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Dive into the research topics where Pedro E. Sánchez-Jiménez is active.

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Featured researches published by Pedro E. Sánchez-Jiménez.


Journal of Physical Chemistry B | 2011

Kinetic Analysis of Complex Solid-State Reactions. A New Deconvolution Procedure

Antonio Perejón; Pedro E. Sánchez-Jiménez; J.M. Criado; Luis A. Pérez-Maqueda

The kinetic analysis of complex solid-state reactions that involve simultaneous overlapping processes is challenging. A method that involves the deconvolution of the individual processes from the overall differential kinetic curves obtained under linear heating rate conditions, followed by the kinetic analysis of the discrete processes using combined kinetic analysis, is proposed. Different conventional mathematical fitting functions have been tested for deconvolution, paying special attention to the shape analysis of the kinetic curves. It has been shown that many conventional mathematical curves such as the Gaussian and Lorentzian ones fit kinetic curves inaccurately and the subsequent kinetic analysis yields incorrect kinetic parameters. Alternatively, other fitting functions such as the Fraser-Suzuki one properly fit the kinetic curves independently of the kinetic model followed by the reaction and their kinetic parameters, and moreover, the subsequent kinetic analysis yields the correct kinetic parameters. The method has been tested with the kinetic analysis of complex processes, both simulated and experimental.


Journal of Physical Chemistry A | 2010

Generalized kinetic master plots for the thermal degradation of polymers following a random scission mechanism.

Pedro E. Sánchez-Jiménez; Luis A. Pérez-Maqueda; Antonio Perejón; J.M. Criado

In this paper, the f(alpha) conversion functions for random scission mechanisms have been proposed to allow for the construction of generalized master plots suitable for these kinds of mechanisms. The master plots have been validated by their application to simulated data and to the thermal degradation of poly(butylene terephthalate), polyethylene, and poly(tetrafluoroethylene).


Journal of Materials Chemistry C | 2013

Direct mechanosynthesis of pure BiFeO3 perovskite nanoparticles: reaction mechanism

Antonio Perejón; Nataliya Murafa; Pedro E. Sánchez-Jiménez; J.M. Criado; Jan Šubrt; M. J. Diánez; Luis A. Pérez-Maqueda

In this work, a mechanochemical procedure is proposed as a simple and fast method to synthesize the pure BiFeO3 perovskite phase as a nanostructured material without the need for purification treatments, while the mechanochemical reaction mechanism has been investigated and correlated with that of the conventional solid-state reaction. Thus, different milling conditions have been used as a tool for tailoring the crystallite size of the resulting BiFeO3 nanoparticles. The materials prepared by the mechanochemical reaction could be annealed or sintered without the formation of undesirable phases. Both the ferroelectric and ferromagnetic transitions were observed by DSC. Finally, the dielectric constants of the prepared material at different frequencies as a function of the temperature have been measured, showing that the material is clearly an isolator below 200 °C, characteristic of a high quality BiFeO3 material.


Journal of Materials Chemistry C | 2014

Single phase, electrically insulating, multiferroic La-substituted BiFeO3 prepared by mechanosynthesis

Antonio Perejón; Pedro E. Sánchez-Jiménez; Luis A. Pérez-Maqueda; J.M. Criado; Julio Romero de Paz; R. Sáez-Puche; Nahum Masó; Anthony R. West

Single phase, electrically insulating samples of Bi1−xLaxFeO3 solid solutions have been prepared by mechanosynthesis over the whole compositional range for the first time. Lanthanum substitution influenced the kinetics of the mechanochemical reaction and crystallite size of the products. For 0 ≤ x ≤ 0.15, an increase in the La content produced a significant decrease in the weight-normalized cumulative kinetic energy required to obtain the final product and an increase in the resulting crystallite size. Larger La contents did not affect either the reactivity or the crystallite size. The effect of x on the structure has been identified. Samples in the ranges x ≤ 0.15 and x ≥ 0.45 gave single phase solid solutions with R3c and Pnma space groups, respectively, while for the intermediate range, a non-centrosymetric Pn21a(00γ)s00 super structure was obtained. For 0 ≤ x ≤ 0.30, differential scanning calorimetry showed two endothermic effects corresponding to the Neel temperature (TN, antiferromagnetic–paramagnetic transition) and the Curie temperature (TC, ferroelectric–paraelectric transition), demonstrating their multiferroic character. Compositions with a larger La content only showed TN. Dilatometric and permittivity measurements confirmed the results obtained by DSC for the ferroelectric–paraelectric transition. The composition dependence of TN and TC showed that, at low x, TN < TC, but a cross-over, or isoferroic transition occurred at x ∼0.28, when TN = TC = 386 °C. Ceramics with 0 ≤ x ≤ 0.15 were highly insulating at room temperature with a resistivity, extrapolated from the Arrhenius plots, of ∼7 × 1016 to 8 × 1014 Ω cm and an activation energy ∼1.14–1.20 eV. Magnetization of the samples improved with La substitution.


