report a theoretical microscopic model to discuss the barocaloric and magnetocaloric effects in the Gd5Si2Ge2 compound based on the recent experimental data by Yuce et al. [Appl. Phys. Lett. 101, 071906 (2012)]. For this purpose, our model Hamiltonian includes three interactions: Zeeman, magnetoelastic, and exchange interactions, considering the magnetic field dependence of phonons entropy. Using this model, the combined magnetocaloric and barocaloric effects were calculated in Gd5Si2Ge2 compound showing satisfactory agreement with the experimental data. Besides, a high entropy change was predicted for simultaneous changes in the applied magnetic field and pressure (the combined magnetocaloric and barocaloric effects).

Theoretical investigation on the magnetic and electric properties in TbSb compound through an anisotropic microscopic model

We report the strong correlations between the magnetoresistivity and the magnetic entropy change in the cubic antiferromagnetic TbSb compound. The theoretical investigation was performed through a microscopic model which takes into account the crystalline electrical field anisotropy, exchange coupling interactions between the up and down magnetic sublattices, and the Zeeman interaction. The easy magnetization directions changes from ⟨001⟩ to ⟨110⟩ and then to ⟨111⟩ observed experimentally was successfully theoretically described. Also, the calculation of the temperature dependence of electric resistivity showed good agreement with the experimental data. Theoretical predictions were calculated for the temperature dependence of the magnetic entropy and resistivity changes upon magnetic field variation. Besides, the difference in the spin up and down sublattices resistivity was investigated.