Peter Shanahan

Solar disinfection (SODIS): simulation of solar radiation for global assessment and application for point-of-use water treatment in Haiti

Haiti and other developing countries do not have sufficient meteorological data to evaluate if they meet the solar disinfection (SODIS) threshold of 3-5 h of solar radiation above 500 W/m2, which is required for adequate microbial inactivation in drinking water. We have developed a mathematical model based on satellite-derived daily total energies to simulate monthly mean, minimum, and maximum 5-h averaged peak solar radiation intensities. This model can be used to assess if SODIS technology would be applicable anywhere in the world. Field measurements were made in Haiti during January 2001 to evaluate the model and test SODIS efficacy as a point-of-use treatment option. Using the total energy from a measured solar radiation intensity profile, the model recreated the intensity profile with 99% agreement. NASA satellite data were then used to simulate the mean, minimum, and maximum 5-h averaged peak intensities for Haiti in January, which were within 98.5%, 62.5%, and 86.0% agreement with the measured values, respectively. Most of the discrepancy was attributed to the heterogeneous nature of Haitis terrain and the spatial resolution of the NASA data. Additional model simulations suggest that SODIS should be effective year-round in Haiti. Actual SODIS efficacy in January was tested by the inactivation of total coliform, E. coli, and H2S-producing bacteria. Exposure period proved critical. One-day exposure achieved complete bacterial inactivation 52% of the time, while a 2-day exposure period achieved complete microbial inactivation 100% of the time. A practical way of providing people with cold water every morning that has undergone a 2-day exposure would be to rotate three groups of bottles every morning, so two groups are out in the sun and one is being used for consumption.

Rainfall-induced landslide susceptibility zonation of Puerto Rico

Landslides are a major geologic hazard with estimated tens of deaths and

Groundwater in the Urban Environment

1–2 billion in economic losses per year in the US alone. The island of Puerto Rico experiences one or two large events per year, often triggered in steeply sloped areas by prolonged and heavy rainfall. Identifying areas susceptible to landslides thus has great potential value for Puerto Rico and would allow better management of its territory. Landslide susceptibility zonation (LSZ) procedures identify areas prone to failure based on the characteristics of past events. LSZs are here developed based on two widely applied methodologies: bivariate frequency ratio (FR method) and logistic regression (LR method). With these methodologies, the correlations among eight possible landslide-inducing factors over the island have been investigated in detail. Both methodologies indicate aspect, slope, elevation, geological discontinuities, and geology as highly significant landslide-inducing factors, together with land-cover for the FR method and distance from road for the LR method. The LR method is grounded in rigorous statistical testing and model building but did not improve results over the simpler FR method. Accordingly, the FR method has been selected to generate a landslide susceptibility map for Puerto Rico. The landslide susceptibility predictions were tested against previous landslide analyses and other landslide inventories. This independent evaluation demonstrated that the two methods are consistent with landslide susceptibility zonation from those earlier studies and showed this analysis to have resulted in a robust and verifiable landslide susceptibility zonation map for the whole island of Puerto Rico.

Distribution and abundance of human‐specific Bacteroides and relation to traditional indicators in an urban tropical catchment

Groundwater is a critical resource for many of the world’s cities. While a few cities (for example, New York) rely upon protected surface-water reservoirs for their supply, many more depend on groundwater. Conservation, protection, and management of groundwater are thus necessities for most cities. This chapter reviews the basics of groundwater hydrology, supply, and water quality, and then goes on to examine groundwater in the specific context of the urban environment.

Associations of chemical tracers and faecal indicator bacteria in a tropical urban catchment.

The study goals were to determine the relationship between faecal indicator bacteria (FIB), the HF183 marker and land use, and the phylogenetic diversity of HF183 marker sequences in a tropical urban watershed.