Physical Chemistry Chemical Physics | 2013

CO2 multicyclic capture of pretreated/doped CaO in the Ca-looping process. Theory and experiments

Jose Manuel Valverde; Pedro E. Sánchez-Jiménez; Antonio Perejón; Luis A. Pérez-Maqueda

We study in this paper the conversion of CaO-based CO2 sorbents when subjected to repeated carbonation-calcination cycles with a focus on thermally pretreated/doped sorbents. Analytical equations are derived to describe the evolution of conversion with the cycle number from a unifying model based on the balance between surface area loss due to sintering in the looping-calcination stage and surface area regeneration as a consequence of solid-state diffusion during the looping-carbonation stage. Multicyclic CaO conversion is governed by the evolution of surface area loss/regeneration that strongly depends on the initial state of the pore skeleton. In the case of thermally pretreated sorbents, the initial pore skeleton is highly sintered and regeneration is relevant, whereas for nonpretreated sorbents the initial pore skeleton is soft and regeneration is negligible. Experimental results are obtained for sorbents subjected to a preheating controlled rate thermal analysis (CRTA) program. By applying this preheating program in a CO2 enriched atmosphere, CaO can be subjected to a rapid carbonation followed by a slow rate controlled decarbonation, which yields a highly sintered skeleton displaying a small conversion in the first cycle and self-reactivation in the next ones. Conversely, carbonation of the sorbent at a slow controlled rate enhances CO2 solid-state diffusion, which gives rise, after a quick decarbonation, to a highly porous skeleton. In this case, CaO conversion in the first cycle is very large but it decays abruptly in subsequent cycles. Data for CaO conversion retrieved from the literature and from further experimental measurements performed in our work are analyzed as influenced by a variety of experimental variables such as preheating temperature program, preheating exposition time, atmosphere composition, presence of additives, and carbonation-calcination conditions. Conversion data are well fitted by the proposed model equations, which are of help for a quantitative interpretation of the effect of experimental conditions on the multicyclic sorbent performance as a function of sintering/regeneration parameters inferred from the fittings and allow foreseeing the critical conditions to promote reactivation. The peculiar behavior of some pretreated sorbents, showing a maximum conversion in a small number of cycles, is explained in light of the model.


Analytical Chemistry | 2010

Quantitative characterization of multicomponent polymers by sample-controlled thermal analysis.

Pedro E. Sánchez-Jiménez; Luis A. Pérez-Maqueda; José E. Crespo-Amoros; Juan Lopez; Antonio Perejón; J.M. Criado

This paper explores the potential of sample-controlled thermal analysis (SCTA) in order to perform compositional analysis of multicomponent polymeric materials by means of thermogravimetric experiments. In SCTA experiments, the response of the sample to the temperature determines the evolution of the temperature by means of a feedback system; thus, what is controlled is not the temperature-time profile, as in conventional analysis, but rather the evolution of the reaction rate with time. The higher resolving power provided by the technique has been used for determining the composition of polymer blends composed of polyvinyl chloride (PVC) and different commercial plasticizers, a system where the individual components have very similar thermal stabilities, thereby rendering useless thermogravimetric experiments run under conventional conditions. Different SCTA procedures, such as constant rate thermal analysis (CRTA), which has received special attention, and high-resolution and stepwise isothermal analysis have been tested, and the results obtained have been compared with linear heating rate technique. It has been proven that CRTA can be used to effectively determine the exact composition of the blend.


ACS Applied Materials & Interfaces | 2016

Template-Assisted Hydrothermal Growth of Aligned Zinc Oxide Nanowires for Piezoelectric Energy Harvesting Applications

Canlin Ou; Pedro E. Sánchez-Jiménez; Anuja Datta; Francesca L. Boughey; Richard A. Whiter; Suman-Lata Sahonta; Sohini Kar-Narayan

A flexible and robust piezoelectric nanogenerator (NG) based on a polymer-ceramic nanocomposite structure has been successfully fabricated via a cost-effective and scalable template-assisted hydrothermal synthesis method. Vertically aligned arrays of dense and uniform zinc oxide (ZnO) nanowires (NWs) with high aspect ratio (diameter ∼250 nm, length ∼12 μm) were grown within nanoporous polycarbonate (PC) templates. The energy conversion efficiency was found to be ∼4.2%, which is comparable to previously reported values for ZnO NWs. The resulting NG is found to have excellent fatigue performance, being relatively immune to detrimental environmental factors and mechanical failure, as the constituent ZnO NWs remain embedded and protected inside the polymer matrix.


