Pei-Ling Wang

Dating the rise of atmospheric oxygen

Several lines of geological and geochemical evidence indicate that the level of atmospheric oxygen was extremely low before 2.45 billion years (Gyr) ago, and that it had reached considerable levels by 2.22 Gyr ago. Here we present evidence that the rise of atmospheric oxygen had occurred by 2.32 Gyr ago. We found that syngenetic pyrite is present in organic-rich shales of the 2.32-Gyr-old Rooihoogte and Timeball Hill formations, South Africa. The range of the isotopic composition of sulphur in this pyrite is large and shows no evidence of mass-independent fractionation, indicating that atmospheric oxygen was present at significant levels (that is, greater than 10-5 times that of the present atmospheric level) during the deposition of these units. The presence of rounded pebbles of sideritic iron formation at the base of the Rooihoogte Formation and an extensive and thick ironstone layer consisting of haematitic pisolites and oölites in the upper Timeball Hill Formation indicate that atmospheric oxygen rose significantly, perhaps for the first time, during the deposition of the Rooihoogte and Timeball Hill formations. These units were deposited between what are probably the second and third of the three Palaeoproterozoic glacial events.

Diachronous uplift of the Tibetan plateau starting 40 Myr ago

The uplift of the Tibetan plateau is generally regarded as a response to the convective removal of the lower portion of the thickened Asian lithosphere. This removal is also thought to be responsible for the east–west extension that took place during the India–Asia collision. The timing of these events has been a subject of great interest for understanding mountain-building processes, collisional tectonics and the influence of these processes on climate change,. In western Tibet, potassic lavas related to east–west extension were found to have been extruded over the past 20 Myr (refs 5, 6). Here we report the widespread occurrence of magmas in eastern Tibet which show similar geochemical signatures to the potassic lavas to the west but formed 40–30 Myr ago. These magmatic activities suggest a diachronous uplift history for the Tibetan plateau, with the convective removal of the lower lithosphere inducing rapid uplift in the east beginning some 40 Myr ago and in the west about 20 Myr later. This observation is consistent with sedimentation records from the Ganges–Brahmaputra delta to the Bengal fan, and can better account for the tectonically driven models for strontium isotope evolution in the ocean and global cooling over the past 40 Myr.

Intraplate extension prior to continental extrusion along the Ailao Shan-Red River shear zone

Left-lateral movement of the Ailao Shan–Red River shear zone lends support to the hypothesis of continental extrusion resulting from the collision of India with Asia. Our new observations from northwestern Yunnan, China, and northwestern Vietnam on different sides of the shear zone demonstrate that the sinistral offset was ∼600 km according to correlations of Permian-Triassic flood basalt successions and late Paleogene highly potassic mafic magmas. We conclude that the shear was propagating on the South China continental margin and does not correspond to a suture between South China and Indochina. Furthermore, the highly potassic magmas were emplaced from ca. 40 to 30 Ma, before the shear movement, which was caused by the late Oligocene to early Miocene (ca. 27–22 Ma) extrusion activity. This suggests that a late Eocene to early Oligocene intraplate extension, possibly induced by delamination of thickened continental lithosphere, took place in northwestern Yunnan (or eastern Tibet) as a response to the India-Asia collision. This extension, and sea-floor spreading of the South China Sea that began ca. 30 Ma, could have accounted for the initiation of the Ailao Shan–Red River shear zone.

Thermochronological evidence for the movement of the Ailao Shan-Red River shear zone: A perspective from Vietnam

In order to explore the timing of strike-slip movement along the Ailao Shan–Red River shear zone, an 40Ar/39Ar thermochronological study of the Day Nui Con Voi metamorphic massif in northern Vietnam was undertaken. The massif, exposed in the southeastern segment of the Ailao Shan–Red River shear zone, reveals a rapid cooling in the early Miocene (25–21 Ma) after a very slow cooling ca. 34–25 Ma. The slow cooling period most likely resulted from a geothermal perturbation in the lithosphere owing to the late Paleogene (40–30 Ma) extension in eastern Tibet and western Yunnan, China. The rapid cooling, consistent with evidence of a wider rapid cooling span from 27 to 17 Ma compiled from the entire Ailao Shan–Red River shear zone, constrains the duration of left-lateral shearing, which eventually offset Indochina from South China by about 600 km. The time constraints we have established reinforce the argument that the onset of the Ailao Shan–Red River shear zone postdates the opening of the South China Sea that began ca. 30 Ma. This result highlights the necessity for reevaluating the Cenozoic tectonic models of Southeast Asia.

