Patrick Kung

Design and analysis of perfect terahertz metamaterial absorber by a novel dynamic circuit model

Metamaterial terahertz absorbers composed of a frequency selective layer followed by a spacer and a metallic backplane have recently attracted great attention as a device to detect terahertz radiation. In this work, we present a quasistatic dynamic circuit model that can decently describe operational principle of metamaterial terahertz absorbers based on interference theory of reflected waves. The model comprises two series LC resonance components, one for resonance in frequency selective surface (FSS) and another for resonance inside the spacer. Absorption frequency is dominantly determined by the LC of FSS while the spacer LC changes slightly the magnitude and frequency of absorption. This model fits perfectly for both simulated and experimental data. By using this model, we study our designed absorber and we analyze the effect of changing in spacer thickness and metal conductivity on absorption spectrum.

Equivalent-Circuit Interpretation of the Polarization Insensitive Performance of THz Metamaterial Absorbers

Polarization insensitive metamaterial perfect absorbers were investigated through finite element numerical method and a new equivalent-circuit electric model was proposed to interpret this polarization insensitivity. The devices were fabricated to validate the model and experimental measurements were shown to be in good agreement with the simulated results. This absorber device is suitable for future use in THz sensing and detection applications.

Plasmon-Induced Transparency by Hybridizing Concentric-Twisted Double Split Ring Resonators

As a classical analogue of electromagnetically induced transparency, plasmon induced transparency (PIT) has attracted great attention by mitigating otherwise cumbersome experimental implementation constraints. Here, through theoretical design, simulation and experimental validation, we present a novel approach to achieve and control PIT by hybridizing two double split ring resonators (DSRRs) on flexible polyimide substrates. In the design, the large rings in the DSRRs are stationary and mirror images of each other, while the small SRRs rotate about their center axes. Counter-directional rotation (twisting) of the small SRRs is shown to lead to resonance shifts, while co-directional rotation results in splitting of the lower frequency resonance and emergence of a PIT window. We develop an equivalent circuit model and introduce a mutual inductance parameter M whose sign is shown to characterize the existence or absence of PIT response from the structure. This model attempts to provide a quantitative measure of the physical mechanisms underlying the observed PIT phenomenon. As such, our findings can support the design of several applications such as optical buffers, delay lines, and ultra-sensitive sensors.

A Facile Electrochemical Reduction Method for Improving Photocatalytic Performance of α-Fe2O3 Photoanode for Solar Water Splitting

Electrochemical reduction method is used for the first time to significantly improve the photo-electrochemical performance of α-Fe2O3 photoanode prepared on fluorine-doped tin oxide substrates by spin-coating aqueous solution of Fe(NO3)3 followed by thermal annealing in air. Photocurrent density of α-Fe2O3 thin film photoanode can be enhanced 25 times by partially reducing the oxide film to form more conductive Fe3O4 (magnetite). Fe3O4 helps facilitate efficient charge transport and collection from the top α-Fe2O3 layer upon light absorption and charge separation to yield enhanced photocurrent density. The optimal enhancement can be obtained for <50 nm films because of the short charge transport distance for the α-Fe2O3 layer. Thick α-Fe2O3 films require more charge and overpotential than thinner films to achieve limited enhancement because of the sluggish charge transport over a longer distance to oxidize water. Electrochemical reduction of α-Fe2O3 in unbuffered pH-neutral solution yields much higher but unstable photocurrent enhancement because of the increase in local pH value accompanied by proton reduction at a hematite surface.

Impact of Substrate and Bright Resonances on Group Velocity in Metamaterial without Dark Resonator

Manipulating the speed of light has never been more exciting since electromagnetic induced transparency and its classical analogs led to slow light. Here, we report the manipulation of light group velocity in a terahertz metamaterial without needing a dark resonator, but utilizing instead two concentric split-ring bright resonators (meta-atoms) exhibiting a bright Fano resonance in close vicinity of a bright Lorentzian resonance to create a narrowband transmittance. Unlike earlier reports, the bright Fano resonance does not stem from an asymmetry of meta-atoms or an interaction between them. Additionally, we develop a method to determine the metamaterial “effective thickness”, which quantifies the influence of the substrate on the metamaterial response and has remained challenging to estimate so far. By doing so, very good agreement between simulated and measured group delays and velocities is accomplished. The proposed structure and method will be useful in designing optical buffers, delay lines, and ultra-sensitive sensors.

