Pier-John Sazio

Highly efficient blue photoluminescence from colloidal lead-iodide nanoparticles

We report the synthesis of solvent-stabilized lead-iodide nanoparticles, using a convenient route involving coordinating solvents. The resultant colloids show strong absorption features in the ultraviolet region of the optical spectrum, which are consistent with the formation of semiconducting nanocrystals of lead (II) iodide. An effective-mass approximation model of quantum-confined states is in good agreement with the observed transition energies, giving strong indications of the particle morphologies and dimensions. Intense photoluminescence is also observed, with some spectral tuning possible with ripening time, giving a range of emission photon energies approximately spanning from 2.5 to 3.0 eV. We measure photo-stable luminescence quantum efficiencies of around 20% in solution, increasing to up to 30% if the coordinating ligand is exchanged for a Lewis-base capping layer. This demonstrates the potential for the utilization of lead-iodide nanocrystals in visible optoelectronics applications.

Single is better than double: analysis of thermal poling configurations using 2D numerical modeling

Thermal poling, a technique to create permanently effective second-order susceptibility in silica optical fibers, has a wide range of applications, such as frequency conversion, electro-optic modulation, switching and polarization-entangled photon pairs generation. After many works where a conventional configuration anode-cathode was used, in 2009 a new electrode configuration (double-anode) was adopted, which allows for a more temperature-stable depletion region formation and a higher value of effective Chi21, 2. In this work we demonstrate, via numerical simulations realized in COMSOL® Multiphysics, that in a double-anode configuration the effective value of Chi2 strongly depends on the relative position of the core with respect to the electrodes, requiring an accurate and precisely tailored geometry of the fiber, while in a single-anode configuration this value, for standard poling conditions1 is almost independent of the position of the core, offering the possibility of relaxing the manufacturing constraint of the fiber fabrication. We also demonstrate that, in the same experimental conditions, the maximum value of effective Chi2 induced by thermal poling in double-anode configuration is smaller than the one obtained in single-anode configuration for any position of the core in the range between the anodic surface and the geometric center of the fiber. Finally, we report the experimental observation of depletion region formation in a twin-hole fused silica fiber poled in single-anode configuration. Using a QPM SHG experimental set-up, we demonstrate that the value of Chi2 obtained in the single anode configuration is at least as large as for the double anode one.

Dataset for proceeding paper: Single is better than double. Analysis of thermal poling configurations using 2D numerical modeling

Dataset supports: De Lucia, F., & Sazio, P-J. (2018). Single is better than double: analysis of thermal poling configurations using 2D numerical modeling. In Proceedings of SPIE Photonics West 2018 SPIE.

Dataset for Optimised optical fiber poling configurations: A numerical study

Dataset supports: De Lucia, F., & Sazio, P-J. (2018). Optimised optical fiber poling configurations: A numerical study. Poster for the conference OSA Advanced Photonics Congress 2018, Zurich, 2-5 July.

Composite material hollow core fibers - functionalisation with silicon and 2D materials

Hollow Core Anti-resonant fibers allow for guidance of mid-infrared light at low attenuation and can be used for a variety of applications, such as high power laser transmission and gas sensing. Recent work has seen the integration of silicon into such fibers with linear losses potentially as low as 0.1dB/m. Due to the change in refractive index difference of silicon via for example the free carrier plasma dispersion effect, the prospect of an all optical modulator using such a fiber has been proposed. Here, further work has been undertaken on the integration of functional materials inside hollow core fibers via the deposition of the TMD semiconductor material MoS2, in its few-layered form. Through the use of a liquid precursor, a high quality MoS2 film can be deposited over 30cm length of fiber, as confirmed via Raman spectroscopy. The transmission spectra of these novel composite material hollow core fibers has also been analysed, showing additional loss of around 5dB/m, despite being only around 2nm in thickness. This implies that the refractive index of the integrated material is potentially able to modify the guidance properties of the fiber sample. We will present a comparison of the composite material hollow core fibers we have fabricated to date and discuss the prospects for using these novel waveguides in the active manipulation of light, including optical switching, sensing and frequency generation.

Four-wave mixing UV generation in optical microfibers

UV generation via four-wave-mixing (FWM) in optical microfibres (OMFs) was demonstrated. This was achieved by exploiting the tailorable dispersion of the OMF in order to phase match the propagation constant of the four frequencies involved in the FWM process. In order to satisfy the frequency requirement for FWM, a Master Oscillator Power Amplifier (MOPA) working at the telecom C-band was connected to a periodically poled silica fibre (PPSF), producing a fundamental frequency (FF) at 1550.3 nm and a second harmonic (SH) frequency at 775.2 nm. A by-product of this second harmonic generation is the generation of a signal at the third harmonic (TH) frequency of 516.7 nm via degenerate FWM. This then allows the generation of the fourth harmonic (FH) at 387.6 nm and the fifth harmonic (5H) at 310nm via degenerate and nondegenerate FWM in the OMF.The output of the PPSF was connected to a pure silica core fibre which was being tapered using the modified flame brushing technique from an initial diameter of 125 μm to 0.5 μm. While no signal at any UV wavelength was initially observed, as the OMF diameter reached the correct phase matching diameters, signals at 387.6 nm appeared. Signals at 310 nm also appeared although it is not phase matched, as the small difference in the propagation constant is bridged by other nonlinear processes such as self-phase and cross phase modulation.

Dataset for All-fiber fourth and fifth harmonic generation from a single source

Raw data for figures in Abdul Khudus, Muhammad, Lee, Timothy, De Lucia, Francesco, Corbari, Constantino, Sazio, Pier-John, Horak, Peter and Brambilla, Gilberto (2016) All-fiber fourth and fifth harmonic generation from a single source. Optics Express, 24, (19), 21777-21793. (doi:10.1364/OE.24.021777)

Enhancement of four-wave mixing frequency generation in optical microfibers

Data for the figures in the paper entitled enhancement of four-wave mixing frequency generation in optical microfibers

Dataset for Numerical analysis using 2D modeling of optical fiber poled by induction

Data for the figures in the paper entitled Numerical analysis using 2D modeling of optical fiber poled by induction

Dataset for Comparison of novel liquid electrodes for silica optical fiber thermal poling

Data for table reported into the Cleo US manuscript entitled Comparison of novel liquid electrodes for silica optical fiber thermal poling