Onset timing of left-lateral movement along the Ailao Shan–Red River Shear Zone: 40Ar/39Ar dating constraint from the Nam Dinh Area, northeastern Vietnam

Left-lateral motion along the Ailao Shan‐Red River (ASRR) Shear Zone has been widely advocated to be the result of the collision between the Indian and Eurasian plates and to account for sea-floor spreading in the South China Sea. Our new 40 Ar/ 39 Ar data on the south-easternmost outcrop of the Day Nui Con Voi metamorphic massif, northern Vietnam, suggest that the exhumation of metamorphic massif by shearing along the ASRR zone began 027 Ma and lasted until 022 Ma. A perfect correlation between location and cooling path for the samples along the shear zone suggests that the transtensional deformation may have propagated northwestward at a rate of 0 6c m y ˇ1 . Such a good correlation also indicates that the onset of the leftlateral movement of the shear zone may have occurred later than 027.5 Ma. This conclusion is consistent with our previous interpretation that collision-induced southeastward extrusion of Indochina along the ASRR Shear Zone postdates the opening of the South China Sea, and that extrusion tectonics in SE China may not be responsible for the opening of the South China Sea. # 2000 Elsevier Science Ltd. All rights reserved.

Geochemical and Sr-Nd isotopic characteristics of granitic rocks from northern Vietnam

Abstract Five major felsic igneous suites from northern Vietnam, with ages from mid-Proterozoic to early Cenozoic, were studied. Representative granitic rocks from the Posen Complex (mid-Proterozoic) and the Dienbien Complex (late Permian to early Triassic) show geochemical characteristics similar to those of calc-alkaline to high-K calc-alkaline I-type granites. However, the former, located in the South China block, has significantly higher initial Nd isotopic ratios [eNd(T)=+0.7 to +1.5] and older Nd isotopic model ages (TDM∼1.7 Ga) than the latter [eNd(T)=−4.7 to −9.7; TDM∼1.3–1.5 Ga] which were emplaced south of the Song Ma Suture and thus in the Indochina block. The generation of both complexes may be attributed to subduction-related processes that occurred in two distinct crustal provenances with different degrees of mantle inputs. On the other hand, Jurassic to Cretaceous granitic rocks from the Phusaphin Complex, contemporaneous rhyolites from the Tule Basin, and late Paleogene granitic rocks from the Yeyensun Complex, all exposed in the South China block between the Ailao Shan–Red River shear zone and the Song Ma Suture, display geochemical features similar to those of A-type granites with intermediate eNd(T) values (+0.6 to −2.8) and younger TDM ages (0.6–1.1 Ga). These magmas are suggested to have been generated as a consequence of intraplate extension in the western part of the South China block (Yunnan), and to have been transported to their present position by mid-Tertiary continental extrusion along the Ailao Shan–Red River shear zone related to the India–Asia collision. Overall, the isotopic and model age data, reported in this study indicate that in northern Vietnam, the most important crust formation episode took place in the Proterozoic. Likewise, repeated mantle inputs have played a role in the petrogenesis of Phanerozoic granitic rocks.

An ultraviolet laser microprobe for the in situ analysis of multisulfur isotopes and its use in measuring Archean sulfur isotope mass-independent anomalies

Abstract A laser fluorination microprobe system has been constructed for high-accuracy, high-precision multisulfur isotope analysis with improved spatial resolution. The system uses two lasers: (a) a KrF excimer laser for in situ spot analysis by ultraviolet (UV) photoablation with λ = 248 nm and (b) a CO 2 laser for whole-grain analysis of powdered samples by infrared heating at λ = 10.6 μm. A CO 2 laser is necessary for the analysis of interlaboratory isotope reference materials because they are supplied as powders. The δ 34 S and δ 33 S compositions of reference materials measured with a CO 2 laser fluorination system agree (±0.2‰, 1σ) with the recommended values by the Sulfur Isotope Working Group of the International Atomic Energy Agency (Ding et al., 2001; Taylor, in press) . The precision of replicate analyses of powdered sulfide minerals with the CO 2 laser is typically ±0.2‰ (1σ) for δ 34 S. The in situ fluorination of sulfides with a KrF excimer laser (λ = 248 nm) was validated by comparison of measurements of side-by-side laser craters and powders excavated from drill holes. Powders from drill holes were analyzed with the CO 2 laser. In situ laser craters and drill hole powders give the same δ 34 S V-CDT and δ 33 S V-CDT values within 0.2‰. The δ 34 S V-CDT and δ 33 S V-CDT values of both powders and in situ analyses are independent of F 2 gas pressure over a range of 15 to 65 torr. No dependence of δ 34 S V-CDT and δ 33 S V-CDT values on UV laser energy fluence has been observed. Mineral-specific fractionation of sulfur isotopes in analyzing pyrite, sphalerite, galena, troilite, and chalcopyrite has not been observed with a KrF excimer laser (λ = 248 nm). Test analyses with an ArF excimer laser (λ = 193 nm), however, gave fractionated sulfur isotope ratios. A range of Δ 33 S anomalies of from – 1.5 to +3.0‰ in Archean samples from the North Pole district, Pilbara Craton, Australia, and from black shale of the Lokamonna Formation, South Africa, were verified by in situ analysis of individual pyrite grains with a KrF excimer laser. These results show that a combination of high-accuracy, high-precision analyses with improved spatial resolution permits locating and analyzing host minerals of non-mass-dependent sulfur isotope anomalies.

