Pavel P. Pashinin

Generation of an Electrical Signal Upon the Interaction of Laser Radiation With Water Surface

A new physical effect lying in the generation of an electrical signal (ES) upon the interaction of IR laser radiation with the water surface at a laser fluences lower than the plasma formation threshold is studied. An ES amplitude exceeding 15 V is detected. A one-to-one relationship between the observed effect and the bulk explosive boiling of water is established, and a qualitative interpretation is proposed. In the case of irradiation of an open surface, the ES is generated due to bulk explosive boiling accompanied by the evacuation and splashing of the surface layer, the destruction of the double electric layer on the surface, and the spread of an electrified vapor-drop mixture (balloelectric effect). When the surface is covered with a transparent plate, ES generation can be caused by the charge separation upon the detachment of the water surface from the plate by a vapor bubble resulting from boiling and the displacement of the charged water surface upon the expansion and contraction of the bubble.

Polarized Raman study of random copolymers of propylene with olefins

The polarized Raman spectroscopy is employed in the study of structural modifications in the films of isotactic polypropylene (PP) whose chain contains ethylene, 1-butene, 1-hexene, 1-octene, and 4-metyl-pentene-1, which represents an isomer of 1-hexene. It is demonstrated that the phase and conformational compositions of copolymer molecules depend on the comonomer content and the side-chain length of the second monomer. The content of the PP molecules in the helical conformation in the crystalline and amorphous phases of the copolymers monotonically decreases with increasing content of the second monomer. The decrease in the content of helical macromolecules in the crystalline phase is faster than the decrease in the amorphous phase. At a certain content of comonomers, the total content of the helical fragments decreases with increasing length of the side chain of the second monomer. The structures and Raman spectra of the copolymers of propylene with 1-hexene and 4-methyl-1-pentene are similar.

Raman Spectroscopic Characterization of the Interlayer Structure of Na+-Montmorillonite Clay Modified by Ditetradecyl Dimethyl Ammonium Bromide

Raman spectroscopy has been applied for the rapid and nondestructive monitoring of the interlayer structure of sodium montmorillonite (MMT) clay modified by ditetradecyl dimethyl ammonium (DDA+) bromide. This work demonstrates that a detailed analysis of Raman spectra in the fingerprint region (600-1600 cm(-1)), in combination with model simulation, allows one to distinguish different conformational states of DDA+ in the interlayer space of the modified clay, namely, a liquidlike state but rich in trans conformers, disordered conformational states, and a crystallike conformation appearing at increasing modifier content. These conformations differ in the angle between their alkyl chains, the relative content of trans and gauche conformers and the relative length of trans segments. The shape and width of the Raman band at 1300 cm(-1) and the peak intensity ratio I1088/I1064 can be used for a qualitative analysis of the ratio of gauche/trans conformers. The integral intensity ratios I*1064/I*1300 and I*1300/I*705 help to determine the proportion of trans conformers and the content of the modifier in the clay, respectively, thereof providing quantitative characterization of the modified clay (conformational reorganization and modifier content). Noteworthy, the transition from a liquidlike to crystal-like conformation is further supported by the splitting of the symmetric C-C stretching Raman band of the trans segments within the alkyl chains at 1133 cm(-1) (liquidlike conformation) into two modes at 1124 and 1135 cm(-1) corresponding to two parallel trans chains of nonequivalent lengths (crystal-like conformation).

Raman study of ethylene-propylene copolymers and polyethylene-polypropylene reactor blends

The Raman spectra of the ethylene-propylene copolymers (EPC) synthesized using new metallocene catalytic systems and the polypropylene/polyethylene/diblockcopolymer of propylene and ethylene (PP/PE/DBC) blends obtained using the sequential polymerization are studied. The copolymer and reactor blend spectra are analyzed using the Raman spectra of a series of liquid n-alkanes. Significant monotonic changes are observed in the spectra of EPC and the PP/PE/DBC blends when the ethylene content increases. Substantial differences between the series of samples of blends and copolymers are revealed. In contrast to the EPC spectra, the spectra of the PP/PE/DBC reactor blends are represented as an exact superposition of the homopolymer spectra with the weight coefficients proportional to the contents of the blend components. A monotonic blue shift of the line that corresponds to the symmetric stretching mode of the CH2 groups is observed in the EPC Raman spectra when the ethylene content increases. It is demonstrated that, for this line, the peak position only depends on the relative content of comonomers and does not depend on the contents of the PP and PE crystalline phases. The intensity ratio of two fundamental vibrations of PE and PP with frequencies of 1295 and 1330 cm−1 can be used to determine the relative contents of the PE molecules in the trans-conformation and PP macromolecules in the helical conformation in the PP/PE blends. It is demonstrated that variations in the Raman spectra of n-alkanes, EPC, and PP/PE/DBC reactor blends related to variations in the relative contents of various chemical groups are reliably traced in the spectra of all of the materials under study.

