Philipp Thiele

Low-melting salts with the [Cr III (NCS) 4 (1,10-phenanthroline)] − complex anion: Syntheses, properties, and structures

Four new low melting salts, “Ionic Liquids” consisting of the [CrIII(NCS)4(Phen)]− complex monoanion and imidazolium based cations A, with A = 1-ethyl-3-methylimidazolium (EMIm), 1-butyl-3-methylimidazolium (BMIm), 1,3-dimethyl-2,4,5-triphenylimidazolium (DML), and 1,2,3,4,5-pentamethyl-imidazolium (PMIm), were investigated. Single-crystal X-ray investigations established the structures of the four compounds. (EMIm)[Cr(NCS)4(Phen)] (I): triclinic,

Electrical Energy Storage by a Magnesium-Copper-Sulfide Rechargeable Battery

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CCDC 1499705: Experimental Crystal Structure Determination

, a = 8.1382(6), b = 10.4760(8), c = 16.003(1) Å, α = 90.330(4)°, β = 94.759(4)°, γ = 107.305(4)°, Z = 2, R1(F)/wR2(F2) = 0.0650/0.1770; (BMIm)[Cr(NCS)4(Phen)] (II): triclinic,

CCDC 1499724: Experimental Crystal Structure Determination

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CCDC 1499714: Experimental Crystal Structure Determination

, a = 8.5545(4), b = 9.8620(4), c = 16.6762(6) Å, α = 92.503(2)°, β = 97.517(2)°, γ = 91.249(2)°, Z = 2, R1(F)/wR2(F2) = 0.0393/0.0848; (DML)[Cr(NCS)4(Phen)] · C3H6O (III): triclinic,