Pei Ling Chiu

Di­bromo­[2,2′,3,3′‐tetra­hydro‐3,3′‐bis(4‐methoxy­benzyl)‐1,1′‐methyl­enedi‐1H‐imidazole‐κ2C2,C2′]­palladium(II)

The structure of the title compound, [PdBr2(C23H24N4O2)], was determined at 273 K. It crystallizes in the non-centrosymmetric trigonal space group P32. Non-classical hydrogen bonds of types C—H⋯Br and C—H⋯O exist in the structure.

1,1′‐Bis(3‐methoxy­benzyl)‐3,3′‐methyl­enediimidazolium dibromide

The structure of the title compound, C23H25N4O22+·2Br−, has been determined at 294 K. The central C atom of the cation is located on a crystallographic twofold rotation axis. Non-classical intermolecular hydrogen bonds of the types C—H⋯Br and C—H⋯O are present in the crystal structure.