Paola Zuppella

Extreme ultraviolet multilayer for the FERMI@Elettra free electron laser beam transport system

In this work we present the design of a Pd/B₄C multilayer structure optimized for high reflectance at 6.67 nm. The structure has been deposited and also characterized along one year in order to investigate its temporal stability. This coating has been developed for the beam transport system of FERMI@Elettra Free Electron Laser: the use of an additional aperiodic capping layer on top of the structure combines the high reflectance with filter properties useful in rejecting the fundamental harmonic when the goal is to select the third FEL harmonic.

Stability of extreme ultraviolet multilayer coatings to low energy proton bombardment

In this work we present results of an new experiment related to low energy protons bombardments on nano-structured optical coatings. Multilayer structures protected by different capping layers have been fabricated and exposed to low energy protons (1 keV). The experimental parameters have been selected considering the potential application of the coatings to solar mission instrumentation. Future solar missions will investigate the Sun from very close distances and optical components are constantly exposed to low energy ion particles irradiation. The experiment was repeated fixing the proton flux while varying the total dose accumulated. Results show that physical processes occurred at the uppermost interfaces can strongly damage the structure.

Graphene–noble metal bilayers for inverted surface plasmon resonance biosensors

Inverted surface plasmon resonance (ISPR) biosensors based on absorbent metal thin films with a graphene sheet on top are presented. Two systems have been examined by means of a numerical study, a bilayer of palladium/graphene and one of iridium/graphene. The features and performances of such biosensors are discussed. The proposed ISPR systems potentially disclose new strategies for high-resolution, sensitive and straightforward detection of multiple biomolecular interactions.

Capped Mo/Si multilayers with improved performance at 30.4 nm for future solar missions

Novel capping layer structures have been deposited on periodic Mo/Si multilayers to optimize reflectance at 30.4 nm. Design, deposition and characterization of such coatings are presented. Most of the structures proposed show improved performance with respect to standard Mo/Si multilayers and are stable over time. Reflectance at 121.6 nm and in the visible spectral range have been also tested to explore the applicability of such coatings to the Multi Element Telescope for Imaging and Spectroscopy (METIS) instrument, a coronagraph being developed for the ESA Solar Orbiter platform.

Functional palladium metal films for plasmonic devices: an experimental proof

Palladium-based, Inverted surface plasmon resonance substrates with functional surfaces are presented and characterized. The advantages of the use of palladium in lieu of other metals (most notably gold) are discussed and assayed experimentally. We demonstrate how the bare metal films can be functionalized by thiol chemistry or by adsorption of functional graphene sheets and how the features of the surfaces affect the performance of the substrate.

Iridium/silicon multilayers for extreme ultraviolet applications in the 20-35 nm wavelength range.

We have developed an Ir/Si multilayer for extreme ultraviolet (EUV) applications. Normal incidence reflectance measurements of a prototype film tuned to 30 nm wavelength show superior performance relative to a conventional Mo/Si multilayer structure; we also find good stability over time. Transmission electron microscopy and electron dispersive x-ray spectroscopy have been used to examine the microstructure and interface properties of this system: we find amorphous Si layers and polycrystalline Ir layers, with asymmetric interlayer regions of mixed composition. Potential applications of Ir/Si multilayers include instrumentation for solar physics and laboratory EUV beam manipulation.

Stability of EUV multilayer coatings to low energy alpha particles bombardment

Future solar missions will investigate the Sun from very close distances and optical components are constantly exposed to low energy ions irradiation. In this work we present the results of a new experiment related to low energy alpha particles bombardments on Mo/Si multilayer optical coatings. Different multilayer samples, with and without a protecting capping layer, have been exposed to low energy alpha particles (4keV), fixing the ions fluency and varying the time of exposure in order to change the total dose accumulated. The experimental parameters have been selected considering the potential application of the coatings to future solar missions. Results show that the physical processes occurred at the uppermost interfaces can strongly damage the structure.

Effects of helium ion bombardment on metallic gold and iridium thin films

Single layer mirrors have been prepared by evaporating gold and iridium on silicon substrates. The samples have been exposed to 4 keV He + ion flux at different total fluences, simulating the effect of solar wind ions on optical coatings. We show that the ion implantation significantly affects the optical characteristics of the metallic films. The phenomena are explained and modeled also considering the related material modifications observed with chemical and morphological analysis.

Palladium on plastic substrates for plasmonic devices.

Innovative chips based on palladium thin films deposited on plastic substrates have been tested in the Kretschmann surface plasmon resonance (SPR) configuration. The new chips combine the advantages of a plastic support that is interesting and commercially appealing and the physical properties of palladium, showing inverted surface plasmon resonance (ISPR). The detection of DNA chains has been selected as the target of the experiment, since it can be applied to several medical early diagnostic tools, such as different biomarkers of cancers or cystic fibrosis. The results are encouraging for the use of palladium in SPR-based sensors of interest for both the advancement of biodevices and the development of hydrogen sensors.

SPR Sensor Platform Based on a Novel Metal Bilayer Applied on D–Shaped Plastic Optical Fibers for Refractive Index Measurements in the Range 1.38–1.42

A surface plasmon resonance sensor based on a D-shaped plastic optical fiber and a palladium/gold (Pd/Au) bilayer was designed, implemented, and characterized. The platform was properly thought to work in the 1.38-1.42 refractive index range, where it exhibits excellent performances. This refractive index range is very important when a thin polymer layer is used on the planar metal surface for bio-chemical sensing applications.