Paul S. Hill

Controls on effective settling velocity of suspended sediment in the Eel River flood plume

Abstract Bulk effective settling velocities required to explain sinking losses from the Eel River flood plume off the coast of northern California are of order 0.1 mm s −1 for five different helicopter-based sampling surveys conducted in January and February 1998. These effective settling velocities exceed those expected for single-grain sinking and implicate flocculation as an important mechanism for speeding the removal of sediment from the Eel River plume. The relative constancy of effective settling velocities despite widely varying winds, waves, and currents is consistent with photographs in the plume that show little variability in floc size with total suspended sediment mass concentration, turbulent-kinetic-energy dissipation rate, elapsed time since sediment within flocs left the river mouth, or depth. These observations of floc size contrast with those made in winter 1997 during the exceptionally large New Years flood. During that event, increases of floc size with depth are evident. In 1997, higher sediment concentrations associated with the significantly larger discharge likely allowed flocs to grow substantially as they sank through the plume, whereas in 1998 low concentrations precluded significant increases in floc size with depth. These observations do not support the hypothesis that concentration controls maximal floc size; rather they indicate that the growth rate of flocs is a function of concentration. Using a published relationship between floc size and settling velocity for the Eel shelf suggests that approximately three fourths of the sediment in the plume was packaged as flocs during the 1998 floods.

Microplastic fibers in the intertidal ecosystem surrounding Halifax Harbor, Nova Scotia

Humans continue to increase the use and disposal of plastics by producing over 240 million tonnes per year, polluting the oceans with persistent waste. The majority of plastic in the oceans are microplastics (<5 mm). In this study, the contamination of microplastic fibers was quantified in sediments from the intertidal zones of one exposed beach and two protected beaches along Nova Scotias Eastern Shore. From the two protected beaches, polychaete worm fecal casts and live blue mussels (Mytilus edulis) were analyzed for microplastic content. Store-bought mussels from an aquaculture site were also analyzed. The average microplastic abundance observed from 10 g sediment subsamples was between 20 and 80 fibers, with higher concentrations at the high tide line from the exposed beach and at the low tide line from the protected beaches. Microplastic concentrations from polychaete fecal casts resembled concentrations quantified from low tide sediments. In two separate mussel analyses, significantly more microplastics were enumerated in farmed mussels compared to wild ones.

Models for effective density and settling velocity of flocs

New models to predict settling velocity and effective density of flocs are proposed. The models are based on the concept of fractal geometry, but with the assumption of variable fractal dimension with the floc size. The best results are obtained when the fractal dimension is estimated by a power law function of the floc diameter. The models are compared with observations from 26 published data sets relating floc size to settling velocity measured under various conditions and at different locations. The floc size covered by the data varies between 1.4 and about 25,500µm. Five commonly used models are also compared to these data and found to reproduce inadequately the full range of the observations. Sensitivity analysis shows that, with the proposed models, the spread in the data may be reproduced by varying the size of primary particles from about 0.05 to 20µm. The new models are proposed for integration into numerical models to simulate sediment transport of cohesive sediments, contaminants, and biological microorganisms such as phytoplankton.

Reconciling aggregation theory with observed vertical fluxes following phytoplankton blooms

Sediment trap data show that rapidly sinking pulses of phytodetritus form after phytoplankton blooms, even when bloom intensity is low. A numerical model of physical aggregation and sedimentation in the surface ocean was used to gauge whether predicted aggregation rates were high enough to generate postbloom sediment pulses. Initial models behaved inaccurately without a full range of particle sizes, abundant nonphytoplankton particles, and explicit hydrodynamic retardation of particle contact. Provision for background particles while tracking phytoplankton required implementation of a novel bookkeeping scheme. To address the degree of retardation for contact between particles, an expression for contact efficiency for collision by turbulent shear was developed. The most realistic way to produce model results that mimicked field data was to include background particles, to invoke particle stickiness in the range 0.1–1.0, and to make modest upward adjustments to contact efficiencies calculated for impermeable spheres. For all but the highest background particle concentrations, the magnitude of a postbloom sediment pulse scaled nonlinearly with vertically integrated cell number in the surface layer of our two layer model. The existence of a nonlinear relationship between pulse size and bloom intensity makes initial cell number per unit of area in the surface layer, and not productivity, the proximate determinant of carbon export flux. This result emphasizes the need for caution when applying established scalings between export flux and productivity. Further, it provides a mechanistic explanation both for tight pelagic-benthic coupling under waters prone to intense blooms and for interannual variability in export flux in polar regions.

