Paolo Ballato

Accommodation of transpressional strain in the Arabia‐Eurasia collision zone: new constraints from (U‐Th)/He thermochronology in the Alborz mountains, north Iran

The Alborz range of N Iran provides key information on the spatiotemporal evolution and characteristics of the Arabia-Eurasia continental collision zone. The southwestern Alborz range constitutes a transpressional duplex, which accommodates oblique shortening between Central Iran and the South Caspian Basin. The duplex comprises NW-striking frontal ramps that are kinematically linked to inherited E-W-striking, right-stepping lateral to obliquely oriented ramps. New zircon and apatite (U-Th)/He data provide a high-resolution framework to unravel the evolution of collisional tectonics in this region. Our data record two pulses of fast cooling associated with SW-directed thrusting across the frontal ramps at ~ 18–14 and 9.5-7.5 Ma, resulting in the tectonic repetition of a fossil zircon partial retention zone and a cooling pattern with a half U-shaped geometry. Uniform cooling ages of ~ 7–6 Ma along the southernmost E-W striking oblique ramp and across its associated NW-striking frontal ramps suggests that the ramp was reactivated as a master throughgoing, N-dipping thrust. We interpret this major change in fault kinematics and deformation style to be related to a change in the shortening direction from NE to N/NNE. The reduction in the obliquity of thrusting may indicate the termination of strike-slip faulting (and possibly thrusting) across the Iranian Plateau, which could have been triggered by an increase in elevation. Furthermore, we suggest that ~ 7-6-m.y.-old S-directed thrusting predated inception of the westward motion of the South Caspian Basin.

Tectonic magnetic lineation and oroclinal bending of the Alborz range: Implications on the Iran‐Southern Caspian geodynamics

In this study we use the anisotropy of magnetic susceptibility (AMS) and paleomagnetic data for deciphering the origin of magnetic lineation in weakly deformed sedimentary rocks and for evaluating oroclinal processes within the Arabia-Eurasia collision zone. In particular, we have analyzed the Miocene Upper Red Formation (URF) from the outer curved front of the southern Central Alborz Mountains of north Iran, to test for the first time with paleomagnetic data the origin (primary versus secondary) of this orogenic arc. AMS data document the existence of a magnetic lineation parallel to the orientation of the major tectonic structures, which vary along strike from WNW to ENE. These directions are highly oblique to the paleoflow directions and hence suggest that the magnetic lineation in the URF was produced by compressional deformation during layer-parallel shortening. In addition, our paleomagnetic data document clockwise and anticlockwise rotations along vertical axis for the western and eastern sectors of the Central Alborz Mountains, respectively. Combined, our results suggest that the orogen represents an orocline, which formed not earlier than circa 7.6 Ma most likely through bending processes caused by the relative motion between the rigid crustal blocks of the collision zone. Moreover, our study provides new insights into the Iran-Southern Caspian Basin kinematic evolution suggesting that the present-day SW motion of the South Caspian Basin with respect to Central Iran postdates oroclinal bending and hence cannot be as old as late Miocene to early Pliocene but a rather recent configuration (i.e., 3 to <1 Ma).

The Paleocene–Eocene thermal maximum (PETM) in shallow-marine successions of the Adriatic carbonate platform (SW Slovenia)

The Paleocene-Eocene thermal maximum represents one of the most rapid and extreme warming events in the Cenozoic. Shallow-water stratigraphic sections from the Adriatic carbonate platform offer a rare opportunity to learn about the nature of Paleocene-Eocene thermal maximum and the effects on shallow-water ecosystems. We use carbon and oxygen isotope stratigraphy, in conjunction with detailed larger benthic foraminiferal biostratigraphy, to establish a high-resolution paleoclimatic record for the Paleocene-Eocene thermal maximum. A prominent negative excursion in δ 13 C curves of bulk-rock (∼1‰–3‰), matrix (∼4‰), and foraminifera (∼6‰) is interpreted as the carbon isotope excursion during the Paleocene-Eocene thermal maximum. The strongly 13 C-depleted δ 13 C record of our shallow-marine carbonates compared to open-marine records could result from organic matter oxidation, suggesting intensified weathering, runoff, and organic matter flux. The Ilerdian larger benthic foraminiferal turnover is documented in detail based on high-resolution correlation with the carbon isotopic excursion. The turnover is described as a two-step process, with the first step (early Ilerdian) marked by a rapid diversification of small alveolinids and nummulitids with weak adult dimorphism, possibly as adaptations to fluctuating Paleocene-Eocene thermal maximum nutrient levels, and a second step (middle Ilerdian) characterized by a further specific diversification, increase of shell size, and well-developed adult dimorphism. Within an evolutionary scheme controlled by long-term biological processes, we argue that high seawater temperatures could have stimulated the early Ilerdian rapid specific diversification. Together, these data help elucidate the effects of global warming and associated feedbacks in shallow-water ecosystems, and by inference, could serve as an assessment analog for future changes.

