Patrick Georges

On thermal effects in solid-state lasers: The case of ytterbium-doped materials

Abstract A review of theoretical and experimental studies of thermal effects in solid-state lasers is presented, with a special focus on diode-pumped ytterbium-doped materials. A large part of this review provides however general information applicable to any kind of solid-state laser. Our aim here is not to make a list of the techniques that have been used to minimize thermal effects, but instead to give an overview of the theoretical aspects underneath, and give a state-of-the-art of the tools at the disposal of the laser scientist to measure thermal effects. After a presentation of some general properties of Yb-doped materials ( Section 1 ), we address the issue of evaluating the temperature map in Yb-doped laser crystals, both theoretically and experimentally ( Section 2 ). This is the first step before studying the complex problem of thermal lensing ( Section 3 ). We will focus on some newly discussed aspects, like the definition of the thermo-optic coefficient: we will highlight some misleading interpretations of thermal lensing experiments due to the use of the dn/dT parameter in a context where it is not relevant. Section 4 will be devoted to a state-of-the-art of experimental techniques used to measure thermal lensing. Eventually, in Section 5 , we will give some concrete examples in Yb-doped materials, where their peculiarities will be pointed out.

Detection of Single Photoluminescent Diamond Nanoparticles in Cells and Study of the Internalization Pathway

Diamond nanoparticles are promising photoluminescent probes for tracking intracellular processes, due to embedded, perfectly photostable color centers. In this work, the spontaneous internalization of such nanoparticles (diameter 25 nm) in HeLa cancer cells is investigated by confocal microscopy and time-resolved techniques. Nanoparticles are observed inside the cell cytoplasm at the single-particle and single-color-center level, assessed by time-correlation intensity measurements. Improvement of the nanoparticle signal-to-noise ratio inside the cell is achieved using a pulsed-excitation laser and time-resolved detection taking advantage of the long radiative lifetime of the color-center excited state as compared to cell autofluorescence. The internalization pathways are also investigated, with endosomal marking and colocalization analyses. The low colocalization ratio observed proves that nanodiamonds are not trapped in endosomes, a promising result in prospect of drug delivery by these nanoparticles. Low cytotoxicity of these nanoparticles in this cell line is also shown.

47-fs diode-pumped Yb 3+ :CaGdAlO 4 laser

The experimental demonstration of a diode-pumped passively mode-locked femtosecond laser based on an Yb3+:CaGdAlO4 single crystal is reported. The oscillator is directly diode pumped by a high-brightness 5 W fiber coupled laser diode, and pulses are produced by use of a semiconductor saturable-absorber mirror. It permits the production of pulses as short as 47 fs at 1050 nm, which are to our knowledge the shortest laser pulses obtained from an oscillator based on Yb3+-doped bulk materials. The average power is 38 mW, and the repetition rate is 109 MHz.

Diode-pumped Yb:Sr(3)Y(BO(3))(3) femtosecond laser.

We have developed a diode-pumped Yb(3+)Sr(3)Y(BO(3))(3) (Yb:BOYS) laser generating 69-fs pulses, at a central wavelength of 1062 nm. This laser is mode locked by use of a semiconductor saturable-absorber mirror and emits 80 mW of average power at 113 MHz. This is, to our knowledge, the first mode-locked Yb:BOYS laser and the shortest duration obtained from an ytterbium laser with a crystalline host. The central wavelength can be tuned from 1051 to 1070 nm, for sub-100-fs pulses. We have also achieved an average power as high as 300 mW with pulse duration of 86 fs at 1068 nm.

High power diode-pumped Yb3+:CaF2 femtosecond laser

We report what is believed to be the first demonstration of a high-power passively mode-locked diode-pumped femtosecond laser based on an Yb3+:CaF2 single crystal, directly pumped by a 15-W fiber-coupled laser diode. With a 5-at. % Yb3+ -doped sample and prisms for dispersion compensation we obtained pulses as short as 150 fs, with 880 mW of average power and up to 1.4-W average output power, with a pulse duration of 220 fs, centered at 1049 nm. The laser wavelength could be tuned from 1040 to 1053 nm in the femtosecond regime. Using chirped mirrors for dispersion compensation, the oscillator provided up to 1.74 W of average power, with a pulse duration of 230 fs, corresponding to a pulse energy of 20 nJ and a peak power of 85 kW.

Diode-pumped Yb:GGG laser: comparison with Yb:YAG

Abstract A diode-pumped ytterbium-doped Gd 3 Ga 5 O 12 (Yb:GGG) laser is reported for the first time. We report up to 4.2 W of CW laser power when pumping on the 971 nm absorption band with a 14 W fiber-coupled diode. The easy growth and the high thermal conductivity of Yb:GGG make it a challenger of Yb:YAG for high power applications. The efficiencies of these two crystals have been compared under the same pumping conditions, and turn out to be comparable.

Perylene- and pyrromethene-doped xerogel for a pulsed laser

Hydrophobic photostable dye molecules such as perylenes or pyrromethenes were trapped in xerogel matrices. Using these new materials as solid-state dye lasers, we have demonstrated efficient laser operation. Slope efficiencies of up to 30% were obtained in the millijoule output-energy range. Tunabilities of up to 60 nm were observed, and more than 150,000 pulses were emitted by the same spot of a given sample when the laser was pumped at millijoule energy levels.

Single-shot measurement of a 52-fs pulse

We demonstrate the possibility of a 52-fs pulse single-shot measurement by using the spatial analysis of the second harmonic beam produced in an optical autocorrelator. We show that this method gives means of optimizing low repetition rate femtosecond amplifiers.

Toward millions of laser pulses with pyrromethene- and perylene-doped xerogels

Significant improvements have been obtained for solid-state dye lasers with doped xerogels. By using longitudinal pumping with a frequency-doubled Q-switched Nd: YAG laser, we obtained as much as 86% slope efficiency and 5 x 10(5) pulses lifetime. Furthermore, newly prepared deoxygenated samples exhibited even greater lifetimes.

Generation of 90-fs pulses from a mode-locked diode-pumped Yb 3+ :Ca 4 GdO(BO 3 ) 3 laser

A diode-pumped Yb>(3+):Ca(4)GdO(BO>(3))(3) (Yb:GdCOB) laser generating 90-fs pulses at a center wavelength of 1045 nm is demonstrated. This is, to our knowledge, the shortest pulse duration obtained from an ytterbium laser with a crystalline host. This laser is mode locked with a high-finesse semiconductor saturable-absorber mirror and emits 40 mW of average power at a repetition rate of 100 MHz.