In situ observations of floc settling velocities in Glacier Bay, Alaska

Abstract In situ floc settling velocities and diameters of particles ranging in size from 0.63 to 5.05 mm equivalent circular diameter were measured under a buoyant discharge plume by deploying a bottom-tripod-mounted Floc Camera Assembly (FCA) in Tarr Inlet, Glacier Bay, Alaska. These observations were used to estimate floc effective densities. Three results emerge from this work. First, fits of settling velocity and effective density to diameter are consistent with expressions published for other environments, suggesting that common controls on floc size and settling velocity operate across diverse marine environments. Second, the raw data show considerable scatter, with upper and lower 95% prediction intervals on settling velocity and excess density differing by about a factor of 7. Analysis of sources of error suggests that the variability is caused by differences in component-grain composition among flocs and turbulent stirring within the stilling box. Third, bin-averaged effective densities and settling velocities are highly correlated with diameter. Thus, while it is not possible, based on diameter, to predict accurately the settling velocity of a single floc, it is possible to estimate the mean settling velocity of a population of like-sized flocs.

Controls on floc size in a continental shelf bottom boundary layer

Simultaneous in situ observations of floc size, waves, and currents in a continental shelf bottom boundary layer do not support generally accepted functional relationships between turbulence and floc size in the sea. In September and October 1996 and January 1997, two tripods were deployed in 70 m of water on the continental shelf south of Woods Hole, Massachusetts. On one a camera photographed particles in suspension 1.2 m above the bottom that had equivalent circular diameters larger than 250 μm, and on the other, three horizontally displaced acoustic current meters measured flow velocity 0.35 m above the bottom. The tripods were separated by ∼150 m. Typically, maximal floc diameter stayed relatively constant, around 1 mm, and it showed a dependence on turbulence parameters that was significantly weaker than that predicted by any model that assumes that turbulence-induced stresses limit floc size. Occasionally, when waves and currents generated intense near-bed turbulence, flocs were destroyed. These precipitous decreases in maximal floc size also were not predicted by conventional models. The correlation in time between episodes of floc destruction and elevated combined wave-current stresses provides the first quantitative support for the hypothesis that floc size throughout bottom boundary layers can be controlled by breakup in the intensely sheared near-bed region. These observations demand a reassessment of the forces limiting floc size in the sea, and they indicate the potential for significant simplifying assumptions in models of floc dynamics.

A laboratory assessment of the relative importance of turbulence, particle composition, and concentration in limiting maximal floc size and settling behaviour

Abstract The fate of fine particulate material in aquatic environments is closely linked to aggregation and disaggregation processes. Understanding the mechanisms controlling these processes is fundamental to the development of predictive models of fate and effects for particulate discharges in the coastal zone from such sources as offshore hydrocarbon exploration and development. One of the variables required for the development of these models is maximal floc size. Using a non-invasive imaging technique, the significance of turbulence, composition, and concentration on maximal floc size in an inverting column flocculator was determined for materials commonly discharged during offshore hydrocarbon development. The settling velocity of the suspension was determined from volume concentrations of samples obtained by pipette during still water settling in a manner similar to that of Owen tubes. After 20 h, both maximal floc size and settling velocity showed a highly significant dependence on turbulence and type of material in suspension, but showed no effect from concentration.