Intracontinental subduction beneath the Pamir Mountains: Constraints from thermokinematic modeling of shortening in the Tajik fold-and-thrust belt

American Philosophical Society; American Association of Petroleum Geologists; Geological Society of America; Exxon Mobil Corporation

Mineralogical study of historical bricks from the Great Palace of the Byzantine Emperors in Istanbul based on powder X-ray diffraction data

This study concerns the Quantitative Phase Analysis (QPA) of historical bricks coming from the complex of the Great Palace of the Byzantine Emperors in Istanbul. The studied samples are characterised by different chemical compositions (low and high calcium content), variable firing temperatures and different amounts of soluble salts as damage products. In the low-Ca samples, the decrease of the phyllosilicate content (from 23.4 to 6.9 wt%) is associated to the increase of the amorphous fraction (from 24 to 48%). This clear negative correlation between the phyllosilicate content and the amorphous fraction indicates that in low-Ca systems vitrification processes are overwhelming with respect to nucleation and recrystallisation processes. By contrast, high-Ca samples present newly formed Ca(Mg) silicates (diopside from 5.7 to 27.2%; anorthite from 1.4 to 8.7%) and aluminium silicates (gehlenite only in two samples, 6.2 and 7.7%) associated to the decrease of quartz (from 27.7 to 11.5%), phyllosilicate (from 6.5% until complete break down) and amorphous (from 30 to 14%) phase fractions. These findings support the role played by the CaO(MgO) content deriving from carbonates decomposition which reacts with Al2O3 and SiO2 oxides from dehydroxylated clay minerals and quartz grains. The above results have been obtained by X-ray powder diffraction data using the combined Rietveld refinement - internal standard method in order to estimate both the crystalline and the amorphous phase fractions. In addition, the coexistence of two distinct plagioclases in high-Ca samples was modelled as follows: a primary albite, which tends to incorporate Ca during the firing process as demonstrated by the increasing of gamma crystallographic angle, and a newly formed anorthite. Finally, by difference between the X-ray fluorescence data and the chemical compositions inferred by QPA, it proved possible to roughly estimate the residual chemical composition attributable to the amorphous fraction. On the basis of our data, we believe that Rietveld refinement combined with the internal standard method represent a powerful tool to better characterise complex polycrystalline and amorphous mixture as in the case of historical bricks

Multiple Exhumation Phases in the Central Pontides (N Turkey): New Temporal Constraints on Major Geodynamic Changes Associated With the Closure of the Neo‐Tethys Ocean

The Central Pontides of N Turkey represents a mobile orogenic belt of the southern Eurasian margin that experienced several phases of exhumation associated with the consumption of different branches of the Neo-Tethys Ocean and the amalgamation of continental domains. Our new low-temperature thermochronology data help to constrain the timing of these episodes, providing new insights into associated geodynamic processes. In particular, our data suggest that exhumation occurred at (1) ~110 to 90 Ma, most likely during tectonic accretion and exhumation of metamorphic rocks from the subduction zone; (2) from ~60 to 40 Ma, during the collision of the Kirşehir and Anatolide-Tauride microcontinental domains with the Eurasian margin; (3) from ~40 to 25 Ma, either during the early stages of the Arabia-Eurasia collision (soft collision) when the Arabian passive margin reached the trench, implying 70 to 530 km of subduction of the Arabian passive margin, or during a phase of trench advance predating hard collision at ~20 Ma; and (4) ~11 Ma to the present, during transpression associated with the westward motion of Anatolia. Our findings document the punctuated nature of fault-related exhumation, with episodes of fast cooling followed by periods of slow cooling or subsidence, the role of inverted normal faults in controlling the Paleogene exhumation pattern, and of the North Anatolian Fault in dictating the most recent pattern of exhumation.