Philippa Huntsman-Mapila

Dissolved Organic Matter Accumulation, Reactivity, and Redox State in Ground Water of a Recharge Wetland

Ground water beneath the seasonal swamp of the Okavango Delta, a recharge wetland in northwestern Botswana, is known to be a sink for solutes. In this study, measurements of organic carbon and inorganic ion concentrations, as well as UV-visible and fluorescence spectroscopy, were used to examine dissolved organic matter (DOM) storage and redox state of fulvic acids in ground water beneath an island and riparian woodland. Increasing dissolved organic carbon (DOC) concentrations along the ground-water flowpath suggests an accumulation of DOM in ground water, especially beneath island centers. However, the increase in DOC concentration was relatively less than the increase in chloride and sulfate concentrations, indicating non-conservative behavior of DOM in ground water beneath wetland islands. In combination with a decrease in fulvic acid content and specific UV absorbance, this result suggests that preferential sorption or destabilization of more aromatic organic compounds may be occurring under conditions of high pH and salinity. Finally, the increase in reduced fluorescence components (semiquinone- and hydroquinone-like components) along the ground-water flowpath strongly supports the transition to reduced fulvic acids in ground water of island centers. The reactivity and potential electron-shuttling function of fulvic acids may play an important role in the dissolution of metal oxides and associated DOM-iron-arsenic interactions in ground water of this recharge wetland.

Spatial and Seasonal Variability in Surface Water Chemistry in the Okavango Delta, Botswana: A Multivariate Approach

The annual flood pulse in the Okavango Delta (Botswana), has a major influence on water chemistry and habitat. We explore spatial and temporal patterns in a suite of chemical variables, analysed from 98 sample points, across four regions, taken at different stages of the flood cycle. The major pattern in water chemistry is characterised by an increasing gradient in ionic concentration from deep-water sites in the Panhandle to more shallow, distal regions to the south. Concentrations of cations, anions, dissolved organic carbon, and SiO2 are significantly higher in the seasonally inundated floodplains than in permanently flooded regions. Several variables (including Na and total nitrogen) significantly increase from low flood to high flood, while others (including HCO3, SiO2, and Cl) increase in concentration, initially between low flood and flood expansion, before declining at maximum flood extent. Redundancy analysis (RDA) revealed that hydrological variables (water depth, flow velocity, flood frequency, and hydroperiod class) significantly explain 17% variation in surface water chemistry. Predictions of increasing flood volume in the near future may result in a decline in alkalinity and dilution of DOC. Our study provides an important baseline from which to monitor future change in the Delta.

Use of remotely sensed data in the analysis of soil‐vegetation changes along a drying gradient peripheral to the Okavango Delta, Botswana

This work determines the value of remotely sensed imagery in developing drying impacts which occur as a result of internal and/or external factors in the Okavango catchment. Three sites provide a preview of the consequences of Delta margin drying as depicted over historical, intermediate and geological timescales. Initially, supervised classification resulted in the identification of sequences of islands and flood plains and their associated vegetation cover on ETM+ imagery, with a classification accuracy of 74–77%. Comparative results, augmented by patch analysis, suggest that through time, island woody vegetation cover has invaded the flood plains and locally developed protected ecotonal areas (extensions) which are densely treed, relative to adjacent, non‐protected flood plains. Over longer time periods, protected areas between extensions became infilled with woody vegetation leading to, in effect, island enlargement or agglomeration. Disadvantages of long‐term Delta drying in terms of natural resource management include a reduced availability of wetland‐based construction and agricultural resources. If natural regeneration (island agglomeration) is allowed to take place, these resources may ultimately be replaced by dryland timber and potential cropland.