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Dive into the research topics where Peter James Smith is active.

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Featured researches published by Peter James Smith.


Tetrahedron Letters | 1985

Large concentration effects on the magnitude of secondary alpha-deuterium kinetic isotope effects

Kenneth Charles Westaway; Zbigniew Waszczylo; Peter James Smith; Kanchugarakoppal S. Rangappa

Because the secondary alpha-deuterium kinetic isotope effects in some SN2 and E2 reactions are strongly concentration dependent, isotope effects measured at a single concentration could lead to erroneous conclusions about the mechanisms and transition state structures.


Tetrahedron Letters | 1982

The reaction of 2-substituted-9-(ortho-substituted penylmethyl) fluoren-9-yltrimethylammonium ions in chloroform. Alkene formation via a carbocation.

J. Pradhan; Peter James Smith

Abstract The reaction of several quaternary ammonium salts in chloroform is found to give exclusively the alkene product by the El mechanism.


Tetrahedron Letters | 1971

Ferrate (VI) ion, a novel oxidizing agent☆

R.J. Audette; J.W. Quail; Peter James Smith


Canadian Journal of Chemistry | 1989

The effect of the nature of the amine leaving group on the nature of the E2 transition state for the reaction of 1-phenylethylammonium ions with sodium ethoxide in ethanol

Peter James Smith; Md. Amin


Canadian Journal of Chemistry | 1986

Solvolysis of 2-substituted-9-(otrho-substituted phenylmethyl)fluoren-9-yltrimethylammonium ions in various solvents. The effect of steric crowding on alkene formation

Peter James Smith; Jyotsna Pradhan


Canadian Journal of Chemistry | 2001

Using secondary alpha deuterium kinetic isotope effects to determine the stereochemistry of an E2 reaction; the stereochemistry of the E2 reaction of 1-chloro-2-phenylethane with potassium tert-butoxide in tert-butyl alcohol

Peter James Smith; David A. J. Crowe; Kenneth Charles Westaway


Canadian Journal of Chemistry | 1987

Secondary α hydrogen–deuterium kinetic isotope effects in the syn-elimination reaction of 2-phenylethyldimethylamine oxide

Peter James Smith; Kenneth Charles Westaway


Canadian Journal of Chemistry | 1985

Secondary α-deuterium kinetic isotope effects for the E2 reaction of the 2-phenylethyl halides with tert-butoxide ion in tert-butyl alcohol

Peter James Smith; Kanchugarakoppal S. Rangappa; Kenneth Charles Westaway


Tetrahedron Letters | 1972

The nature of the transition state for the E2 reaction of 1-arylethylammonium ions with sodium ethoxide in ethanol1

Peter James Smith; S.K. Tsui


Diazonium and Diazo Groups: Volume 2 (1978) | 2010

Preparation and uses of isotopically labelled diazonium and diazo compounds

Peter James Smith; Kenneth Charles Westaway

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S.K. Tsui

University of Saskatchewan

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J. Pradhan

University of Saskatchewan

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J.W. Quail

University of Saskatchewan

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R.J. Audette

University of Saskatchewan

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