Flocculation and sedimentation on the Po River Delta

With the goal of improving understanding of the effect of flocculation on the formation of fine-grained deposits on continental shelves, hydrographic profiling, in situ imaging of suspended matter, and collection of surficial sediment samples were conducted at the Po River Delta in June 2001. These data show that during medium flow conditions (1920 m3/s), sedimentation occurs rapidly immediately offshore of the main distributary, Po della Pila. Rapid sedimentation is promoted by large rapidly sinking flocs forming in the river well upstream of the mouth. The delivery of fine sediment to the seabed at the mouth of the Po is sufficient to overwhelm the erosive effects of waves and currents, leading to accumulation of mud in water depths as shallow as 4 m. On cross-shelf transects 2 km north and south of the mouth, however, suspended sediment supply from the river is reduced to the point that mud accumulates only seaward of the 8-m isobath. Along the central transect, suspended sediment concentration decreases rapidly seaward of the 6-m isobath where the emergence of a more organic-rich population of flocs along a mid-water density interface is suggested. Energetic activity along the 15-m isobath likely promotes resuspension with the potential for removal of material from the delta. Further investigation of floc properties, namely the relationship of floc size to settling velocity, is necessary to establish the degree to which the suspension is flocculated during transport and deposition.

Effect of particulate aggregation in aquatic environments on the beam attenuation and its utility as a proxy for particulate mass

Marine aggregates, agglomerations of particles and dissolved materials, are an important particulate pool in aquatic environments, but their optical properties are not well understood. To improve understanding of the optical properties of aggregates, two related studies are presented. In the first, an in situ manipulation experiment is described, in which beam attenuation of undisturbed and sheared suspensions are compared. Results show that in the sheared treatment bulk particle size decreases and beam attenuation increases, consistent with the hypothesis that a significant fraction of mass in suspension is contained in fragile aggregates. Interestingly, the magnitude of increase in beam attenuation is less than expected if the aggregates are modeled as solid spheres. Motivated by this result, a second study is presented, in which marine aggregates are modeled to assess how the beam attenuation of aggregates differs from that of their constituent particles and from solid particles of the same mass. The model used is based on that of Latimer [Appl. Opt. 24, 3231 (1985)] and mass specific attenuation is compared with that based on homogeneous and solid particles, the standard model for aquatic particles. In the modeling we use recent research relating size and solid fraction of aquatic aggregates. In contrast with Mie theory, this model provides a rather size-insensitive mass specific attenuation for most relevant sizes. This insensitivity is consistent with the observations that mass specific beam-attenuation of marine particles is in the range 0.2-0.6m(2)/gr despite large variability in size distribution and composition across varied aquatic environments.

Characteristics of oil droplets stabilized by mineral particles: Effects of oil type and temperature

Abstract The relative influence of oil type and temperature on the characteristics of oil droplets stabilized by mineral particles (oil–mineral aggregates––OMA) was studied in the laboratory. OMA were generated by shaking eight different oils under two temperatures with natural mineral fines in seawater at a pre-defined energy level. Shape, mean and maximum sizes, size distribution and concentration of oil droplets forming negatively buoyant OMA were measured by image analysis using epi-fluorescence microscopy. Results showed that oil droplets are, on average, spherical regardless of oil composition and temperature. Non-spherical “elongated” oil droplets form more at 20 °C than at 0 °C. Droplet shape and size were not correlated to oil viscosity. The concentration of oil droplets decreased rapidly with oil viscosity, temperature and asphaltenes–resins content (ARC). When normalized with ARC, mass concentration of oil droplets correlates well with oil viscosity, regardless of experimental temperature. A model was proposed to calculate mass of oil dispersed by OMA as a function of oil viscosity and ARC. Size distributions of oil droplets follow similar trends, but their magnitudes depend on oil type and temperature. A function was derived that describes all the data when size distributions were presented in a normalized form N / N t = f ( D / D 50 ), where N is number of droplets of diameter D , N t is the total number of droplets and D 50 the mean size of the droplets.