Chemistry Central Journal | 2013

Clarifications regarding the use of model-fitting methods of kinetic analysis for determining the activation energy from a single non-isothermal curve

Pedro E. Sánchez-Jiménez; Luis A. Pérez-Maqueda; Antonio Perejón; J.M. Criado

BackgroundThis paper provides some clarifications regarding the use of model-fitting methods of kinetic analysis for estimating the activation energy of a process, in response to some results recently published in Chemistry Central journal.FindingsThe model fitting methods of Arrhenius and Savata are used to determine the activation energy of a single simulated curve. It is shown that most kinetic models correctly fit the data, each providing a different value for the activation energy. Therefore it is not really possible to determine the correct activation energy from a single non-isothermal curve. On the other hand, when a set of curves are recorded under different heating schedules are used, the correct kinetic parameters can be clearly discerned.ConclusionsHere, it is shown that the activation energy and the kinetic model cannot be unambiguously determined from a single experimental curve recorded under non isothermal conditions. Thus, the use of a set of curves recorded under different heating schedules is mandatory if model-fitting methods are employed.


Physical Chemistry Chemical Physics | 2016

Combined TGA-MS kinetic analysis of multistep processes. Thermal decomposition and ceramification of polysilazane and polysiloxane preceramic polymers

Cristina García-Garrido; Pedro E. Sánchez-Jiménez; Luis A. Pérez-Maqueda; Antonio Perejón; J.M. Criado

The polymer-to-ceramic transformation kinetics of two widely employed ceramic precursors, 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (TTCS) and polyureamethylvinylsilazane (CERASET), have been investigated using coupled thermogravimetry and mass spectrometry (TG-MS), Raman, XRD and FTIR. The thermally induced decomposition of the pre-ceramic polymer is the critical step in the synthesis of polymer derived ceramics (PDCs) and accurate kinetic modeling is key to attaining a complete understanding of the underlying process and to attempt any behavior predictions. However, obtaining a precise kinetic description of processes of such complexity, consisting of several largely overlapping physico-chemical processes comprising the cleavage of the starting polymeric network and the release of organic moieties, is extremely difficult. Here, by using the evolved gases detected by MS as a guide it has been possible to determine the number of steps that compose the overall process, which was subsequently resolved using a semiempirical deconvolution method based on the Frasier-Suzuki function. Such a function is more appropriate that the more usual Gaussian or Lorentzian functions since it takes into account the intrinsic asymmetry of kinetic curves. Then, the kinetic parameters of each constituent step were independently determined using both model-free and model-fitting procedures, and it was found that the processes obey mostly diffusion models which can be attributed to the diffusion of the released gases through the solid matrix. The validity of the obtained kinetic parameters was tested not only by the successful reconstruction of the original experimental curves, but also by predicting the kinetic curves of the overall processes yielded by different thermal schedules and by a mixed TTCS-CERASET precursor.


Inorganic Chemistry | 2015

Structural, Optical, and Electrical Characterization of Yttrium-Substituted BiFeO3 Ceramics Prepared by Mechanical Activation.

Antonio Perejón; Eva Gil-González; Pedro E. Sánchez-Jiménez; J.M. Criado; Luis A. Pérez-Maqueda

Ceramics of Bi(1-x)Y(x)FeO3 solid solutions (x = 0.02, 0.07, and 0.10) have been prepared by mechanical activation followed by sintering. The effect of yttrium content on the structural, electrical, and optical properties of the materials has been studied. Thus, single-phase solid solutions with rhombohedral R3c structure have been achieved for x = 0.02 and 0.07, while for x = 0.10 the main R3c phase has been detected together with a small amount of the orthorhombic Pbnm phase. Multiferroic properties of the samples, studied by differential scanning calorimetry (DSC), showed that both T(N) and T(C) (temperatures of the antiferromagnetic-paramagnetic and ferroelectric-paraelectric transitions, respectively) decrease with increasing yttrium content. The nature of the ferroelectric-paraelectric transition has been studied by temperature-dependent X-ray diffraction (XRD), which revealed rhombohedral R3c to orthorhombic Pbnm phase transitions for x = 0.07 and 0.10. On the other hand, for x = 0.02 the high-temperature phase was indexed as Pnma. Optical properties of the samples, as studied by diffuse reflectance spectroscopy, showed low optical band gap that decreases with increasing yttrium content. Prepared ceramics were highly insulating at room temperature and electrically homogeneous, as assayed by impedance spectroscopy, and the conductivity increased with x.

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Luis A. Pérez-Maqueda

Spanish National Research Council

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Antonio Perejón

Spanish National Research Council

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J.M. Criado

Spanish National Research Council

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Eva Gil-González

Spanish National Research Council

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M. J. Diánez

Spanish National Research Council

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Rishi Raj

University of Colorado Boulder

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Cristina García-Garrido

Spanish National Research Council

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Juan Miranda-Pizarro

Spanish National Research Council

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