Philippe Pagé

Forearc extension and sea-floor spreading in the Thetford Mines Ophiolite Complex

Abstract The Ordovician Thetford Mines Ophiolite Complex (TMOC) is an oceanic terrane accreted to the Laurentian margin during the Taconic Orogeny and is affected by syn-obduction (syn-emplacement) deformation and two post-obduction events (Silurian backthrusting and normal faulting, and Acadian folding and reverse faulting). The southern part of the TMOC was tilted to the vertical during post-obduction deformation and preserves a nearly complete cross-section through the crust. From base to top we distinguish cumulate Dunitic, Pyroxenitic and Gabbroic Zones, a hypabyssal unit (either sheeted dykes or a subvolcanic breccia facies), and an ophiolitic extrusive-sedimentary sequence, upon which were deposited sedimentary rocks constituting the base of a piggy-back basin. Our mapping has revealed the presence of subvertically dipping, north-south- to 20°-striking faults, spaced c. 1 km apart on average. The faults are manifested as sheared or mylonitic dunites and synmagmatic breccias, and correspond to breaks in lithology. The fault breccias are cut by undeformed websteritic to peridotitic intrusions, demonstrating the pre- to synmagmatic nature of the faulting. Assuming that rhythmic cumulate bedding was originally palaeo-horizontal, kinematic analysis indicates that these are normal faults separating a series of tilted blocks. In the upper part of the crust, the north-south-striking fault blocks contain north-south-striking dykes that locally constitute a sheeted complex. The faults correspond to marked lateral changes in the thickness and facies assemblages seen in supracrustal rocks, are locally marked by prominent subvolcanic breccias, and have upward decreasing throws suggesting that they are growth faults. The base of the volcano-sedimentary sequence is a major erosional surface in places, which can penetrate down to the Dunitic Zone. The evidence for coeval extension and magmatism, and the discovery of a locally well-developed sheeted dyke complex, suggest that the TMOC formed by sea-floor spreading. The dominance of a boninitic signature in cumulate and volcanic rocks suggests that spreading occurred in a subduction zone environment, possibly in a forearc setting.

Chalcophile and platinum-group element distribution in the Ultramafic series of the Stillwater Complex, MT, USA—implications for processes enriching chromite layers in Os, Ir, Ru, and Rh

All of the rocks from the Ultramafic series of the Stillwater Complex are enriched in PGE relative to most mafic magmas. Furthermore, the chromite layers are particularly enriched in IPGE (Os, Ir, and Ru) and Rh. This enrichment appears to be a common characteristic of ultramafic rocks from many types of settings, layered intrusions, ophiolites, and zoned complexes. We have carried out a petrological, mineralogical, and geochemical study to assess how the enrichment occurred in the case of the Stillwater Complex and applied our results to the chromite layers of the Bushveld and Great Dyke complexes. The minerals that now host the PGE are laurite and fine-grained intergrowths of pentlandite, millerite, and chalcopyrite. The laurite occurs as inclusions in chromite, and mass balance calculations indicate that it hosts most of the Os, Ir, and Ru. The sulfide minerals occur both as inclusions in chromite and as interstitial grains. The sulfides host much of the Pd and Rh. The IPGE and Rh correlate with Cr but not with S or Se, indicating that these elements were not collected by a sulfide liquid. Palladium, Cu, and Se correlate with each other, but not with S. The low S/Se (<1500) of the whole rock and magnetite rims around the sulfides indicate some S has been lost from the rocks. We conclude that to account for all observations, the IPGE and Rh were originally collected by chromite, and subsequently, small quantities of base metal sulfide liquid was added to the chromite layers from the overlying magma. The IPGE and Rh in the chromite diffused from the chromite into the base metal sulfides and converted some of the sulfides to laurite.