First evidence for Archean continental crust in northern Vietnam and its implications for crustal and tectonic evolution in Southeast Asia

Southeast Asia, or, in a more strict sense, the Indochinese continent, was previously considered to be composed entirely of Proterozoic to Phanerozoic rocks, and reliable evidence for Archean crust was lacking. Gneisses from the Cavinh Complex, south of the Red River shear zone, northern Vietnam, however, show Archean Nd model ages of 3.4–3.1 Ga. Zircon separates from the rocks yielded U-Pb dates of 2.8–2.5 Ga, the first convincing evidence for the presence of a Late Archean complex in Southeast Asia. Given that the Red River shear zone was propagating in the South China block with a left-lateral offset of ∼600 km, the Cavinh Complex can be correlated with the Late Archean Kangding Complex in the western margin of the Yangtze craton, southwestern China. The Cavinh Complex therefore represents one of the oldest crustal nuclei of the South China block.

Microbial methane cycling in a terrestrial mud volcano in eastern Taiwan

Microbial communities responsible for methane cycling in mud volcanoes onshore are poorly characterized. This study analysed bubbling fluids and cored sediments retrieved from a mud volcano in eastern Taiwan. The pore water profiles revealed that methane concentrations generally increased with depth and changed dramatically at different depth intervals at different sites. The methane concentrations were inversely correlated with Fe(2+)/Mn(2+) concentrations and δ(13)C values of methane, marking iron/manganese-methane transition zones in the sediment cores. Archaeal communities were dominated by ANME-2a members and methylotrophic methanogens, whereas bacterial communities consisted primarily of Proteobacteria, Firmicutes and Bacteroidetes. The 16S rRNA gene copy numbers of ANME-2a and Desulfuromonas/Pelobacter populations varied by two to three orders of magnitude along the profile and exhibited a pattern comparable with those of Fe(2+) and δ(13)C values of methane. These lines of evidence suggest a coupling between anaerobic methanotrophy and metal reduction in the metal-methane transition zones under sulfate-deficient conditions, a metabolic scheme contrasting with that observed in marine cold seeps. Anaerobic methanotrophs proliferate by removing methane produced from in situ methanogenesis and originating from the deep source. Methane finally emitted into the atmosphere is quantitatively and isotopically altered by various microbial processes compartmentalized at different depth intervals.

Testing the use of microfossils to reconstruct great earthquakes at Cascadia

Coastal stratigraphy from the Pacific Northwest of the United States contains evidence of sudden subsidence during ruptures of the Cascadia subduction zone. Transfer functions (empirical relationships between assemblages and elevation) can convert microfossil data into coastal subsidence estimates. Coseismic deformation models use the subsidence values to constrain earthquake magnitudes. To test the response of foraminifera, the accuracy of the transfer function method, and the presence of a pre-seismic signal, we simulated a great earthquake near Coos Bay, Oregon, by transplanting a bed of modern high salt-marsh sediment into the tidal flat, an elevation change that mimics a coseismic subsidence of 0.64 m. The transplanted bed was quickly buried by mud; after 12 mo and 5 yr, we sampled it for foraminifera. Reconstruction of the simulated coseismic subsidence using our transfer function was 0.61 m, nearly identical to the actual elevation change. Our transplant experiment, and additional analyses spanning the A.D. 1700 earthquake contact at the nearby Coquille River 15 km to the south, show that sediment mixing may explain assemblage changes previously interpreted as evidence of pre-seismic land-level change in Cascadia and elsewhere.