Evaluation of pollutant removal efficiency of a bioretention basin and implications for stormwater management in tropical cities

Surface water contamination by human faecal wastes is a widespread hazard for human health. Faecal indicator bacteria (FIB) are the most widely used indicators to assess surface water quality but are less-human-specific and have the potential to survive longer and/or occur naturally in tropical areas. In this study, 13 wastewater chemicals (chloride, boron, orthosphophate, detergents as methylene blue active substances, cholesterol, cholestanol, coprostanol, diethylhexyl phthalate, caffeine, acetaminophen, ibuprofen, sucralose and saccharin) were investigated in order to evaluate tracers for human faecal and sewage contamination in tropical urban catchments. Surface water samples were collected at an hourly interval from sampling locations with distinct major land uses: high-density residential, low-density residential, commercial and industrial. Measured concentrations were analysed to investigate the association among indicators and tracers for each land-use category. Better correlations were found between different indicators and tracers in each land-use dataset than in the dataset for all land uses, which shows that land use is an important determinant of drain water quality. Data were further segregated based on the hourly FIB concentrations. There were better correlations between FIB and chemical tracers when FIB concentrations were higher. Therefore, sampling programs must be designed carefully to take the time of sampling and land use into account in order to effectively assess human faecal and sewage contamination in urban catchments. FIB is recommended as the first tier in assessment of surface water quality impairment and chemical tracers as the second tier. Acetaminophen and coprostanol are recommended as chemical tracers for high-density residential areas, while chloride, coprostanol and caffeine are recommended for low-density residential areas.

Iterative approach to groundwater flow modeling of the Martinsville Alternative Site, under consideration for low-level radioactive waste storage in Clark County, Illinois, U.S.A.

Non-point source pollution is a prevalent problem throughout the world. Bioretention basins have been deployed worldwide to treat stormwater runoff and alleviate eutrophication in downstream water resources. However, basin performance in the tropics is poorly understood. Given the distinctly different rainfall-runoff characteristics of tropical climates, whether basins that are built according to temperate design guidelines are effective is questionable. There have been no field studies based on continuous, high-resolution, long-term monitoring in the tropics. In this study, 96 storms were monitored in the first bioretention basin in Singapore. Of these, flow measurements were made during 80 events and samples were collected and analyzed for 15 water quality parameters (including nitrogen and phosphorus species, total suspended solids, and chemical oxygen demand) during six events. The mean removal rates were 25%, 46%, and 53% for total nitrogen, total phosphorus, and total suspended solids respectively. Results show that a lack of storage capacity and resulting high overflow reduce pollutant removal efficiency for high-rainfall-depth events. The transition from efficient to non-efficient removal occurs at a rainfall depth between 10 and 30 mm. Low EMC (event mean concentration) and weak first flush as a result of frequent and intense rainfall in the tropics also contribute to low removal rate. The results suggest a need to revise bioretention basin design guidelines for the tropics to be based on WQV or WQD (water quality volume or depth) instead of ARI (average recurrence interval). A larger basin volume (WQD between 10 to 30 mm) is recommended.

Dry weather bacteria monitoring and variation with land use for Kranji Reservoir Catchment, Singapore

The regulatory requirements for characterization of the Martinsville Alternative Site (MAS) were fulfilled by applying an iterative approach to the groundwater flow modeling of the site and surrounding area. The approach consisted of field data collection and development of an initial conceptual model. The numerical model was then constructed to be consistent with the data and conceptual model. Next, the calibration results were evaluated statistically, and visually by a groundwater modeling review committee, to determine if the model accurately represented groundwater flow at the site. Initial results failed acceptance criteria because the values of numerical model input parameters had to be varied beyond observed data ranges to calibrate the results, and therefore the model was inconsistent with the initial conceptual model. This led to additional field data collection in areas where the numerical model deviated most from field-determined data. The new data provided sufficient information to revise the conceptual model and calibrate the numerical model successfully. Model calibration was followed by validation. Validation of the numerical model provided additional assurance that the model correctly simulated the observed system. No additional data were found to be necessary during validation of the MAS numerical model. The iterative approach proved to be successful for calibrating and validating this groundwater flow model and should be implemented from the onset of characterization planning in other applications.