The spall strength limit of matter at ultrahigh strain rates induced by laser shock waves

New results concerning the process of dynamic fracture of materials (spallation) by laser-induced shock waves are presented. The Nd-glass laser installations SIRIUS and KAMERTON were used for generation of shock waves with pressure up to 1 Mbar in plane A1 alloy targets. The wavelengths of laser radiation were 1.06 and 0.53 μm, the target thickness was changed from 180 to 460 μm, and the laser radiation was focused in a spot with a 1-mm diameter on the surface of AMg6M aluminum alloy targets. Experimental results were compared to predictions of a numerical code which employed a real semiempirical wide-range equation of state. Strain rates in experiments were changed from 10 6 to 5 X 10 7 s -1 Two regimes of spallation were evidenced: the already known dynamic regime and a new quasi-stationary regime. An ultimate dynamic strength of 80 kbar was measured. Finally, experiments on targets with artificial spall layers were performed showing material hardening due to shock-wave compression.

Raman study of polyethylene-polypropylene blends

The Raman spectra of the blends that result from the melt mixing of polyethylene (PE) and isotactic polypropylene (PP) are studied. The contents of the blend components can be determined using the ratio of the integral intensities of the PE and PP fundamental vibrations.

High-power laser beam shaping using apodized apertures

This paper gives the results of the investigations of four types of apodized (soft) apertures for beam shaping of UV, visible and IR high-power lasers with near-Gaussian and flat-top transmittance. The apodized apertures (AA) are ≈3–45 mm in diameter, but the principles of fabrication of such apertures lends the possibility of apodizing beams with diameter 200 mm. The examples of studies of the AA in high-power lasers are presented. The possibility of avoiding the Fresnel diffraction ripples is proved experimentally.

Raman spectra of various polymorphs of isotactic polypropylene

The Raman spectra of the α, γ, and smectic modifications of isotactic polypropylene (PP) are studied. The most significant spectral differences are observed in the frequency range around 2960 cm−1 for the spectral doublet assigned to the asymmetric stretching vibrations of the CH3 groups and in the frequency range around 800 cm−1, which is used for analysis of the phase composition of isotactic PP. It is demonstrated that the peak positions and relative intensities of the doublet assigned to the asymmetric stretching vibrations of the CH3 groups can be used to identify the polymorph modifications of isotactic PP.

Highly charged ions from Nd-laser produced plasma of medium and high- Z targets

The project ITEP-TWAC (Tera Watt Accumulator) being in progress at ITEP (Moscow) requires He-like ions for non-Liouvillean injection into the storage ring to accumulate ≈2·10 13 particles with medium masses up to 59 Co 25+ . Powerful lasers were found to be the best choice for those ions production. This work presents the experimental results of highly charge ion generation in plasmas produced by the second harmonic of Nd-glass laser facility with a total energy E ≤ 50 J and pulse duration of about 2.5 ns at GPI (Moscow). Ti and Ta targets were under investigation. An electrostatic ion energy analyzer and an ion charge collector were used to measure the ion charge state spectra at a 3-m distance from the targets. 5·10 7 He-like Ti ions per cm 2 within 1 μs pulse as well as 10 7 Ta +41 per cm 2 within 0.8 μs were observed.

Quantitative characterization of the orientation of macromolecules in intercalated nanocomposites of polyolefins/layered silicates by Raman spectroscopy

Raman spectroscopy is used to study variations in the orientational order of macromolecules in the uniaxially drawn intercalated nanocomposites based on two polymer matrices (polyethylene (PE) and isotactic polypropylene (PP)) and a filler (modified clay (MC)). The orientation parameters of macromolecules measured using Raman spectroscopy are compared with the X-ray data. It is demonstrated that, for the uniaxially drawn PE-MC and PP-MC intercalated nanocomposites, the filler impedes the orientation along the draw direction for the macromolecules localized in the noncrystalline phase of the polymer matrix. The orientational ability of the PE and PP crystallites in nanocomposites is not affected by the filler.