Surface optical phonons in GaAs nanowires grown by Ga-assisted chemical beam epitaxy

Surface optical (SO) phonons were studied by Raman spectroscopy in GaAs nanowires (NWs) grown by Ga-assisted chemical beam epitaxy on oxidized Si(111) substrates. NW diameters and lengths ranging between 40 and 65 nm and between 0.3 and 1.3 μm, respectively, were observed under different growth conditions. The analysis of the Raman peak shape associated to either longitudinal or surface optical modes gave important information about the crystal quality of grown NWs. Phonon confinement model was used to calculate the density of defects as a function of the NW diameter resulting in values between 0.02 and 0.03 defects/nm, indicating the high uniformity obtained on NWs cross section size during growth. SO mode shows frequency downshifting as NW diameter decreases, this shift being sensitive to NW sidewall oxidation. The wavevector necessary to activate SO phonon was used to estimate the NW facet roughness responsible for SO shift.

Observation of Hydrofluoric Acid Burns on Osseous Tissues by Means of Terahertz Spectroscopic Imaging

Terahertz technologies have gained great amount of attention for biomedical imaging and tissue analysis. In this study, we utilize terahertz imaging to study the effects of hydrofluoric acid on both compact bone tissue and cartilage. We compare the differences observed in the exposure for formalin fixed and raw, dried, tissue as well as those resulting from a change in hydrofluoric (HF) concentration. Measurements are performed with THz-TDS, and a variety of spectroscopic-based image reconstruction techniques are utilized to develop contrast in the features of interest.

Terahertz metamaterials perfect absorbers for sensing and imaging

Devices operating at THz frequencies have been continuously expanded in many areas of application and major research field, which requires materials with suitable electromagnetic responses at THz frequency ranges. Unlike most naturally occurring materials, novel THz metamaterials have proven to be well suited for use in various devices due to narrow and tunable operating ranges. In this work, we present the results of two THz metamaterial absorber structures aiming two important device aspects; polarization sensitivity and broad band absorption. The absorbers were simulated by finite element method and fabricated through the combination of standard lift-off photolithography and electron beam metal deposition. The fabricated devices were characterized by reflection mode THz time domain spectroscopy. The narrow band absorber structures exhibit up to 95% absorption with a bandwidth of 0.1 THz to 0.15 THz.

Growth, doping, and characterization of ZnO nanowire arrays

Zinc oxide (ZnO) nanowire (NW) arrays were grown by chemical vapor deposition using the carbothermal reduction of ZnO powder at different pressures from 0.13 to 1.0 atm on basal plane sapphire substrates. The ZnO NWs were oriented in their [0001] direction. Lower growth pressures led to generally longer and smaller diameter wires. A model relating the length and diameter of the NWs was used to interpret the growth mechanism of these ZnO NWs as a function of pressure as the combination of adatom diffusion along the NW sidewalls and direct impingement growth on the NW tip. Al-doped ZnO NWs were synthesized by introducing Al power into the source material, resulting in an Al mole fraction up to 1.8 at. % in the NWs and a concurrent reduction in NW resistivity. Raman spectroscopy revealed slight lattice distortion to the ZnO crystal lattice, while room temperature photoluminescence showed an increase in the near band edge emission concurrently with a reduction in the green emission. The near band edge emissio...

New Green Phosphor (Ba1.2Ca0.8-xEux)SiO4 for White-Light-Emitting Diode

A novel promising green phosphor, (Ba1.2Ca0.8-xEux)SiO4, has been developed for low- color-temperature solid-state lighting when used in combination with near-ultraviolet light-emitting diodes. It has a unique crystal structure (hexagonal, T phase) with five different cation sites among all possible (Ba,Sr,Ca)2SiO4:Eu2+ compounds. It exhibits a broad absorption band in the near-ultraviolet region of approximately 400 nm and an intense broad green emission. It shows a slightly higher thermal quenching temperature (175 °C) than conventional yellow (Ba,Sr,Ca)2SiO4:Eu2+ phosphors (150 °C).