Paramasivam Balasubramanian

A new electrochemical sensor for highly sensitive and selective detection of nitrite in food samples based on sonochemical synthesized Calcium Ferrite (CaFe 2 O 4 ) clusters modified screen printed carbon electrode

Herein, we report a novel, disposable electrochemical sensor for the detection of nitrite ions in food samples based on the sonochemical synthesized orthorhombic CaFe2O4 (CFO) clusters modified screen printed electrode. As synthesized CFO clusters were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transformer infrared spectroscopy (FT-IR), Thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and amperometry (i-t). Under optimal condition, the CFO modified electrode displayed a rapid current response to nitrite, a linear response range from 0.016 to 1921 µM associated with a low detection limit 6.6 nM. The suggested sensor also showed the excellent sensitivity of 3.712 μA μM-1 cm-2. Furthermore, a good reproducibility, long-term stability and excellent selectivity were also attained on the proposed sensor. In addition, the practical applicability of the sensor was investigated via meat samples, tap water and drinking water, and showed desirable recovery rate, representing its possibilities for practical application.

Sonochemical synthesis of molybdenum oxide (MoO3) microspheres anchored graphitic carbon nitride (g-C3N4) ultrathin sheets for enhanced electrochemical sensing of Furazolidone

Present strategy introduce the sonochemical synthesis of molybdenum oxide (MoO3) microspheres anchored graphitic carbon nitride (g-C3N4) ultrathin sheets as a novel electrocatalyst for the detection of Furazolidone (FU). TEM results revealed that MoO3 are microspheres with an average size of 2 µM and the g-C3N4 seems like ultrathin sheets. Owing to their peculiar morphological structure, g-C3N4/MoO3 composite modified electrode provided an enriched electroactive surface area (0.3788 cm2) and higher heterogeneous electron transfer kinetics (K°eff = 4.91×10-2 cm s-1) than the other controlled electrodes. It is obviously observed from the voltammetric studies that the proposed sensor based on g-C3N4/MoO3 composite can significantly improve the electrocatalytic efficiency towards the sensing of FU. Due to the excellent synergic effect of g-C3N4/MoO3 composite, can detect the ultra-level FU with a limit of detection of 1.4 nM and a broad dynamic range of 0.01-228 µM, which surpassed the many previously reported FU sensors. Hence, the proposed sensor was successfully applied to sensing the FU in human blood serum, urine and pharmaceutical samples, gained an agreeable recoveries.

Simplistic synthesis of ultrafine CoMnO3 nanosheets: An excellent electrocatalyst for highly sensitive detection of toxic 4-nitrophenol in environmental water samples

Design and fabrication of cost effective analytical tools to monitor toxic organic emissions in eco system is of a great necessity. Nitrophenols are a class of widespread toxic organic pollutant lead to serious adverse effects in biosphere on its consumption. This article reports a high sensitive, cost effective, robust electrochemical sensor for 4-nitrophenol (4-NP) in environmental water samples. A novel sheet like CoMnO3 (CMO Ns) nanocatalyst was synthesized via oxalic acid assisted co-precipitation technique and employed as electrocatalyst for the high sensitive detection of 4-NP. The physiochemical properties of CMO Ns are studied in detail via XRD, FTIR, TEM, TGA, and XPS. TEM results reviled the protocol is an excellent way for synthesis of a uniformly distributed CMO Ns with lathery surface. Evident to the surface and other physiochemical studies the CMO Ns based sensor holds superior electrocatalytic activity towards 4-NP detection with excellent sensitivity (2.458 μA μM-1 cm-2) coupled with nanomolar detection (10 nm) limits. Moreover, the constructed sensor holds reliable long-term durability, good reproducibility, and excellent working stability. The practical applicability of the developed sensor was evaluated by determination of 4-NP in samples acquired from water resources with RSD ± 3.3%.